journal article·2008-12

Modelling of high-chromia refractory spalling in slagging coal gasifiers

R.E. Williford, K.I. Johnson, S.K. Sundaram

Ceramics International· Volume 34· Issue 8
Publisher page

Abstract

The economic viability of converting coal into clean burning liquid fuels in slagging coal gasifiers is compromised by the limited service lifetime of hot-face refractories. One of the most severe refractory degradation mechanisms is spalling, which can occur by either volume-expansion phenomena (compressive stresses) or by volume-shrinkage phenomena (tensile stresses). A volume-shrinkage model is benchmarked to high-chromia refractory material properties and performance under gasifier operating conditions. The model is found to be appropriate for first-order estimates of gasifier refractory lifetime when the apparent diffusivity of volatized Cr in the refractory includes the effects of slag-filled pores and cracks.
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Research context

OpenAlex topics: Iron and Steelmaking Processes · Thermochemical Biomass Conversion Processes · Metallurgical Processes and Thermodynamics

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