journal article·2020-12

Fex-Co1-x bimetallic catalysts for highly efficient growth of carbon nanotubes on carbon fibers

Zhiqiang Yao, Chengguo Wang, Jianjie Qin, Yanxiang Wang, Qifen Wang, Huazhen Wei

Ceramics International· Volume 46· Issue 17
Publisher page

Abstract

Abstract This paper aims to develop a catalyst for highly efficient growth of carbon nanotubes (CNTs) on carbon fibers (CFs) with improved tensile strength by chemical vapor deposition (CVD). The effect of the composition of Fex-Co1-x catalysts on the morphology of the synthesized CNTs and the tensile properties of the CFs at different stages of the CVD process were explored. It was found that the bimetallic catalysts possessed better catalytic effect than monometallic catalysts at low temperature. The detailed study of the tensile properties of CFs at different stages of CVD process manifested that the composition of catalysts affected the catalytic activity. When the atomic fraction of Fe was 50%, the bimetallic catalyst among Fex-Co1-x family was considered to hold the highest catalytic efficiency due to the least damage to the fibers and the ability to generate more carbon atoms to repair and reinforce CFs. The corresponding tensile strength of the final CNTs-grafted CFs was 11.53% higher than that of the desized CFs.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fiber-reinforced polymer composites · Carbon Nanotubes in Composites · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (19)

Show source-provided references
1. Carbon nanotube – carbon fiber reinforced polymer composites with extended fatigue life10.1016/j.compositesb.2018.11.056 ↗
2. Interfacial modification and enhancement of toughening mechanisms in epoxy composites with CNTs grafted on carbon fibers10.1016/j.compscitech.2016.08.010 ↗
3. On the optimal design of manufacturing-induced residual stresses in filament wound carbon fiber composite cylindrical shells reinforced with carbon nanotubes10.1016/j.compscitech.2019.107743 ↗
4. Design of electrically conductive structural composites by modulating aligned CVD-grown carbon nanotube length on glass fibers10.1021/acsami.6b13397 ↗
5. Grafting CNTs on carbon fabrics with enhanced mechanical and thermal properties for tribological applications of carbon fabrics/phenolic composites10.1016/j.carbon.2018.06.032 ↗
6. Hierarchical carbon nanotube-coated carbon fiber: ultra lightweight, thin, and highly efficient microwave absorber10.1021/acsami.8b06673 ↗
7. Effect of growth temperature on carbon nanotube grafting morphology and mechanical behavior of carbon fibers and carbon/carbon composites10.1016/j.jmst.2016.08.015 ↗
8. Synthesis and growth mechanism of carbon nanotubes growing on carbon fiber surfaces with improved tensile strength10.1088/1361-6528/aad10c ↗
9. Degradation and healing mechanisms of carbon fibers during the catalytic growth of carbon nanotubes on their surfaces10.1021/am3002499 ↗
10. Preparation of vertically aligned carbon nanotube arrays grown onto carbon fiber fabric and evaluating its wettability on effect of composite10.1016/j.apsusc.2011.09.003 ↗
11. Direct growth of carbon nanotubes on carbon fibers: effect of the CVD parameters on the degradation of mechanical properties of carbon fibers10.1016/j.diamond.2014.11.002 ↗
12. Continuous method for grafting CNTs on the surface of carbon fibers based on cobalt catalyst assisted by thiourea10.1007/s10853-019-03827-8 ↗
13. Communication—catalyst study on the large-scale preparation of carbon nanotube-grafted carbon fibers with high tensile strength10.1149/2.0131606jss ↗
14. Low-temperature grafting of carbon nanotubes on carbon fibers using a bimetallic floating catalyst10.1016/j.diamond.2016.06.012 ↗
15. Investigation on the temperature-dependent growth rate of carbon nanotubes using chemical vapor deposition of ferrocene and acetylene10.1016/j.cplett.2004.11.113 ↗
16. Controllable growth of uniform carbon nanotubes/carbon nanofibers on the surface of carbon fibers10.1039/C5RA15556H ↗
17. Effect of a multiscale reinforcement by carbon fiber surface treatment with graphene oxide/carbon nanotubes on the mechanical properties of reinforced carbon/carbon composites10.1016/j.compositesa.2016.08.012 ↗
18. Synergistic effects in bimetallic nanoparticles for low temperature carbon nanotube growth10.1002/adma.200801006 ↗
19. Mechanisms for catalytic carbon nanofiber growth studied byab initiodensity functional theory calculations10.1103/PhysRevB.73.115419 ↗