A critical electrochemical performance descriptor of ferrites as anode materials for Li-ion batteries: Inversion degree
Source abstract
Abstract
Abstract In order to understand the essential relationship between the degree of inversion of MFe2O4 and their electrochemical properties as anode materials for Li-ion batteries (LIBs), microspherical MFe2O4 (M = Ni, Co and Zn) nanocomposites were prepared via a facile wet-chemical method. The results showed that all the obtained microspherical nanocomposites are composed of their corresponding nanoparticles with a diameter of about 20 nm. The electrochemical results showed that these hierarchical nanocomposites exhibit excellent properties with high capacities, good cycling stabilities and superior rate capabilities. Moreover, MFe2O4 electrodes at different degree of inversion demonstrated the different Li-ions storage mechanisms. NiFe2O4, at high degree of inversion demonstrated one-step mechanism. CoFe2O4, at medium degree of inversion demonstrated consecutive two-step mechanism. Finally, ZnFe2O4, at low degree of inversion, demonstrated separated multistep mechanism. Therefore, it is reasonable to believe that different degree of inversion can be used as the electrochemical performance descriptor for novel ferrites-based anode materials for high performance LIBs.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Magnetic Properties and Synthesis of Ferrites · Extraction and Separation Processes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (40)
Show source-provided references
1. A review on the growing concern and potential management strategies of waste lithium-ion batteries10.1016/j.resconrec.2017.11.001 ↗
2. A review on design strategies for carbon based metal oxides and sulfides nanocomposites for high performance Li and Na ion battery anodes10.1002/aenm.201601424 ↗
3. A scalable formation of nano-SnO2 anode derived from tin metal–organic frameworks for lithium-ion battery10.1039/C5RA12295C ↗
4. Sandwich-structured graphite-metallic silicon@ C nanocomposites for Li-ion batteries10.1016/j.electacta.2016.01.067 ↗
5. Facial synthesis of three-dimensional cross-linked cage for high-performance lithium storage10.1021/acsami.6b02855 ↗
6. Carbon cloth supported anatase TiO2 aligned arrays as a high-performance anode material for Li-ion batteries10.1016/j.matlet.2016.01.065 ↗
7. A composite with SiOx nanoparticles confined in carbon framework as an anode material for lithium ion battery10.1039/C6RA04885D ↗
8. Carbon-coated SiO/ZrO2 composites as anode materials for lithium-ion batteries10.1016/j.ceramint.2016.12.074 ↗
9. Challenges in the development of advanced Li-ion batteries: a review10.1039/c1ee01598b ↗
10. Systematics of the spinel structure type10.1007/BF00307535 ↗
11. Spinel structures: with and without variate atom equipoints10.1524/zkri.1932.82.1.325 ↗
12. Effect of surface modification with spinel NiFe2O4 on enhanced cyclic stability of LiMn2O4 cathode material in lithium ion batteries10.1021/acssuschemeng.7b02876 ↗
13. What happens structurally and electronically during the Li conversion reaction of CoFe2O4 nanoparticles: an operando XAS and XRD investigation10.1021/acs.chemmater.5b01754 ↗
14. Probing the Li insertion mechanism of ZnFe2O4 in Li-ion batteries: a combined X-ray diffraction, extended X-ray absorption fine structure, and density functional theory study10.1021/acs.chemmater.7b00467 ↗
15. ZnFe2O4-nanocrystal-assembled microcages as an anode material for high performance lithium-ion batteries10.1016/j.mtener.2016.12.001 ↗
16. Mixed oxides,(Ni1–x Zn x) Fe2O4 (x= 0, 0.25, 0.5, 0.75, 1): molten salt synthesis, characterization and its lithium-storage performance for lithium ion batteries10.1021/jp5121178 ↗
17. The kinetics and mechanism of solid-state spinel formation—a review and critique10.1007/BF00603514 ↗
18. A structural and magnetic investigation of the inversion degree in ferrite nanocrystals MFe2O4 (M= Mn, Co, Ni)10.1021/jp901077c ↗
19. Cationic exchange in nanosized ZnFe2O4 spinel revealed by experimental and simulated near-edge absorption structure10.1103/PhysRevB.75.073408 ↗
20. A facile hydrothermal synthesis of novel hollow triple-shell CuNiFe2O4 nanospheres with robust catalytic performance in the Suzuki–Miyaura coupling reaction10.1016/j.jcat.2018.01.028 ↗
21. Monodisperse magnetic single‐crystal ferrite microspheres10.1002/ange.200462551 ↗
22. Uniform NiCo2O4/NiFe2O4 hollow nanospheres with excellent properties for Li-ion batteries and supercapacitors10.1016/j.jallcom.2018.07.091 ↗
23. In situ synthesis of hierarchical CoFe2O4 nanoclusters/graphene aerogels and their high performance for lithium-ion batteries10.1039/C5CP04628A ↗
24. Corncob-shaped ZnFe2O4/C nanostructures for improved anode rate and cycle performance in lithium-ion batteries10.1039/C5RA04790K ↗
25. Synthesis of carbon embedded MFe2O4 (M= Ni, Zn and Co) nanoparticles as efficient hydrogenation catalysts10.1039/C4DT01123F ↗
26. Three-dimensional NiCo2O4@ NiWO4 core–shell nanowire arrays for high performance supercapacitors10.1039/C6TA08578D ↗
27. Morphology and structure of electrospun CoFe2O4/multi-wall carbon nanotubes composite nanofibers10.1016/j.cej.2010.05.025 ↗
28. Band alignment engineering for improved performance and stability of ZnFe2O4 modified CdS/ZnO nanostructured photoanode for PEC water splitting10.1016/j.nanoen.2016.04.001 ↗
29. A low temperature synthesis of nanocrystalline spinel NiFe2O4 and its electrochemical performance as anode of lithium-ion batteries10.1016/j.materresbull.2012.12.072 ↗
30. CoFe2O4 nanoplates synthesized by dealloying method as high performance Li-ion battery anodes10.1016/j.electacta.2017.08.189 ↗
31. 3-dimensional hierarchically porous ZnFe2O4/C composites with stable performance as anode materials for Li-ion batteries10.1016/j.cej.2018.08.202 ↗
32. SEI growth and depth profiling on ZFO electrodes by soft X‐ray absorption spectroscopy10.1002/aenm.201500642 ↗
33. Mesoporous zinc ferrite/graphene composites: towards ultra-fast and stable anode for lithium-ion batteries10.1016/j.carbon.2014.08.007 ↗
34. Graphene oxide sheets-induced growth of nanostructured Fe3O4 for a high-performance anode material of lithium ion batteries10.1039/C5TA01617G ↗
35. One-pot synthesis of NiFe2O4/C composite as an anode material for lithium-ion batteries10.1016/j.jpowsour.2013.01.043 ↗
36. Porous ZnFe2O4 nanospheres as anode materials for Li-ion battery with high performance10.1016/j.jallcom.2017.06.031 ↗
37. Porous CoFe2O4 nanocubes derived from metal-organic frameworks as high-performance anode for sodium ion batteries10.1016/j.jcis.2017.03.104 ↗
38. Fabrication of NiFe2O4/C hollow spheres constructed by mesoporous nanospheres for high-performance lithium-ion batteries10.1016/j.cej.2016.06.032 ↗
39. A general approach for MFe2O4 (Má= áZn, Co, Ni) nanorods and their high performance as anode materials for lithium ion batteries10.1016/j.jpowsour.2013.08.109 ↗
40. Long cycle life of CoMn2O4 lithium ion battery anodes with high crystallinity10.1039/C5TA03570H ↗