journal article·2020-03Open access

Preparation and characterization of Ce0.8Sm0.2O1.9–La0.8Sr0.2Cr0.5Fe0.5O3-δ dual-phase membranes for oxygen permeation

Guangjun Zhang, Xiaonan Bao, Fanrong Zeng, Nguyen Q. Minh, Shaorong Wang

Journal of Materiomics· Volume 6· Issue 1

Abstract

In this study, with La0.8Sr0.2Cr0.5Fe0.5O3-δ (LSCrF) and Ce0.8Sm0.2O1.9 (SDC) taken as the electronic conducting phase and the oxide ion conductor, respectively, dual-phase composite ceramic membranes with or without 3 % (in mole) Y2O3 stable ZrO2 (3YSZ) support were prepared and tested as oxygen separation membranes. Then, the oxygen transmission performance was tested by the electrochemical method based on the limiting current. The results obtained with this method coincide with those acquired by means of gas chromatography. Furthermore, the dependences of oxygen permeation rate on oxygen partial pressure, temperature and ceramic membrane thickness were analyzed. When air was used as the sweeping gas on the porous 3YSZ supported SDC-LSCrF dual-phase membrane, the oxygen permeation rate can reach 0.73, 0.82, 0.90 and 0.97 mL cm−2 min−1 at 650, 700, 750 and 800 °C, respectively.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Solid Oxide Fuel Cells · Electronic and Structural Properties of Oxides · Fuel Cells and Related Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. Research progress and materials selection guidelines on mixed conducting perovskite-type ceramic membranes for oxygen production10.1039/c1ra00419k ↗
2. Current status of ceramic-based membranes for oxygen separation from air10.1016/j.cis.2010.07.007 ↗
3. Partial oxidation of methane in a Zr0.84Y0.16O1.92-La0.8Sr0.2Cr0.5Fe0.5O3−δ hollow fiber membrane reactor targeting solid oxide fuel cell applications10.1016/j.jpowsour.2012.06.042 ↗
4. Partial oxidation of methane in hollow-fiber membrane reactors based on alkaline-earth metal-free CO2-tolerant oxide10.1002/aic.14540 ↗
5. Development and application of oxygen permeable membrane in selective oxidation of light alkanes10.1007/s11244-005-3820-6 ↗
6. Synthesis of Ca0.8Sr0.2Ti0.7Fe0.3O3−δ thin film membranes and its application to the partial oxidation of methane10.1016/j.ssi.2012.06.001 ↗
7. Selective oxidation of ethane to ethylene in a dense tubular membrane reactor10.1016/S0376-7388(02)00363-0 ↗
8. Zr0.84Y0.16O1.92-La0.8Sr0.2Cr0.5Fe0.5O3−δ composite membrane for CO2 decomposition10.1016/j.matlet.2012.06.101 ↗
9. Simultaneous production of hydrogen and synthesis gas by combining water splitting with partial oxidation of methane in a hollow-fiber membrane reactor10.1002/anie.200803899 ↗
10. Hydrogen production by water dissociation in surface-modified BaCoxFeyZr1−x−yO3−δ hollow-fiber membrane reactor with improved oxygen permeation10.1002/chem.200902494 ↗
11. Dense ceramic oxygen permeable membranes and catalytic membrane reactors10.1016/j.cej.2013.01.048 ↗
12. Tin-doped perovskite mixed conducting membrane for efficient air separation10.1039/C4TA00926F ↗
13. Perovskite oxides applications in high temperature oxygen separation, solid oxide fuel cell and membrane reactor: a review10.1016/j.pecs.2017.03.003 ↗
14. Investigation of the permeation behavior and stability of a Ba0.5Sr0.5Co0.8Fe0.2O3−δ oxygen membrane10.1016/S0376-7388(00)00337-9 ↗
15. Zinc-doped BSCF perovskite membranes for oxygen separation10.1016/j.seppur.2017.08.029 ↗
16. Behavior of Ba (Co, Fe, Nb) O3-δ perovskite in CO2-containing atmospheres: degradation mechanism and materials design10.1021/cm101665r ↗
17. CO2-Stable and cobalt-free dual-phase membrane for oxygen separation10.1002/anie.201003723 ↗
18. Facile fabrication and improved carbon dioxide tolerance of a novel bilayer-structured ceramic oxygen permeating membrane10.1016/j.memsci.2014.08.039 ↗
19. CO2-stable Ce0.9Gd0.1O2−δ-perovskite dual phase oxygen separation membranes and the application in partial oxidation of methane to syngas10.1016/j.cej.2017.06.104 ↗
20. High-performance microchanneled asymmetric Gd0.1Ce0.9O1.95−δ–La0.6Sr0.4FeO3−δ-based membranes for oxygen separation10.1021/acsami.5b10714 ↗
21. A novel cobalt-free, CO2-stable, and reduction-tolerant dual-phase oxygen-permeable membrane10.1021/am403272z ↗
22. A novel CO 2-stable dual phase membrane with high oxygen permeability10.1039/C3CC47962E ↗
23. High-performance oxygen permeation membranes: cobalt-free Ba0.975La0.025Fe1-xCuxO3-δ ceramics10.1016/j.jmat.2019.01.013 ↗
24. Ce0.8Sm0.2O1.9–La0.8Sr0.2Cr0.5Fe0.5O3−δ dual-phase hollow fiber membranes operated under different gradients10.1021/ie500193c ↗
25. Ultrahigh oxygen permeation flux through supported Ba0.5Sr0.5Co0.8Fe0.2O3−δ membranes10.1016/j.memsci.2011.04.050 ↗
26. A dual-phase bilayer oxygen permeable membrane with hierarchically porous structure fabricated by freeze-drying tape-casting method10.1016/j.memsci.2016.07.046 ↗
27. Enhancing oxygen permeation through hierarchically-structured perovskite membranes elaborated by freeze-casting10.1039/c3ta14069e ↗
28. C. Gaudillere, J. Garcia-Fayos, M. Balaguer, J.M. Serra, Enhanced oxygen separation through robust freeze-cast bilayered dual J.M. Serra, enhanced oxygen separation through Ro
29. Efficient modification for enhancing surface activity of Ba0.5Sr0.5Co0.8Fe0.2O3−δ oxygen permeation membrane10.1016/j.memsci.2014.12.020 ↗
30. Asymmetric La0.6Sr0.4Co0.2Fe0.8O3-δ membrane with reduced concentration polarization prepared by phase-inversion tape casting and warm pressing10.1016/j.memsci.2017.03.025 ↗
31. Tailoring of surface modified ultrathin membranes with CO2 tolerance and high oxygen permeability10.1039/C5TA10205G ↗
32. Phase inversion tape casting and oxygen permeation properties of supported planar Zr 0.84Y0.16O1.92–La 0.8Sr 0.2Cr0.5Fe0.5O3−δ composite membrane10.1016/j.ssi.2015.12.024 ↗
33. Oxygen permeation properties of supported planar Zr0.84Y0.16O1.92-La0.8Sr0.2Cr0.5Fe0.5O3−δ composite membranes10.1016/j.seppur.2016.04.029 ↗
34. Characteristics of limiting current-type oxygen sensor10.1149/1.2100216 ↗
35. High-performance limiting current oxygen sensor comprised of highly active La0.75Sr0.25Cr0.5Mn0.5O3Electrode10.3390/s18072155 ↗
36. A high performance limiting current oxygen sensor with Ce0.8Sm0.2O1.9 electrolyte and La 0.8Sr0.2Co0.8Fe0.2O3 diffusion barrier10.1016/j.electacta.2013.07.005 ↗
37. A limiting current oxygen sensor based on FeO1.5 doped LDC as dense diffusion barrier