Single step hydrothermal synthesis of 3D urchin like structures of AACH and aluminum oxide with thin nano-spikes

Abstract 3D urchins like ammonium aluminum carbonate hydroxide (AACH) nanostructures with nano-spikes of dia. 20–30 nm were synthesized by a simple, single step hydrothermal technique by using aluminum nitrate and urea as precursor materials. It was found that morphology of the produced structure strongly depends upon the urea concentration. With increasing the amount of urea, the AACH particles having embedded rods like surface features transformed into 3D urchins. The added urea decomposed during hydrothermal treatment and increased the pH of the solution, which affected the morphology of the produced nanostructures. SEM, XRD, FTIR and TGA were employed to characterize the produced structures. On heating, the volatile ingredients of AACH were removed, leaving behind the alumina urchins.