journal article·2015-06

Oxidation behavior of magnetron sputtered Mo2N/AlN multilayer coatings during heat treatment

Tao Wang, Guojun Zhang, Zhuanning Liu, Bailing Jiang

Ceramics International· Volume 41· Issue 5
Publisher page

Abstract

Abstract The Mo 2 N/AlN multilayer coatings with AlN layer thickness in the range of 0.5 nm to 3.7 nm were deposited by dc magnetron sputtering. The Mo 2 N/AlN multilayer coatings exhibited columnar growth structure. As the AlN layers’ thickness exceeds 1.2 nm, AlN layers changed from fcc structure to amorphous structure, which breaks off the crystallization integrity of multilayer coatings. The coatings oxidized at 400 °C, 550 °C, 700 °C in air for 1 h were investigated by X-ray diffractions (XRD), X-ray photoelectron spectroscopy (XPS) and Scanning electron microscopy (SEM). It was found that with the increase of AlN layer thickness, the oxidation resistance of Mo 2 N/AlN multilayer coatings was improved by reducing the density of columnar grain boundaries and forming dense Al 2 O 3 oxide layer on the surface. The addition of AlN to Mo 2 N coatings also leads to the lower coefficient of friction (0.36–0.42) of Mo 2 N/AlN multilayer coatings than that (0.62) of Mo 2 N coatings.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metal and Thin Film Mechanics · MXene and MAX Phase Materials · Semiconductor materials and devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (23)

Show source-provided references
1. Effects of Al target power on the mechanical and oxidation resistance of the CrN/AlN multilayer coatings10.1016/j.surfcoat.2008.06.146 ↗
2. A study of the oxidation behavior of CrN and CrAlN thin films in air using DSC and TGA analyses10.1016/j.surfcoat.2007.11.037 ↗
3. Oxidation and wear behaviors of Ti-based thin films10.1016/j.surfcoat.2006.08.026 ↗
4. Tribology and oxidation behavior of TiN/AlN nano-multilayer films10.1016/j.triboint.2005.02.015 ↗
5. Surf. Coat. Technol.
6. Advantages of using self-lubricating, hard, wear-resistant MoS2-based coatings10.1016/S0257-8972(01)01108-2 ↗
7. Microstructural design of hard coatings10.1016/j.pmatsci.2006.02.002 ↗
8. Magnéli phase formation of PVD Mo–N and W–N coatings10.1016/j.surfcoat.2006.07.067 ↗
9. Phase composition and tribological performance of molybdenum nitride coatings synthesized by IBAD10.1016/j.surfcoat.2012.06.032 ↗
10. Characterization of Mo–Al–N nanocrystalline films synthesized by reactive magnetron sputtering10.1016/j.materresbull.2008.03.029 ↗
11. Microstructure, oxidation resistance, mechanical and tribological properties of MoeAleN films by reactive magnetron sputtering10.1016/j.vacuum.2013.11.013 ↗
12. Nano-structured CrN/AlN multilayer coatings synthesized by pulsed closed field unbalanced magnetron sputtering10.1016/j.surfcoat.2009.04.013 ↗
13. SiNx thickness dependent morphology and mechanical properties of CrAlN/SiNx nanomultilayers10.1016/j.tsf.2013.02.049 ↗
14. Crystallization of amorphous AlN and superhardness effect in VC/AlN nanomultilayers10.1016/j.tsf.2011.09.079 ↗
15. A. Madan, I.W. Kim, S.C. Cheng, P. Yashar, V.P. Dravid, S.A. Barnett. Stabilization of cubic Al in epitaxial AlN/TiN superlattices, Phys. Rev. Lett. 78 (1997) 1743.10.1103/PhysRevLett.78.1743 ↗
16. Oxidation behavior of molybdenum nitride coatings10.1016/S0257-8972(03)00702-3 ↗
17. Trethewey · 1995
18. Oxidation of arc-evaporated Al1−xCrxN coatings10.1116/1.2738492 ↗
19. Microstructural evolution during film growth10.1116/1.1601610 ↗
20. XPS analysisi of AlN thin films deposited by plasma enhanced atomic layer deposition10.1016/j.apsusc.2014.07.105 ↗
21. Growth and characterization of chloronitroalniline crystals for optical parametric oscillators I. XPS study of Mo-based compounds10.1016/S0169-4332(99)00293-7 ↗
22. NIST-JANAF thermochemical tables, fourth edition
23. Tribology of thin coatings10.1016/S0272-8842(00)00015-8 ↗