journal article·2015-08

Morphology and luminescence properties of ZnO micro/nanostructures synthesized via thermal evaporation of Zn–Mg mixtures

Geun-Hyoung Lee

Ceramics International· Volume 41· Issue 7
Publisher page

Abstract

Abstract ZnO crystals with various morphologies were synthesized by thermal evaporation of Zn/Mg mixtures under air atmosphere. When Zn powder was used as a source material, ZnO crystals had a tetrapod morphology. Depending on the mass ratio of Mg to Zn in the source material, ZnO crystals were synthesized having wires, tubes and grain-like morphologies. This provides strong evidence that Mg had an important effect on the morphology of the ZnO crystals and that the ratio of Mg to Zn is critical to the changes in morphology of the ZnO crystals. All the ZnO crystals had a wurtzite crystallographic structure. The possible role of Mg in the growth of the tubular-shaped ZnO crystals was discussed. Two emission peaks at around 380 (ultraviolet) and 510 nm (green) were observed in the cathodoluminescence spectra. A high intensity ratio of ultraviolet emission to green emission was observed for the tubular-shaped ZnO crystals, indicating the high crystalline quality of the ZnO crystals.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: ZnO doping and properties · Ga2O3 and related materials · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (18)

Show source-provided references
1. Ultraviolet light emitting diode based on p-NiO/n-ZnO nanowire heterojunction10.1016/j.jcrysgro.2012.10.037 ↗
2. Synthesis of multi-dimensional ZnO nanostructures in aqueous medium for the application of gas sensor10.1016/j.snb.2012.11.100 ↗
3. Fabrication of hierarchical ZnO nanostructures for dye-sensitized solar cells10.1016/j.electacta.2012.06.022 ↗
4. Sensing devices based on ZnO hexagonal tube-like nanostructures grown on p-GaN heterojunction by wet thermal evaporation10.1016/j.tsf.2013.05.091 ↗
5. Hydrothermal synthesis of tubular ZnO materials10.1016/j.matlet.2011.10.036 ↗
6. Sol–gel template synthesis of ZnO nanotubes and its coaxial nanocomposites of LiMn2O4/ZnO10.1016/j.msea.2006.05.059 ↗
7. A general low-temperature route for large-scale fabrication of highly oriented ZnO nanorod/nanotube arrays10.1021/ja043121y ↗
8. Semiconductor nanowires and nanotubes10.1146/annurev.matsci.34.040203.112300 ↗
9. Direct Observation of vapor–liquid–solid nanowire growth10.1021/ja0059084 ↗
10. Optimal Zn/O ratio in vapor phase for the synthesis of high ZnO tetrapod nanocrystals via thermal evaporation of Zn in air10.1016/j.apsusc.2012.04.183 ↗
11. Study of the role of Mg and Zn in the directive oxidation of Al alloys10.1023/A:1026451708175 ↗
12. Changing the shape of ZnO nanostructures by controllong oxygen concentration: from terapod-like to dandelion-like nanostructures10.1080/10584587.2011.575727 ↗
13. Low temperature growth and photoluminescence of well-aligned zinc oxide nanowires10.1016/S0009-2614(02)01145-4 ↗
14. Correlation between photoluminescence and oxygen vacancies in ZnO phosphors10.1063/1.116699 ↗
15. Thermal evaporation synthesis and properties of ZnO nano/microstructures using carbon group elements as the reducing agents10.1007/s11671-010-9524-2 ↗
16. Preparation and optical properties of Mg-doped ZnO nanorods10.1016/j.apsusc.2014.08.110 ↗
17. Growth mechanism and growth habit of oxide crystals10.1016/S0022-0248(99)00076-7 ↗
18. Fabrication of ZnO microtube arrays via vapor phase growth10.1016/j.matlet.2007.09.015 ↗