journal article·2018-10

Positive effect of codoping Yb3+ on the super-long persistent luminescence of Cr3+-doped zinc aluminum germanate

Yi Zhang, Rui Huang, Zhenxu Lin, Hongliang Li, Dejian Hou, Jie Song, Shaomin Lin, Chao Song, Huihong Lin, Zewen Lin

Ceramics International· Volume 44· Issue 14
Publisher page

Abstract

Abstract A series of novel near-infrared (NIR) long persistent phosphors of Zn1.2Al1.6Ge0.2O4: Cr3+, Yb3+ was synthesized by a solid state method. The crystal structure of Zn1.2Al1.6Ge0.2O4 was identified. Yb3+ ions were effective codopants for improving the NIR persistent luminescence intensity even after 100 h of decay. The persistent luminescence decay curves and the thermo-luminescence spectra were analyzed. Results indicated that the increase in efficient electron trap concentration induced by doping Yb3+ ions was a major factor in the improvement of the NIR persistent luminescence. Moreover, short-wave infrared (SWIR = 900–1700 nm) emission of Yb3+ was be excited by UV and visible light through charge transfer transition of O2-–Yb3+ and energy transfer from Cr3+ to Yb3+, respectively.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Luminescence and Fluorescent Materials · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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