journal article·2021-01

Estimating the density and molar volume of ferrite-based ternary molten slags by geometrical model

Zhigang Yu, Jieyu Zhang, Haiyan Leng, Xiaochun Wu, Kuo-Chih Chou

Ceramics International· Volume 47· Issue 1
Publisher page

Abstract

Abstract Ferrite-based slags are the basic systems in the pyrometallurgical production of copper, and the density and molar volume of these systems are of vital importance for optimizing the metallurgical process. However, due to the high melting points of melts and the expensive trial costs, experimental methods are inefficient to obtain all the data needed. As a result, a geometrical model has been applied to the estimation of density and molar volume of ferrite-based ternary slags. The calculated results agree well with experimental data in three ferrite-based ternary systems of Fe2O3–CaO–FeO, Fe2O3–BaO–FeO and Fe2O3–CaO–Cu2O. The mean deviation of the predicted results by the present model is lower than those by various empirical models for corresponding systems. The application of the present will enrich the data of density and molar volume for more ternary melts.
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Research context

OpenAlex topics: Metallurgical Processes and Thermodynamics · Iron and Steelmaking Processes · Aluminum Alloy Microstructure Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (51)

Show source-provided references
1. The recovery of copper, by flotation, from calcium-ferrite-based slags made in continuous pilot plant smelting trials10.1016/j.mineng.2003.12.004 ↗
2. Cleaning of a copper matte smelting slag from a water-jacket furnace by direct reduction of heavy metals10.1016/j.jhazmat.2008.08.107 ↗
3. Density and Young׳s Modulus of ternary glasses close to the eutectic composition in the CaO-Al2O3-SiO2 -system10.1016/j.ceramint.2015.12.123 ↗
4. Relationship between thermophysical properties and structure of CMAS glass melts based on chromium slag10.1088/2053-1591/ab6e30 ↗
5. A density estimation model for molten silicate slags10.1515/HTMP.2007.26.5-6.341 ↗
6. Calculation for density of molten slags using optical basicity10.1179/1743281212Y.0000000083 ↗
7. Influence of alloying elements on the structural stability, elastic, hardness and thermodynamic properties of Mo5SiB2 from first-principles calculations10.1016/j.ceramint.2020.03.233 ↗
8. A study of ternary geometrical models10.1002/bbpc.19890930615 ↗
9. Application of phenomenological theory to chemical metallurgy10.2355/isijinternational.ISIJINT-2018-120 ↗
10. General formalism for new generation geometrical model: Application to the thermodynamics of liquid mixtures10.1007/s10953-010-9570-5 ↗
11. A general representation of geometrical solution model for predicting ternary thermodynamic properties
12. Estimating the excess molar volume using the new generation geometric model10.1016/j.fluid.2009.07.024 ↗
13. Molar volume calculation of Ga-Bi-X( X=Sn, In) liquid alloys using the general solution model10.3139/146.110381 ↗
14. Excess molar volume and viscosity study of ternary mixtures of tert-butylmethylether and n-heptane with alcohols at 293.15 K
15. A comparison of different geometrical models in calculating physicochemical properties of quaternary systems10.1016/j.calphad.2010.10.004 ↗
16. Calculation of density in a ternary system with a limited homogenous region using a geometric model10.1016/j.calphad.2005.05.003 ↗
17. Surface tension and density of liquid Sn-Ag-Cu alloys10.3139/146.110819 ↗
18. Measuring and modeling of density for selected CaO-MgO-Al2O3-SiO2 slag with low Silica10.1016/S1006-706X(12)60109-5 ↗
19. Comparison of different calculation methods of the new generation geometric model in predicting the density of NaCl-MgCl2-CaCl2 systems10.1007/s10953-014-0147-6 ↗
20. Surface tension and density of liquid Bi-Pb, Bi-Sn and Bi-Pb-Sn eutectic alloys10.1016/j.susc.2011.02.026 ↗
21. Estimation of various properties of CaO-“FeO”-SiO2 system at 1,673 K by mass triangle model
22. Electrical conductivity of CaCl2-KCl-NaCl system at 1080 K, Thermochim
23. Ternary Bi-Cu-Ni alloys–thermodynamics, characterization, mechanical and electrical properties
24. Estimating sulfide capacities for ternary systems with limited solubility10.2298/JMMB111201025W ↗
25. Geometric modelling of viscosity of copper-containing liquid alloys10.1080/14786435.2015.1133938 ↗
26. Thermophysical properties of Cu-In-Sn liquid Pb-free alloys: viscosity and surface tension10.1080/14786435.2017.1392053 ↗
27. Evaluation model for viscosity of Fe-Ni-Cr alloys using Gibbs free energy of mixing and geometric methods10.2355/isijinternational.ISIJINT-2016-215 ↗
28. An optimal method to calculate the viscosity of simple liquid ternary alloys from the measured binary data10.1016/j.calphad.2005.08.002 ↗
29. Ternary Au-Ga-Sb system: calculation of thermodynamic properties using general solution model10.1007/s12598-015-0456-y ↗
30. Thermodynamic analysis and characterization of Bi-Cu-Sn alloys as advanced lead-free solder materials for high temperature application10.1007/s10854-010-0272-y ↗
31. Surface tension modelling of liquid Cd-Sn-Zn alloys10.1080/14786435.2018.1448124 ↗
32. Prediction of thermodynamic properties associated with six component alloys, Pb-free quaternary and ternary alloys
33. A general solution model for predicting ternary thermodynamic properties10.1016/0364-5916(95)00029-E ↗
34. Empirical methods of predicting and representing thermodynamic properties of ternary solution phases10.1016/0364-5916(80)90016-4 ↗
35. Estimation of the thermodynamic data for a ternary system from the corresponding binary systems10.1007/BF00899814 ↗
36. Enthalpies of formation of liquid alloy bismuth-gallium-tin at 723 K. Choice of an analytical representation of integral and partial excess functions of mixing10.1051/jcp/1975720083 ↗
37. Predicting ternary activities using binary data
38. A new solution model for predicting ternary thermodynamic properties10.1016/0364-5916(87)90048-4 ↗
39. Interpolation algorithms for thermodynamic functions of mixtures in multicomponent systems from binary boundary systems
40. Calculation of physicochemical properties in a ternary system with miscibility gap10.1007/s11663-004-0011-y ↗
41. Calculation of the physicochemical properties for ternary solution with limited solubility10.1016/j.ceramint.2018.08.099 ↗
42. Computational study on various properties of CaO-Al2O3-SiO2 mold flux10.1016/j.ceramint.2018.12.225 ↗
43. Geometrical modelling of the physicochemical properties of CaO-Al2O3-CaF2 slag at 1873K10.1016/j.ceramint.2019.12.033 ↗
44. An insight into the viscosity prediction of ternary alloys with limited solubility10.1080/14786435.2019.1630762 ↗
45. Determination of viscosity and surface tension for CaO-SiO2-CaF2 slags10.1007/s10953-020-00998-w ↗
46. Evaluation of carbide capacity in CaO-based ternary systems at 1773K for refining process10.2298/JMMB190110054Y ↗
47. PANDAT software with PanEngine, PanOptimizer and PanPrecipitation for multi-component phase diagram calculation and materials property simulation10.1016/j.calphad.2008.08.004 ↗
48. Density and surface tension of the systems CaO-FeO-Fe2O3-MgO, CaO-FeO-Fe2O3-ZnO and CaO-Fe2O3-Cu2O
49. Densities of melts in the FeO-Fe2O3-BaO system10.2320/matertrans1960.29.990 ↗
50. Densities of melts in the FeO-Fe2O3-CaO and FeO-Fe2O3-2CaO·SiO2 systems10.2320/matertrans1960.29.977 ↗
51. New insights into ternary geometrical models for material design10.1016/j.matdes.2020.108778 ↗