journal article·2020-09

Fabrication of porous Cu supported Ni-P/CeO2 composite coatings for enhanced hydrogen evolution reaction in alkaline solution

Qiongyu Zhou, Songli Liu, Yadong Zhang, Zhiyun Zhu, Wei Su, Minqi Sheng

Ceramics International· Volume 46· Issue 13
Publisher page

Abstract

Abstract Cost-effective electrodes with high activity for hydrogen evolution reaction (HER) and durability are required to develop clean and renewable hydrogen energy. In this work, a porous Cu supported Ni-P/CeO2 composite coating was fabricated by a facile electrodeposition technique. Owing to the contribution from the 3D porous Cu support and the incorporating agglomeration-free and uniformly distributed CeO2 particles into the Ni-P matrix, the optimal composite coating (porous Cu supported Ni-P/CeO2 (20 g L-1)) exhibits outstanding electrocatalytic performance with small overpotentials (η) of 118 and 320 mV at a cathodic current density of 10 and 100 mA cm2. Moreover, the composite electrode also presents excellent electrochemical stability in the alkaline solution. This work provides a feasible option to fabricate composite electrodes that may have desirable electrochemical properties for HER.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (45)

Show source-provided references
1. Oxygen deficient V2O3: a stable and efficient electrocatalyst for HER and high performance EDLCs10.1016/j.ceramint.2019.09.023 ↗
2. Short O–O separation in layered oxide Na0. 67CoO2 enables an ultrafast oxygen evolution reaction10.1073/pnas.1901046116 ↗
3. Network-like porous Co-Ni-B grown on carbon cloth as efficient and stable catalytic electrodes for hydrogen evolution10.1016/j.elecom.2018.06.017 ↗
4. Improved water electrolysis using magnetic heating of FeC–Ni core–shell nanoparticles10.1038/s41560-018-0132-1 ↗
5. Polypyrrole encapsulating TiB2 as newly-emerged electrocatalyst for highly boosted hydrogen evolution reaction10.1016/j.ceramint.2019.08.028 ↗
6. Ultrafine molybdenum carbide nanoparticles supported on nitrogen doped carbon nanosheets for hydrogen evolution reaction10.1016/j.cclet.2018.05.009 ↗
7. Supramolecularly bonded layered heterostructures exhibiting HER activity10.1039/C8TA10985K ↗
8. Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions–a review10.1016/j.ijhydene.2014.10.109 ↗
9. Electrodeposited tungsten-rich Ni-W, Co-W and Fe-W cathodes for efficient hydrogen evolution in alkaline medium10.1016/j.electacta.2019.06.087 ↗
10. Electrocatalytic properties of a cerium/nickel coating deposited using a deep eutectic solvent10.1016/j.elecom.2019.106538 ↗
11. Ultrafine dual‐phased carbide nanocrystals confined in porous nitrogen‐doped carbon dodecahedrons for efficient hydrogen evolution reaction10.1002/adma.201900699 ↗
12. Cuboid Ni2P as a bifunctional catalyst for efficient hydrogen generation from hydrolysis of ammonia borane and electrocatalytic hydrogen evolution10.1002/asia.201701302 ↗
13. Electrodeposited NiCoP hierarchical nanostructure as a cost-effective and durable electrocatalyst with superior activity for bifunctional water splitting10.1016/j.jpowsour.2019.04.050 ↗
14. General formation of M–MoS3 (M= Co, Ni) hollow structures with enhanced electrocatalytic activity for hydrogen evolution10.1002/adma.201504024 ↗
15. Sponge-like nickel phosphide–carbon nanotube hybrid electrodes for efficient hydrogen evolution over a wide pH range10.1007/s12274-016-1301-9 ↗
16. Effects of ligands on electroless Ni–P alloy plating from alkaline citrate–ammonia solution10.1016/S0257-8972(03)00013-6 ↗
17. Parameterization of phosphine ligands demonstrates enhancement of nickel catalysis via remote steric effects10.1038/nchem.2741 ↗
18. Electrocatalytic hydrogen production by a nickel (II) complex with a phosphinopyridyl ligand10.1002/anie.201511621 ↗
19. Co-W/CeO2 composite coatings for highly active electrocatalysis of hydrogen evolution reaction10.1016/j.jallcom.2018.01.356 ↗
20. Application of a deep eutectic solvent to prepare nanocrystalline Ni and Ni/TiO2 coatings as electrocatalysts for the hydrogen evolution reaction10.1016/j.ijhydene.2019.07.188 ↗
21. Integrating catalysis of methane decomposition and electrocatalytic hydrogen evolution with Ni/CeO2 for improved hydrogen production efficiency10.1002/cssc.201802618 ↗
22. Development of Fe2O3–TiO2 mixed oxide incorporated Ni–P coating for electrocatalytic hydrogen evolution reaction10.1016/j.ijhydene.2012.12.009 ↗
23. Tuning of phosphorus content and electrocatalytic character of CeO2-RuO2 composite incorporated Ni-P coating for hydrogen evolution reaction10.1016/j.jallcom.2016.11.238 ↗
24. One-step synthesis of Ni-Mo-S/MoOx composite self-supported on Ni foam for efficient electrocatalytic hydrogen evolution10.1016/j.matlet.2019.03.027 ↗
25. Facile electrodeposition of three-dimensional flower-like structure of nickel matrix composite electrodes for hydrogen evolution reaction10.1016/j.apsusc.2019.143768 ↗
26. Electrodeposition of NiP alloy coatings: a review10.1016/j.surfcoat.2019.03.055 ↗
27. A review of electrodeposited Ni-Co alloy and composite coatings: microstructure, properties and applications10.1016/j.surfcoat.2019.04.079 ↗
28. Novel electrocatalyst of nickel sulfide boron coating for hydrogen evolution reaction in alkaline solution10.1016/j.apsusc.2019.03.025 ↗
29. Electrodeposited nanostructured CoFe2O4 for overall water splitting and supercapacitor applications10.3390/catal9020176 ↗
30. Pulsed laser deposition-assisted synthesis of porous WP2 nanosheet arrays integrated on graphite paper as a 3D flexible cathode for efficient hydrogen evolution10.1016/j.jpowsour.2017.08.034 ↗
31. Engineering of hierarchical and three‐dimensional architectures constructed by titanium nitride nanowire assemblies for efficient electrocatalysis10.1002/celc.201900252 ↗
32. Hollow–structure NiCo hydroxide/carbon nanotube composite for High–Performance supercapacitors10.1016/j.jpowsour.2019.04.035 ↗
33. Microstructures of electroless Ni–P alloy deposits and their transformation sequences during post-deposition annealing10.1557/JMR.2008.0170 ↗
34. Study of hydrogen evolution reaction on Ni–P amorphous alloy in the light of experimental and quantum chemistry10.1016/j.elecom.2007.09.006 ↗
35. Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions–a review10.1016/j.ijhydene.2014.10.109 ↗
36. Corrosion properties of electrodeposited nanocrystalline and amorphous patterned Ni–W alloy10.1016/j.matdes.2008.06.036 ↗
37. Study of Ni–S/CeO2 composite material for hydrogen evolution reaction in alkaline solution10.1016/j.ijhydene.2016.09.080 ↗
38. Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions–a review10.1016/j.ijhydene.2014.10.109 ↗
39. Self-supported Co-Ni-P ternary nanowire electrodes for highly efficient and stable electrocatalytic hydrogen evolution in acidic solution10.1016/j.cattod.2016.09.007 ↗
40. Amorphous Co-WP grown on carbon cloth as a bifunctional catalytic electrode for water splitting10.1088/2053-1591/ab4630 ↗
41. Impedance study of hydrogen evolution on Ni/Zn and Ni–Co/Zn stainless steel based electrodeposits10.1016/j.electacta.2010.10.093 ↗
42. Study of the hydrogen evolution reaction on nickel-based composite coatings containing molybdenum powder10.1016/j.ijhydene.2006.11.020 ↗
43. Facile electrodeposition of three-dimensional flower-like structure of nickel matrix composite electrodes for hydrogen evolution reaction10.1016/j.apsusc.2019.143768 ↗
44. A nanoporous molybdenum carbide nanowire as an electrocatalyst for hydrogen evolution reaction10.1039/C3EE42441C ↗
45. Bifunctionality and mechanism of electrodeposited nickel–phosphorous films for efficient overall water splitting10.1002/cctc.201501150 ↗