journal article·2015-04Open access

Spark plasma sintering of agglomerated vanadium carbide powder

Wei Li, Eugene A. Olevsky, Oleg L. Khasanov, Christina A. Back, Oleg Izhvanov, Jonas Opperman, Hesham E. Khalifa

Ceramics International· Volume 41· Issue 3

Abstract

Abstract Spark plasma sintering (SPS) is an emerging powder consolidating technique which promises high potential capabilities to process refractory ceramics with properties previously unattainable. As the first step in studying the applicability of this technique to the processing of tailored ceramic structures, the validity of SPS to consolidate refractory carbides with controllable porosity is investigated. Vanadium carbide (V 8 C 7 ) is chosen as a studied material. The structure, thermal and mechanical properties of the V 8 C 7 powder pellets produced by SPS are analyzed and discussed in the paper. The attained properties of the processed ceramic material are in particular suitable for applications where high electrical conductivity and strength at high melting temperatures, low thermal conductivity and low thermal expansion coefficient are needed.
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Research context

OpenAlex topics: Advanced materials and composites · Advanced ceramic materials synthesis · Nuclear Materials and Properties

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References (37)

Show source-provided references
1. Electric pulse consolidation: an alternative to spark plasma sintering10.1007/s10853-013-7805-8 ↗
2. Outside mainstream electronic databases: review of studies conducted in USSR and post-soviet countries on electric current-assisted consolidation of powder materials10.3390/ma6104375 ↗
3. Densification, mechanical properties and wear behavior of WC–VC–Co–Al hardmetals10.1016/S0263-4368(01)00014-2 ↗
4. Sintering and microstructural development in WC/Co-based alloys made with superfine WC powder10.1016/S0263-4368(98)00073-0 ↗
5. Reduction of carbide grain growth in WC–VC–Co by sintering in a nitrogen atmosphere10.1016/j.ijrmhm.2008.01.014 ↗
6. Binderless WC and WC–VC materials obtained by pulsed electric current sintering10.1016/j.ijrmhm.2007.01.002 ↗
7. Role of vanadium carbide additive during sintering of WC–Co: mechanism of grain growth inhibition10.1111/j.1151-2916.2003.tb03293.x ↗
8. Influence and effectivity of VC and Cr3C2 grain growth inhibitors of sintering of binderless tungsten carbide10.1016/j.ijrmhm.2011.11.006 ↗
9. Pressureless densification of ZrB2–SiC composites with vanadium carbide10.1016/j.scriptamat.2008.03.029 ↗
10. In situ production of vanadium carbide particulates reinforced iron matrix surface composites by cast-sintering10.1016/j.matdes.2006.07.008 ↗
11. TiC–VC–Co: a study on its sintering and microstructure10.1016/S0263-4368(01)00013-0 ↗
12. Reaction synthesis of in situ vanadium carbide particulates-reinforced iron matrix composites by spark plasma sintering10.1007/s10853-010-4295-9 ↗
13. Effect of VC addition on sinterability and microstructure of ultrafine Ti(C,N)-based cermets in spark plasma sintering10.1016/j.jallcom.2007.05.091 ↗
14. Densification of uranium dioxide fuel pellets prepared by spark plasma sintering10.1016/j.jnucmat.2012.12.010 ↗
15. Metallic fast reactor fuels10.1016/0149-1970(96)00005-4 ↗
16. Configuring EM2 to meet the challenges of economics, waste disposition and non-proliferation confronting nuclear energy in the U.S10.13182/FST12-A13411 ↗
17. Thermalphysical properties of uranium dioxide10.1016/S0022-3115(99)00273-1 ↗
18. Applicability of CeO2 as a surrogate for PuO2 in a MOX fuel development10.1016/j.jnucmat.2008.05.003 ↗
19. Effect of sintering conditions on the microstructure and mechanical properties of ZrN as a surrogate for actinide nitride fuels10.1016/j.jnucmat.2007.03.023 ↗
20. Lide · 1998
21. Ma · 1983
22. The carbides of uranium10.1016/0022-3115(63)90181-8 ↗
23. R. Edwin, Air Force Materials Laboratory Report AFML-TR-69-117, Part VII, 1970.
24. Phase transformations in non-stoichiometric vanadium carbide10.1088/0953-8984/11/1/014 ↗
25. Pierson · 1996
26. Initial state of free pressureless spark-plasma sintering of vanadium carbide: determination of surface diffusion parameters10.1016/j.ijrmhm.2013.06.009 ↗
27. Measurement of grain size using the circle intercept method10.1016/0036-9748(87)90167-0 ↗
28. ASTM C1499 – 09 Standard Test Method for Monotonic Equibiaxial Flexural Strength of Advanced Ceramics at Ambient Temperature.
29. Graphene-induced strengthening in spark plasma sintered tantalum carbide-nanotube composite10.1016/j.scriptamat.2012.10.043 ↗
30. Theory of sintering: from discrete to continuum10.1016/S0927-796X(98)00009-6 ↗
31. Murain · 2011
32. Specific heat capacity and Debye temperature of zirconia and its solid solution10.1016/S0040-6031(03)00060-1 ↗
33. German · 1996
34. Processing model for tungsten powders and extension to nanoscale size range10.1179/174329006X94690 ↗
35. Complex thermoelectric materials10.1038/nmat2090 ↗
36. Spark plasma sintering of tantalum carbide10.1016/j.scriptamat.2010.06.006 ↗
37. Combustion synthesis and quasi-isostatic densification of powder cermets10.1016/S0924-0136(01)01236-5 ↗