journal article·2021-01Open access

Environment-friendly preparation of exfoliated graphite and functional graphite sheets

Shiyu Hou, Shuaijie He, Tianle Zhu, Jihui Li, Liqiang Ma, Hongda Du, Wanci Shen, Feiyu Kang, Zheng-Hong Huang

Journal of Materiomics· Volume 7· Issue 1

Abstract

Exfoliated graphite (EG) is promising oil sorbent as well as an intermediate product for the preparation of flexible graphite films (FGFs). It has been a critical challenge to energy conservation and pollution abatement for the traditional EG production technique. Here, we propose a simple and effective preparation method to acquire EG in which flake graphite is intercalated and exfoliated at room temperature, not involving any pollutant emission. The influence factors in the preparation process were explored, such as the amount of H2SO4 and H2O2, the temperature for the preparation of room temperature exfoliated graphite (RTEG). In contrast to the EG by high temperature exfoliation (HTEG), RTEG exhibits a homogeneous structure and a significantly increased volume and surface area. Moreover, EG blocks with high oil sorption capacity and excellent reuse performance can be obtained by RTEG method. Especially, FGFs fabricated by RTEG has high flexibility, thermal conductivity and electrical conductivity. It suggests that this environment-friendly technology is suitable for large-scale industrial implementation of graphite-based oil sorbents and flexible materials.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Fiber-reinforced polymer composites · Advancements in Battery Materials · Graphite, nuclear technology, radiation studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (36)

Show source-provided references
1. Different exfoliated graphite as a base of sealing materials10.1016/j.jpcs.2006.01.048 ↗
2. Flexible graphite for gasketing, adsorption, electromagnetic interference shielding, vibration damping, electrochemical applications, and stress sensing10.1361/105994900770346105 ↗
3. Flexible graphite as a heating element10.1016/S0008-6223(02)00141-0 ↗
4. Controlled partial-exfoliation of graphite foil and integration with MnO2 nanosheets for electrochemical capacitors10.1039/C4NR06559J ↗
5. Flexible graphite as battery anode and current collector10.1016/j.jpowsour.2004.09.009 ↗
6. Exfoliation of graphite into graphene in aqueous solutions of inorganic salts10.1021/ja5017156 ↗
7. Modelling of exfoliated graphite10.1016/j.pmatsci.2004.01.001 ↗
8. High-yield synthesis of few-layer graphene flakes through electrochemical expansion of graphite in propylene carbonate electrolyte10.1021/ja203725d ↗
9. Interlayer catalytic exfoliation realizing scalable production of large-size pristine few-layer graphene10.1038/srep01134 ↗
10. Room-temperature intercalation and similar to 1000-fold chemical expansion for scalable preparation of high-quality graphene10.1021/acs.chemmater.5b05043 ↗
11. One-step room-temperature preparation of expanded graphite10.1016/j.carbon.2017.04.076 ↗
12. Silver nanoparticles-loaded exfoliated graphite and its anti-bacterial performance
13. Compacted exfoliated natural graphite as heat conduction medium10.1016/S0008-6223(01)00032-X ↗
14. The alignment of AlN platelets in polymer matrix and its anisotropic thermal properties10.1016/j.jmat.2019.04.011 ↗
15. Exfoliation of graphite flake and its nanocomposites10.1016/S0008-6223(02)00409-8 ↗
16. Graphene sheets from worm-like exfoliated graphite10.1039/b904093p ↗
17. Synthesis of graphene nano-sheets using eco-friendly chemicals and microwave radiation10.1016/j.carbon.2010.04.034 ↗
18. An asymmetric supercapacitor with ultrahigh energy density based on nickle cobalt sulfide nanocluster anchoring multi-wall carbon nanotubes hybrid10.1016/j.jpowsour.2016.04.066 ↗
19. Influence of modified graphite flakes on the physical, thermo-mechanical and barrier properties of butyl rubber10.1016/j.jallcom.2016.12.232 ↗
20. Facile synthesis of graphene via reduction of graphene oxide by artemisinin in ethanol10.1016/j.jmat.2018.01.002 ↗
21. Interlayer polymerization in chemically expanded graphite for preparation of highly conductive, mechanically strong polymer composites10.1021/acs.chemmater.6b04734 ↗
22. Graphite foam from pitch and expandable graphite10.1016/j.carbon.2014.02.035 ↗
23. Mechanical, electrical, thermal performances and structure characteristics of flexible graphite sheets10.1007/s10853-010-4216-y ↗
24. A novel layered sedimentary rocks structure of the oxygen-enriched carbon for ultrahigh-rate-performance supercapacitors10.1021/acsami.5b12484 ↗
25. N-doped reduced graphene oxide aerogel coated on carboxyl-modified carbon fiber paper for high-performance ionic-liquid supercapacitors10.1016/j.carbon.2015.12.092 ↗
26. The complexity of gene expression dynamics revealed by permutation entropy10.1186/1471-2105-11-607 ↗
27. Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets10.1016/j.carbon.2006.06.004 ↗
28. Comparison of methods for determining specific surface area of soils10.1061/(ASCE)1090-0241(2006)132:7(931) ↗
29. Exfoliated graphite with relative dielectric constant reaching 360, obtained by exfoliation of acid-intercalated graphite flakes without subsequent removal of the residual acidity10.1016/j.carbon.2015.04.042 ↗
30. Towards wastewater treatment: photo-assisted electrochemical degradation of 2-nitrophenol and orange II dye at a tungsten trioxide exfoliated graphite composite electrode10.1016/j.cej.2017.02.084 ↗
31. Preparation of sulfur-free exfoliated graphite by a two-step intercalation process and its application for adsorption of oils
32. Inagaki · 2014
33. A rapid and efficient method to prepare exfoliated graphite by microwave irradiation10.1016/j.carbon.2008.10.013 ↗
34. Review of materials and processing methods used in the production of bipolar plates for fuel cells10.1179/174328006X102556 ↗
35. Flexible graphite as a compliant thermoelectric material10.1016/S0008-6223(01)00260-3 ↗
36. Paraffin/porous-graphite-matrix composite as a high and constant power thermal storage material10.1016/S0017-9310(00)00309-4 ↗