journal article·2016-11

Amorphous carbon nanotubes incorporated MgO-graphite composite with enhanced properties for steel making furnaces

D. Halder, P.R. Midya, S. Das, N.S. Das, I. Roy, K.K. Chattopadhyay

Ceramics International· Volume 42· Issue 14
Publisher page

Abstract

Abstract Conventional MgO-graphite composite used in steel ladles suffer drawbacks like limited lifetime due to slag corrosion and inherent tendency of rapid oxidation of carbon. Carbon content of MgO-graphite refractories was varied by replacing graphite partly by amorphous carbon nanotubes to decrease the total carbon content keeping the surface area of carbon the same or larger. The structural and compositional characterizations were performed by X-ray diffraction and energy dispersive analysis of X-rays. The Fourier transformed infrared and Raman spectroscopies were used to find bonding information and distinctive carbon phases. Distribution of amorphous carbon nanotubes within MgO matrix and its nature of attachment were studied by field emission scanning electron microscopy and transmission electron microscopy respectively. The cumulative volume of the large pores decreased significantly by incorporation of amorphous carbon nanotubes. Cup test using the composite material with actual molten slag indicated significantly less penetration of slag in the nanocarbon based nanocomposite.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnesium Oxide Properties and Applications · Advanced ceramic materials synthesis · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Corrosion behavior of pure Cr, Ni, and Fe exposed to molten salts at high temperature10.1155/2014/923271 ↗
2. Treatment of refractory powders by a novel, high enthalpy dc plasma10.1088/0022-3727/46/22/224019 ↗
3. Baibhaw Prakash, Sachin Gupta, Pravanjan Malik, Characterization and testing of 30kV, 60kW electron optical column for melting applications, in: Proceedings of the 2014 IEEE International Symposium on Discharges and Electrical Insulation in Vacuum (ISDEIV), 14, 2014, pp. 617–62010.1109/DEIV.2014.6961758 ↗
4. Effect of Al addition on mechanical properties and microstructure of refractory AlxHfNbTaTiZr alloys10.1016/j.jallcom.2014.11.064 ↗
5. Strength behavior of magnesia-based refractories after thermal cycling10.1111/ijac.12027 ↗
6. Experience from the use of modern unmolded refractory materials in the lining of the heating furnaces of rolling mills10.1007/s11148-012-9466-6 ↗
7. Synthesis and thermal properties of inorganic polymers (geopolymers) for structural and refractory applications from volcanic ash10.1016/j.ceramint.2011.05.002 ↗
8. Investigation of surface morphology, anti-corrosive and abrasionresistance properties of nickel oxide epoxy nanocomposite (NiO-ENC)coating on mild steel substrate10.1016/j.porgcoat.2014.11.007 ↗
9. Damage resistance and anticorrosion properties of nanosilica-filledepoxy-resin composite coatings10.1016/j.porgcoat.2014.11.011 ↗
10. A. Sen, B. Prasad, J.K. Sahu, J.N. Tiwari, Enhancement of high temperature structural strength of carbon bonded ceramics by using nano materials, in: Proceedings of the 2015 IEEE International Conference on Nascent Technologies in the Engineering Field (ICNTE), 201510.1109/ICNTE.2015.7029935 ↗
11. Microstructure and mechanical properties of low-carbon MgO-C refractories bonded by an Fe nanosheet-modified phenol resin10.1016/j.ceramint.2014.09.091 ↗
12. Enhanced mechanical properties of HfMoTaTiZr and HfMoNbTaTiZr refractory high-entropy alloys10.1016/j.intermet.2015.03.013 ↗
13. Lightweight cordierite–mullite refractories with low coefficients of thermal conductivity and high mechanical properties10.1007/s12034-014-0837-0 ↗
14. Chemical wear of Al2O3–MgO–C bricks by air and basic slag10.1016/j.jeurceramsoc.2014.11.024 ↗
15. Radiation effects and damage mechanisms in ceramic insulators and window materials10.1016/0022-3115(88)90228-0 ↗
16. Treatment of refractory organic pollutants in industrial wastewater by wet air oxidation
17. Fabrication of nanocrystalline WC and nanocomposite WC–MgO refractory materials at room temperature10.1016/S0925-8388(99)00508-3 ↗
18. Synthesis, vaporization and thermodynamics of ceramic powders based on the Y2O3-ZrO2-HfO2 system10.1016/j.matchemphys.2014.12.037 ↗
19. Extraction and characterization of alumina nanopowders from aluminum dross by acid dissolution process10.1007/s12613-015-1090-2 ↗
20. The limitations of applying zero-valent iron technology in contaminants sequestration and the corresponding countermeasures: the development in zero-valent iron technology in the last two decades (1994–2014)10.1016/j.watres.2015.02.034 ↗
21. Chemical compositions of black carbon particle cores and coatings via soot particle aerosol mass spectrometry with photoionization and electron ionization10.1021/jp510711u ↗
22. Catalytic formation of one-dimensional nano carbon and MgO whiskers in low carbon MgO-C refractories10.1016/j.ceramint.2014.11.017 ↗
23. Fabrication and properties of MgO-C refractories improved with expanded graphite10.1016/j.ceramint.2014.08.007 ↗
24. Study on low carbon containing MgO-C refractory: use of nano carbon10.1016/j.ceramint.2011.10.086 ↗
25. Synthesis and characterization of water soluble functionalized amorphous carbon nanotube-polyvinyl alcohol composite10.1007/s13233-012-0154-7 ↗
26. Fabrication of barium/strontium carbonate coated amorphous carbon nanotubes as an improved field emitter10.1007/s00339-012-7252-4 ↗
27. Surface modification of amorphous carbon nanotubes with copper phthalocyanine leading to enhanced field emission10.1039/C2RA21776G ↗
28. Amorphous carbon nanotube/polyaniline core-shell nanostructure for efficient cold cathode application10.1039/c3ra44517h ↗
29. Shear and friction between carbon nanotubes in bundles and yarns10.1021/nl502210r ↗
30. Effect of MgO doping on the phase transformations of BaTiO310.1111/j.1151-2916.2000.tb01156.x ↗
31. Excellent fluoride removal properties of porous hollow MgO microspheres10.1039/C4NJ01361A ↗
32. Graphene oxide reduced and modified by environmentally friendly glycylglycine and its excellent catalytic performance10.1088/0957-4484/25/13/135707 ↗
33. In situ FTIR and Raman spectro electrochemical characterization of graphene oxide upon electrochemical reduction in organic solvents10.1039/C5CP00942A ↗
34. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide10.1016/j.carbon.2007.02.034 ↗
35. Atomic structure and physical properties of amorphous carbon and its hydrogenated analogs10.1103/PhysRevB.48.4823 ↗