journal article·2013-12

Microstructure and mechanical properties of Cf/ZrC composites fabricated by reactive melt infiltration at relatively low temperature

Yulin Zhu, Song Wang, Hongmei Chen, Wei Li, Jinming Jiang, Zhaohui Chen

Ceramics International· Volume 39· Issue 8
Publisher page

Abstract

Abstract Carbon fiber-reinforced zirconium carbide matrix composites (Cf/ZrC) were prepared by vacuum infiltrating porous carbon/carbon preforms with molten Zr2Cu alloy at 1200 °C. X-ray diffraction, scanning electron microcopy and transmission electron microscopy analysis were used to characterize the composition and microstructure of the final composites. It was found that the matrix of the composites were composed of the Cu–Zr–C amorphous phase dispersed with either single- or polycrystalline ZrC. Based on the microstructural analysis, the formation mechanism of the matrix was proposed to be a solution-precipitation and grain coalescence process. The influence of the heat treatment at 1800 °C was also investigated. Results indicated that at very high temperature the volatilization of residual metal somewhat deteriorated the flexural strength and the elastic modulus, but the fracture toughness of the composites was improved due to the sintering of ZrC grains.
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Research context

OpenAlex topics: Advanced materials and composites · Advanced ceramic materials synthesis · Aluminum Alloys Composites Properties

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References (20)

Show source-provided references
1. Spark plasma sintering and mechanical behaviour of ZrC-based composites10.1016/j.scriptamat.2008.05.026 ↗
2. Rapid oxidation characterization of ultra-high temperature ceramics10.1111/j.1551-2916.2007.01861.x ↗
3. Fabrication of ZrB2–ZrC-based composites by reactive melt infiltration at relative low temperature10.1016/j.scriptamat.2011.03.033 ↗
4. ZrC ablation protective coating for carbon/carbon composites10.1016/j.carbon.2009.07.047 ↗
5. Microstructural development of a Cf/ZrC composite manufactured by reactive melt infiltration10.1016/j.jeurceramsoc.2009.10.016 ↗
6. Preparation of carbon fiber-reinforced zirconium carbide matrix composites by reactive melt infiltration at relative low temperature10.1016/j.scriptamat.2012.07.044 ↗
7. Ablation behavior and mechanism of 3D C/ZrC composite in oxyacetylene torch environment10.1016/j.compscitech.2011.05.005 ↗
8. Reaction kinetics and ablation properties of C/C–ZrC composites fabricated by reactive melt infiltration10.1016/j.ceramint.2010.12.002 ↗
9. Melt infiltration approach to ceramic matrix composites10.1111/j.1151-2916.1988.tb05840.x ↗
10. Microstructure and properties of W–ZrC composites prepared by the displacive compensation of porosity (DCP) method10.1016/j.jallcom.2011.05.105 ↗
11. Near net-shape/net-dimension ZrC/W-based composites with complex geometries via rapid prototyping and displacive compensation of porosity10.1016/j.jeurceramsoc.2010.01.011 ↗
12. Microstructural evolution in reaction-bonded silicon carbide10.1007/BF00553278 ↗
13. The combined effect of porosity and reactivity of the carbon preforms on the properties of SiC produced by reactive infiltration with liquid Si10.1016/j.carbon.2009.04.002 ↗
14. The kinetics of incongruent reduction of tungsten carbide via reaction with a hafnium–copper melt10.1016/j.actamat.2009.04.052 ↗
15. Near net-shape, ultra high melting, recession-resistant ZrC/W-based rocket nozzle liners via displacive compensation of porosity (DCP) method10.1023/B:JMSC.0000041697.67626.46 ↗
16. C/C–ZrC composite prepared by chemical vapor infiltration combined with alloyed reactive melt infiltration10.1016/j.ceramint.2012.04.017 ↗
17. Laser ablation ICP-MS investigation of solute element distributions during Al–Si solidification10.1016/j.jallcom.2005.07.060 ↗
18. Massalski · 1990
19. Study of formation behavior of ZrC in the Cu–Zr–C system during combustion synthesis10.1016/j.ijrmhm.2011.11.008 ↗
20. Mechanical properties of the low-temperature reactive melt infiltrated ZrB2–ZrC based composites10.1016/j.matlet.2012.03.028 ↗