journal article·2021-09

In-situ growth of silicon carbide nanofibers on carbon fabric as robust supercapacitor electrode

Zhenghe Zhang, Jing Tan, Lisheng Cheng, Weimin Yang

Ceramics International· Volume 47· Issue 17
Publisher page

Abstract

Abstract Silicon carbide nanofibers (SiCnf) that possess high electron mobility and wide bandgap have attracted tremendous research attention in the past decades, and they have been of paramount importance in promoting the application of novel energy technologies. Herein, we proposed a facile and efficient method to accelerate the in-situ growth of SiCnf on a carbon fabric with fused KCl. The carbon fabric impregnated with KCl solution can realize an efficient reaction between the active carbon atom and the silicon source at a temperature as low as 1100 °C. The as-obtained composite yields a porous structure with an enhanced graphitization degree. It is suggested that the fused KCl can promote the growth of SiCnf with much lower energy consumption, and the proposed method is facile, eco-friendly, and easy to be scaled-up. When evaluated as a supercapacitor electrode, the as-prepared material exhibits a capacitance as high as 4.36 mF⋅cm−2 at a scan rate of 0.05 V⋅s−1. Furthermore, the capacitance of the as-assembled supercapacitor exhibits an increase of 6.51% after 10000 cycles at room temperature. Therefore, the prepared SiCnf is a good candidate for supercapacitor electrodes. This work may facilitate the design of high-performing supercapacitor electrodes in the future.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Electrospun Nanofibers in Biomedical Applications · Advanced Sensor and Energy Harvesting Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Conjugated microporous polymer network grafted carbon nanotube fibers with tunable redox activity for efficient flexible wearable energy storage10.1021/acs.chemmater.0c02089 ↗
2. Microstructure design of carbonaceous fibers: a promising strategy toward high-performance weaveable/wearable supercapacitors10.1002/smll.202000653 ↗
3. Scalable synthesis of hierarchically structured carbon nanotube-graphene fibres for capacitive energy storage10.1038/nnano.2014.93 ↗
4. Direct growth of ultrathin NiCo2O4/NiO nanosheets on SiC nanowires as a free-standing advanced electrode for high-performance asymmetric supercapacitors10.1021/acssuschemeng.6b00697 ↗
5. Laser transmission welding and surface modification of graphene film for flexible supercapacitor applications10.1016/j.apsusc.2019.03.349 ↗
6. Enhanced supercapacitor performance with binder-free helically coiled carbon nanotube electrodes10.1016/j.carbon.2018.08.064 ↗
7. Postsynthetic treatment of carbon nano-onions: surface modification by heteroatoms to enhance their capacitive and electrocatalytic properties10.1016/j.carbon.2019.02.063 ↗
8. High-performance biscrolled MXene/carbon nanotube yarn supercapacitors
9. Strong charge transfer at 2H-1T phase boundary of MoS2 for superb high-performance energy storage10.1002/smll.201900131 ↗
10. Balancing crystallinity and specific surface area of metal-organic framework derived nickel hydroxide for high-performance supercapacitor10.1016/j.electacta.2018.07.173 ↗
11. Quasi-aligned SiC@C nanowire arrays as free-standing electrodes for high-performance micro-supercapacitors10.1016/j.ensm.2020.02.009 ↗
12. Silicon carbide nanowires as highly robust electrodes for micro-supercapacitors10.1016/j.jpowsour.2012.12.085 ↗
13. Performance characteristics of supercapacitor electrodes made of silicon carbide nanowires grown on carbon fabric10.1016/j.jpowsour.2013.06.050 ↗
14. Solution blown silicon carbide porous nanofiber membrane as electrode materials for supercapacitors10.1016/j.electacta.2016.05.003 ↗
15. The crystallization and growth of SiC nanowires converted from self-assembly Si nanorods on carbon fabric and their electrochemical capacitance property10.1016/j.jallcom.2020.154168 ↗
16. Supercapacitor behavior of SiC coated copper hydroxide and copper sulfide nano-wires10.1016/j.jallcom.2019.01.373 ↗
17. Fabrication of Ni@SiC composite nanofibers by electrospinning and autocatalytic electroless plating techniques10.1016/j.rinp.2018.12.051 ↗
18. A high-energy density asymmetric supercapacitor based on Fe2O3 nanoneedle arrays and NiCo2O4/Ni(OH)(2) hybrid nanosheet arrays grown on SiC nanowire networks as free-standing advanced electrodes10.1002/aenm.201702787 ↗
19. Growth of silicon carbide nanowires by a microwave heating-assisted physical vapor transport process using group VIII metal catalysts10.1021/cm071213r ↗
20. Ultralong SiC/SiO2 nanowires: simple gram-scale production and their effective blue-violet photoluminescence and microwave absorption properties10.1021/acssuschemeng.7b03908 ↗
21. Fabrication and mechanical properties of carbon fibers/lithium aluminosilicate ceramic matrix composites reinforced by in-situ growth SiC nanowires10.1016/j.jeurceramsoc.2019.06.035 ↗
22. Ultralight, recoverable, and high-temperature-resistant SiC nanowire aerogel10.1021/acsnano.7b08577 ↗
23. Catalytic synthesis of crystalline SiC nanowires from a Ni/a-C/Si sandwich configuration10.1039/c3ce40372f ↗
24. WO3-x@Au@MnO2 core-shell nanowires on carbon fabric for high-performance flexible supercapacitors10.1002/adma.201104113 ↗
25. Growth of β-SiC nanowires on Si(100) substrates by MOCVD using nickel as a catalyst10.1016/j.tsf.2004.06.077 ↗
26. Siloxene nanosheets: a metal-free semiconductor for water splitting10.1039/C6TA07545B ↗
27. Two-dimensional silicon suboxides nanostructures with Si nanodomains confined in amorphous SiO2 derived from siloxene as high performance anode for Li-ion batteries10.1016/j.nanoen.2017.07.040 ↗
28. Dielectric and infrared properties of silicon carbide nanopowders10.1016/S0272-8842(02)00037-8 ↗
29. Synthesis and growth mechanism of SiC nanofibres on carbon fabrics10.1039/C6CE02602H ↗
30. Molten salt in-situ exfoliation of graphite to graphene nanoplatelets applied for energy storage10.1016/j.carbon.2021.01.133 ↗
31. Mixed-valent MnSiO3/C nanocomposite for high-performance asymmetric supercapacitor10.1016/j.jcis.2019.08.054 ↗
32. Graphene-based supercapacitor with an ultrahigh energy density10.1021/nl102661q ↗
33. High temperature all solid state supercapacitor based on multi-walled carbon nanotubes and poly[2,5 benzimidazole]10.1007/s10008-012-1679-6 ↗
34. Laser CVD growth of graphene/SiC/Si nano-matrix heterostructure with improved electrochemical capacitance and cycle stability10.1016/j.carbon.2021.01.004 ↗
35. Synthesis of a novel magnetite/nitrogen-doped reduced graphene oxide nanocomposite as high performance supercapacitor10.1016/j.powtec.2016.08.054 ↗
36. Synthesis of a novel interconnected 3D pore network algal biochar constituting iron nanoparticles derived from a harmful marine biomass as high-performance asymmetric supercapacitor electrodes10.1021/acssuschemeng.7b03871 ↗
37. Single-crystalline integrated 4H-SiC nanochannel array electrode: toward high-performance capacitive energy storage for robust wide-temperature operation10.1039/C8MH00474A ↗
38. Silicon carbide nanocauliflowers for symmetric supercapacitor devices10.1021/acs.iecr.6b02243 ↗
39. Silicon carbide coated silicon nanowires as robust electrode material for aqueous micro-supercapacitor10.1063/1.4704187 ↗
40. Graphitization of n-type polycrystalline silicon carbide for on-chip supercapacitor application10.1063/1.3638468 ↗
41. Electrochemistry of nanocrystalline 3C silicon carbide films10.1002/chem.201103765 ↗
42. 3D 3C-SiC/Graphene hybrid nanolaminate films for high-performance supercapacitors10.1002/smll.201801857 ↗