journal article·2012-12

Preparation of SiC nanowires-filled cellular SiCO ceramics from polymeric precursor

Jian-mei Pan, Xue-hua Yan, Xiao-nong Cheng, Qing-bo Lu, Ming-song Wang, Cheng-hua Zhang

Ceramics International· Volume 38· Issue 8
Publisher page

Abstract

Abstract SiC nanowires-filled cellular SiCO ceramics were prepared using polyurethane sponge as a porous template infiltrated with silicone resin by pyrolysis at 1400 °C under Ar atmosphere. The pyrolysis temperature was an important parameter affecting the formation of SiC nanowires. The as-prepared sample obtained at 1000 °C was composed of SiCO glasses and turbostratic carbon. The SiCO ceramic was further converted into SiO 2 crystals and amorphous carbon by pyrolysis at 1200 °C. With the increasing pyrolysis temperature, SiC nanocrystals embedded in the non-crystalline SiCO matrix were observed. Furthermore, the SiC nanowires were formed in the pores of the SiCO ceramic. The diameters of the SiC nanowires are in the range 80–150 nm and the lengths are up to several tens of micrometers. The growth mechanism of the nanowires was supported by the vapor-solid mechanism.
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Research context

OpenAlex topics: Advanced ceramic materials synthesis · Carbon Nanotubes in Composites · Diamond and Carbon-based Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (36)

Show source-provided references
1. Highly porous macro- and micro-cellular ceramics from a polysilazane precursor10.1016/j.ceramint.2009.05.022 ↗
2. Laminated biomorphous SiC/Si porous ceramics made from wood veneer10.1016/j.matdes.2011.05.004 ↗
3. Engineering porosity in polymer-derived ceramics10.1016/j.jeurceramsoc.2007.12.002 ↗
4. Silicon oxycarbide glasses for blood-contact applications10.1016/j.actbio.2005.05.005 ↗
5. Polymerderived microcellular SiOC foams with magnetic functionality10.1007/s10853-007-2224-3 ↗
6. Conductive ceramic foams from preceramic polymers10.1111/j.1151-2916.2001.tb01000.x ↗
7. Polymer-derived Si-based bulk ceramics, Part I: preparation, processing and properties10.1016/0955-2219(95)00041-R ↗
8. Polymer-derived Si-based bulk ceramics, Part II: microstructural characterisation by electron spectroscopic imaging10.1016/0955-2219(95)00029-T ↗
9. Crystallization maps for SiCO amorphous ceramics10.1111/j.1551-2916.2006.01423.x ↗
10. Processing and properties of polysiloxane-derived porous silicone carbide ceramics using hollow microspheres as templates10.1016/j.jeurceramsoc.2007.09.009 ↗
11. Interfacial SiC formation in polysiloxane-derived Si–O–C ceramics10.1016/S0254-0584(01)00395-9 ↗
12. Processing of polysiloxane-derived porous ceramics: a review10.1088/1468-6996/11/4/044303 ↗
13. Macro- and micro-cellular porous ceramics from preceramic polymers10.1016/S0266-3538(03)00268-9 ↗
14. SiOC ceramic foams synthesized from electron beam irradiated methylsilicone resin10.1007/s10853-008-2654-6 ↗
15. Biomorphous SiOC/C-ceramic composites from chemically modified wood templates10.1016/S0955-2219(03)00202-4 ↗
16. Mechanical properties of silicon oxycarbide ceramic foams10.1111/j.1151-2916.2001.tb00996.x ↗
17. Silicon oxycarbide ceramic foams from a preceramic polymer10.1111/j.1151-2916.1999.tb01803.x ↗
18. Novel microcellular ceramics from a silicone resin10.1111/j.1551-2916.2004.00152.x ↗
19. Preparation of silicone carbide foams using polymeric precursor solutions10.1023/A:1004805023228 ↗
20. Porosity and strength of silicon carbide foams prepared using preceramic polymers10.1023/A:1020834509443 ↗
21. Preparation of silicon carbide-silicon nitride composite foams from pre-ceramic polymers10.1016/S0955-2219(00)00046-7 ↗
22. Macroporous silicon carbide foams for porous burner applications and catalyst supports10.1016/j.jpcs.2006.12.008 ↗
23. Nanobeam mechanics: elasticity, strength and toughness of nanorods and nanotubes10.1126/science.277.5334.1971 ↗
24. Field emission characteristics of SiC nanowires prepared by chemical vapour deposition10.1063/1.125189 ↗
25. High-temperature stability of silicon carbide nanowires10.1166/jnn.2008.452 ↗
26. The effect of whisker orientation in SiC whisker-reinforced Si3N4 ceramic matrix composites10.1016/S0955-2219(98)00289-1 ↗
27. Chemical vapor deposition of C on SiO2 and subsequent carbothermal reduction for the synthesis of nanocrystalline SiC particles/nanowires10.1016/j.ijrmhm.2011.03.005 ↗
28. Formation of SiC nanowires from raw rice husks in argon atmosphere10.1016/0272-8842(95)00084-4 ↗
29. Production of SiC and Si3N4 nanowires in C + SiO2 solid mixtures10.1016/S0254-0584(01)00332-7 ↗
30. Microstructure and growth mechanism of SiC nanowires on carbon/carbon composites prepared by CVD10.1016/j.matlet.2005.02.088 ↗
31. A new synthesis method for producing Si3N4 nanowires by heat treating porous Si objects10.1111/j.1551-2916.2008.02721.x ↗
32. In situ synthesis of porous silicone carbide (SiC) ceramics decorated with SiC nanowires10.1111/j.1551-2916.2007.02037.x ↗
33. Synthesis and structural characterization of carbon-rich SiCxOy derived from a Ni-containing hybrid polymer10.1016/j.jeurceramsoc.2008.03.001 ↗
34. Phase separation in an SiCO glass studied by transmission electron microscopy and electron energy-loss spectroscopy10.1111/j.1151-2916.2001.tb00792.x ↗
35. Synthesis of silicon carbide nanopowder using silica fume10.1111/j.1551-2916.2010.03867.x ↗
36. Crystal growth of SiC whisker from the SiO(g)–CO System10.1007/BF00728713 ↗