journal article·2024-11Open access

Improved oxidation and ablation resistance of SiCf/SiC-HfB2 composites: Role of oxygen-blocking scale and protection mechanism

Ruru Guo, Lu Li, Zhijian Li, Ruixiao Zheng, Chaoli Ma

Ceramics International· Volume 50· Issue 22

Abstract

To improve the oxidation and ablation resistance of SiC f /SiC composites, the as-synthesized ultrafine HfB 2 powder was used as the modification phase to fabricate SiC f /SiC-HfB 2 composites, and their oxidation and ablation behaviors were investigated. Compared with the unmodified SiC f /SiC composites, the oxidation resistance at 800–1500 °C and the ultra-high temperature ablation resistance of SiC f /SiC-HfB 2 composites were significantly improved. After oxidation, a compact compound glass scale consisting of HfO 2 , HfSiO 4 and Si-Hf-O glass was formed, providing the effective oxidation protection. A dual-phase oxide scale composed of HfO 2 skeleton and Si-Hf-O glass was formed after ablation, exhibiting the high viscosity, the significant oxygen-blocking effect and resistance to gas flow scouring. The improved oxidation and ablation resistance of SiC f /SiC-HfB 2 composites could be attributed to the effective protective role of oxygen-blocking scales formed during the oxidation and ablation processes .
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Research context

OpenAlex topics: Advanced ceramic materials synthesis · Advanced materials and composites · Aluminum Alloys Composites Properties

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