journal article·2016-11

Consolidation and grain growth of tantalum diboride during spark plasma sintering

Dmytro Demirskyi, Oleg Vasylkiv

Ceramics International· Volume 42· Issue 14
Publisher page

Abstract

Bulk tantalum diboride ceramics have been consolidated by spark plasma sintering (SPS) at 1700–2200 °C using moderate pressure of 30 MPa. The effect of temperature and dwell time on the densification, microstructure and mechanical properties were investigated. SPS resulted in dense, crack-free specimens with strength ranging from 280 to 550 MPa. The room-temperature strength of TaB2 ceramics was analyzed as a function of the grain size. Activation energy for the grain growth process was estimated as 1078±31 kJ mol−1.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced ceramic materials synthesis · Advanced materials and composites · MXene and MAX Phase Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Hard compounds of refractory metals, Moscow
2. Bulk monolithic zirconium and tantalum diborides by reactive and non-reactive spark plasma sintering10.1016/j.jallcom.2015.12.096 ↗
3. Synthesis, densification, and mechanical properties of TaB210.1016/j.matlet.2008.06.052 ↗
4. Consolidation of B4C–TaB2 eutectic ceramics composites by spark plasma sintering10.1016/j.jascer.2015.08.001 ↗
5. High-strength B4C–TaB2 eutectic composites obtained via in situ by spark plasma sintering10.1111/jace.14235 ↗
6. High-temperature reaction consolidation of TaC–TiB2 ceramic composites by spark-plasma sintering10.1016/j.jeurceramsoc.2014.08.007 ↗
7. High-strength TiB2–TaC ceramic composites prepared using reactive spark plasma consolidation10.1016/j.ceramint.2015.09.065 ↗
8. TaB2-based ceramics: Microstructure, mechanical properties and oxidation resistance10.1016/j.jeurceramsoc.2011.07.032 ↗
9. Synthesis, processing and properties of TaC-TaB2-C ceramics10.1016/j.jeurceramsoc.2010.01.032 ↗
10. Effect of SiC, TaB2 and TaSi2 additives on the isothermal oxidation resistance of fully dense zirconium diboride10.1557/jmr.2009.0216 ↗
11. Oxidation Resistance of Fully Dense ZrB2 with SiC, TaB2, and TaSi2 Additives10.1111/j.1551-2916.2008.02368.x ↗
12. Elliot · 1967 · 565
13. Sintering and properties of titanium diboride made from powder synthesized in a plasma-arc heater10.1111/j.1151-2916.1984.tb19744.x ↗
14. The sintering of combustion-synthesized titanium diboride10.1007/BF01132409 ↗
15. Tough ceramics by microwave sintering of nanocrystalline titanium diboride ceramics10.1016/j.ceramint.2013.07.010 ↗
16. Densification and grain growth during microwave sintering of titanium diboride10.1016/j.scriptamat.2013.07.012 ↗
17. The mechanism of shrinkage of zirconium diboride during sintering10.1007/BF00775860 ↗
18. Sintering mechanisms and kinetics for reaction hot pressed ZrB210.1111/jace.13544 ↗
19. Densification mechanisms in high-pressure hot-pressing of HfB210.1111/j.1151-2916.1969.tb12654.x ↗
20. Hardness and toughness control of brittle boron suboxide ceramics by consolidation of star-shaped particles by spark plasma sintering10.1016/j.ceramint.2015.10.157 ↗
21. High-Temperature strength of boron suboxide ceramic consolidated by spark plasma sintering10.1111/jace.14308 ↗
22. In situ fabrication of B4C–NbB2 eutectic composites by spark–plasma sintering10.1111/jace.13083 ↗
23. Fabrication, microstructure and properties of in situ synthesized B4C–NbB2 eutectic composites by spark plasma sintering10.2109/jcersj2.123.33 ↗
24. Peculiarities of the neck growth process during initial stage of spark-plasma, microwave and conventional sintering of WC spheres10.1016/j.jallcom.2012.01.146 ↗
25. A scaling law study of the initial stage of microwave sintering of iron spheres10.1016/j.scriptamat.2011.11.017 ↗
26. Kang · 2005
27. Touloukian · 1977 · 13
28. Thermal expansion studies on the group IV-VII transition metal diborides10.1016/0022-5088(88)90219-6 ↗
29. Self-diffusion of boron in TiB210.1063/1.1530715 ↗
30. Mechanical properties of ZrB2- and HfB2-based ultra-high temperature ceramics fabricated by spark plasma sintering10.1016/j.jeurceramsoc.2012.12.009 ↗