journal article·2014-07

Electrical properties of SiC ceramics sintered with 0.5wt% AlN–RE2O3 (RE=Y, Nd, Lu)

Kwang-Young Lim, Young-Wook Kim, Kwang Joo Kim

Ceramics International· Volume 40· Issue 6
Publisher page

Abstract

Abstract Silicon carbide ceramics with 0.5 wt% AlN–RE 2 O 3 (RE=Y, Nd, Lu) additives were prepared by hot-pressing the powder mixtures at 2050 °C for 6 h under an applied pressure of 40 MPa in a nitrogen atmosphere. The effects of additive composition on the sinterability, microstructure, and electrical properties of hot-pressed liquid-phase sintered (LPS)-SiC ceramics were investigated. It was found that all specimens could be sintered to >95% of the theoretical density by adding 5 wt% in situ -synthesized nano-sized SiC and 0.5 wt% AlN–RE 2 O 3 additives. SiC ceramics sintered with AlN–Y 2 O 3 and AlN–Nd 2 O 3 showed low electrical resistivity on the order of 10 −2 Ω cm. This low electrical resistivity was attributed to the growth of nitrogen-doped SiC grains and the confinement of non-conducting RE-containing phases in the junction areas. The electrical resistivity of LPS-SiC ceramics sintered with AlN–RE 2 O 3 was dependent on the chemistry of the additive composition.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced ceramic materials synthesis · Aluminum Alloys Composites Properties · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (36)

Show source-provided references
1. Oxidation and burner rig corrosion of liquid phase sintered SiC10.1016/S0955-2219(99)00160-0 ↗
2. Flexural strength and toughness of liquid phase sintered silicon carbide10.1016/S0272-8842(99)00084-X ↗
3. Effects of additives on densification, microstructure and properties of liquid-phase sintered silicon carbide10.1023/A:1004881430804 ↗
4. High-purity semi-insulating 4H–SiC for microwave device applications10.1007/s11664-003-0173-4 ↗
5. Preparation of dense nanocrystalline silicon carbide ceramics by sinter forging in the presence of a liquid phase10.1002/adem.200500009 ↗
6. Mechanical properties of hot-forged silicon carbide ceramics10.1016/j.scriptamat.2004.09.012 ↗
7. Effect of AlN-content on the microstructure and fracture toughness of hot-pressed and heat-treated LPS-SiC ceramics10.1016/j.jeurceramsoc.2004.01.024 ↗
8. Densification of liquid phase sintered silicon carbide10.1016/j.jeurceramsoc.2005.03.253 ↗
9. Influence of small amount of sintering additives on unlubricated sliding wear properties of SiC ceramics10.1016/j.ceramint.2011.06.018 ↗
10. The effects of nanoparticle addition on the densification and properties of SiC10.1016/j.ceramint.2012.03.049 ↗
11. Microstructural evolution and contact-mechanical properties of SiC ceramics prepared colloidally with low additive content10.1016/j.ceramint.2012.04.051 ↗
12. Mechanical properties of nanostructured silicon carbide consolidated by spark plasma sintering10.1016/j.jeurceramsoc.2012.07.030 ↗
13. Consolidation of nanostructured β-SiC by spark plasma sintering10.1111/j.1551-2916.2004.01436.x ↗
14. Densification of additive-free polycrystalline β-SiC by spark-plasma sintering10.1016/j.ceramint.2011.06.036 ↗
15. Processing of nano-SiC ceramics: Densification by SPS and mechanical characterization10.1016/j.jeurceramsoc.2011.10.006 ↗
16. Fabrication of highly dense pure SiC ceramics via the HTPVT method10.1016/j.actamat.2011.06.035 ↗
17. Processing of high performance silicon carbide10.2109/jcersj2.116.665 ↗
18. Electrical resistivity of silicon carbide ceramics sintered with 1wt% aluminum nitride and rare earth oxide10.1016/j.jeurceramsoc.2012.07.021 ↗
19. Variation of aluminum concentration in β´-sialon grains formed during liquid-phase sintering of Si3N4–Al2O3–Nd2O310.1007/BF01154942 ↗
20. Thermal conductivity of β-Si3N4: III, Effect of rare-earth (RE=La, Nd, Gd, Y, Yb, and Sc) oxide additives10.1111/j.1151-2916.2001.tb00662.x ↗
21. Effect of in situ-synthesized nano-size SiC addition on density and electrical resistivity of liquid-phase sintered silicon carbide ceramics10.2109/jcersj2.119.965 ↗
22. Structural and optical chracteristics of crystalline silicon carbide nanoparticles synthesized by carbothermal reduction10.1111/j.1551-2916.2008.02913.x ↗
23. Effects of the initial α-SiC content on the microstructure, mechanical properties, and permeability of macroporous silicon carbide ceramics10.1016/j.jeurceramsoc.2011.11.040 ↗
24. High-temperature strength of silicon carbide ceramics sintered with rare-earth oxide and aluminum nitride10.1016/j.actamat.2006.08.059 ↗
25. High temperature strength of silicon carbide sintered with 1wt% aluminum nitride and lutetium oxide10.1016/j.jeurceramsoc.2012.09.005 ↗
26. Solid solubility of aluminum and boron in silicon carbide10.1111/j.1151-2916.1982.tb10375.x ↗
27. Electrodischarge-machinable silicon carbide ceramics sintered with yttrium nitrate10.1111/j.1551-2916.2011.04419.x ↗
28. Temperature dependence of the electrical properties and seebeck coefficient of AlN–SiC ceramics10.1111/j.1551-2916.2005.00837.x ↗
29. Influence of Y2O3 addition on electrical properties of β-SiC ceramics sintered in nitrogen atmosphere10.1016/j.jeurceramsoc.2012.07.001 ↗
30. Effective nitrogen doping for fabricating highly conductive β-SiC ceramics10.1111/j.1551-2916.2011.04799.x ↗
31. Temperature dependence of electrical resistivity (4–300K) in aluminum- and boron-doped SiC ceramics10.1111/jace.12351 ↗
32. Interface characteristics affecting electrical properties of Y-doped SiC10.1557/JMR.2003.0365 ↗
33. Thermal and electrical properties in plasma-activation-sintered silicon carbide with rare-earth-oxide additives10.1111/j.1151-2916.2001.tb01033.x ↗
34. Relationships between microstructure and electrical properties of liquid-phase sintered silicon carbide materials using impedance spectroscopy10.1016/j.jeurceramsoc.2006.05.053 ↗
35. Compositional effects on the properties of Si–Al–RE-based oxynitride glasses (RE=La, Nd, Gd, Y, or Lu)10.1111/j.1151-2916.2002.tb00189.x ↗
36. Control of electrical resistivity in silicon carbide ceramics sintered with aluminum nitride and yttria10.1111/jace.12498 ↗