Extrinsic magnetism in Co-doped BaTiO3 powders prepared by sol-gel route
Source abstract
Abstract
Abstract We report on the structural, magnetic, and magnetocaloric properties of Ba 1−x Co x TiO 3 (x=0,0.02, and 0.03) powders prepared by sol-gel technique. X-ray diffraction shows that pure BaTiO 3 powders crystallize in a tetragonal phase with a transition to pseudo-cubic phase after Co doping. Using the modified Brillouin modelling of the isothermal magnetization at various temperatures, we report that the magnetism of our system is extrinsic and due to the existence of antiferromagnetic cobalt oxide particles randomly distributed, which are undetectable by structural analyses. We discuss the existence of particles by the low enthalpy formation of cobalt oxides (high stability). Furthermore, it is demonstrated that the Ba 0.97 Co 0.03 TiO 3 sample exhibits a magnetocaloric effect with a maximum magnetic entropy change of 50 mJ/kg K for a magnetic field change of ΔH=50 kOe at 3 K.
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Research context
OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Multiferroics and related materials · Advanced Condensed Matter Physics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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