journal article·2014-09

Zeolite decorated highly porous acicular calcium silicate ceramics

Cekdar Vakifahmetoglu

Ceramics International· Volume 40· Issue 8
Publisher page

Abstract

Abstract Macrocellular calcium silicate (wollastonite) ceramic foams possessing ~86 vol% total porosity were produced from commercial calcium silicate hydrate (xonotlite) nano-size acicular crystals and poly-methyl-methacrylate microbeads (PMMA) (used as sacrificial pore formers). Open cell wollastonite foams had a bi-modal pore size distribution with major modes located ~100 nm due to interparticle porosity and ~100 µm due to the sacrificial pore former. These macrocellular ceramics were then used as a scaffold for MFI type zeolite (silicalite-1) synthesis. Monolayer coffin shaped zeolite crystals (~3 µm size, measured from the c-axis and ~300 nm thickness) were observed with almost full coverage on the inner macro-cell walls. The specific surface area of the components increased from 9.6 m2/g to 108.2 m2/g via zeolite functionalization, leading to components possessing multiscale porosity.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Zeolite Catalysis and Synthesis · Mesoporous Materials and Catalysis · Concrete and Cement Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Fabrication of ceramic components with hierarchical porosity10.1007/s10853-010-4708-9 ↗
2. Endo- and exotemplating to create high-surface-area inorganic materials10.1002/anie.200300593 ↗
3. Zeolitic materials with hierarchical porous structures10.1002/adma.201100462 ↗
4. Zeolite coatings on microcellular ceramic foams: a novel route to microreactor and microseparator devices10.1002/adma.200306304 ↗
5. Biomorphic ceramics as porous supports for zeolite coating10.4028/www.scientific.net/AST.45.819 ↗
6. Bioinspired Rattan-derived SiSiC/zeolite monoliths: preparation and characterisation10.1016/j.micromeso.2005.10.049 ↗
7. Hierarchical pore ZSM-5 zeolite structures: from micro- to macro-engineering of structured catalysts10.1016/j.cej.2009.09.041 ↗
8. Hydrothermal transformation of porous glass granules into ZSM-5 granules10.1016/j.micromeso.2004.06.029 ↗
9. Formation of a Y-type zeolite membrane on a porous α-alumina tube for gas separation10.1021/ie960519x ↗
10. ZSM-5 coatings on β-SiC monoliths: possible new structured catalyst for the methanol-to-olefins process10.1021/jp067535k ↗
11. Zeolite covered polymer derived ceramic foams: novel hierarchical pore systems for sorption and catalysis10.1179/174367605225011016 ↗
12. Microwave-assisted preparation of Ca6Si6O17(OH)(2) and beta-CaSiO3 nanobelts10.1016/j.materresbull.2009.10.006 ↗
13. Hydrothermal synthesis of xonotlite from carbide slag10.1016/j.pnsc.2008.01.036 ↗
14. Structure, bonding and morphology of hydrothermally synthesised xonotlite10.1179/174367608X353638 ↗
15. Hydrothermal processing of xonotlite based compositions10.1179/174367607X228124 ↗
16. The calcium silicate hydrates10.1016/j.cemconres.2007.11.005 ↗
17. Effect of hydrothermal process on xonotlite crystal10.4028/www.scientific.net/AMR.382.379 ↗
18. A simple method to synthesize single-crystalline beta-wollastonite nanowires10.1016/j.jcrysgro.2006.11.215 ↗
19. Synthesis of wollastonite nanowires via hydrothermal microemulsion methods10.1016/j.matlet.2006.02.034 ↗
20. Synthesis of wollastonite single crystal nanowires by a novel hydrothermal route10.1246/cl.2004.1458 ↗
21. Preparation of porous wollastonite ceramics for filtration10.4028/www.scientific.net/KEM.336-338.1102 ↗
22. Preparation of macroporous calcium silicate ceramics10.1016/j.matlet.2004.01.008 ↗
23. Low-temperature fabrication of macroporous scaffolds through foaming and hydration of tricalcium silicate paste and their bioactivity10.1007/s10853-009-4026-2 ↗
24. Hydrothermal processing of xonotlite based compositions10.1179/174367607X228124 ↗
25. The dehydration of xonotlite10.1107/S0365110X56002916 ↗
26. Structure of calcium silicate hydrate (C-S-H): near-, mid-, and far-infrared spectroscopy10.1111/j.1151-2916.1999.tb01826.x ↗
27. Structural characterization of gel-derived calcium silicate systems10.1021/jp1053502 ↗
28. Hydrothermal synthesis of size-controlled silicalite-1 crystals10.1007/s10934-010-9404-2 ↗
29. Silicalite, a new hydrophobic crystalline silica molecular sieve10.1038/271512a0 ↗
30. Functional silica monoliths with hierarchical uniform porosity as continuous flow catalytic reactors10.1016/j.micromeso.2010.10.044 ↗
31. Size-dependent properties of nanocrystalline silicalite synthesized with systematically varied crystal sizes10.1021/la049817m ↗
32. Fabrication of hollow zeolite microcapsules with tailored shapes and functionalized interiors10.1016/S1387-1811(03)00484-0 ↗
33. Novel open cell aluminum foams and their use as reactive support for zeolite crystallization10.1007/s10934-010-9359-3 ↗
34. Preparation and characterization of ceramic foam supported nanocrystalline zeolite catalysts10.1016/S0920-5861(01)00387-X ↗
35. Washcoating of different zeolites on cordierite monoliths10.1111/j.1551-2916.2007.02032.x ↗