Single-phased emission-tunable Ca3Si2O7:Ce3+, Eu2+ phosphors for white light-emitting diodes
Source abstract
Abstract
Abstract A series of single-phased emission-tunable Ca3Si2O7:Ce3+, Eu2+ phosphors has been prepared by the solid-state reaction method. The phosphors show two intense emission bands at about 450 nm and 610 nm, which are attributed to the 5d→4f transitions of Ce3+ and Eu2+ ions, respectively. The emission colors of Ca3Si2O7:Ce3+, Eu2+ phosphors vary from blue (0.148, 0.147) to white (0.309, 0.260), and eventually to orange (0.407, 0.319) by tuning the Eu2+/Ce3+ ratio. Energy transfer from Ce3+ to Eu2+ is studied by luminescence spectra and energy transfer efficiency. The results show an electric quadrupole–quadrupole interaction plays an important role in the process of energy transfer. The phosphors with tunable emission are suitable for application in white light-emitting diodes.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Luminescence Properties of Advanced Materials · Radiation Detection and Scintillator Technologies · Gas Sensing Nanomaterials and Sensors
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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