journal article·2016-08

Enhanced photocatalytic and photoelectrochemical properties of TiO2 nanorod arrays sensitized with CdS nanoplates

Jiajia Tao, Zezhou Gong, Guang Yao, Yunlang Cheng, Miao Zhang, Jianguo Lv, Shiwei Shi, Gang He, Xiaoshuang Chen, Zhaoqi Sun

Ceramics International· Volume 42· Issue 10
Publisher page

Abstract

Abstract TiO 2 nanorod arrays (NRAs) sensitized with CdS nanoplates (NPLs) were fabricated via a two-step method. Vertically aligned TiO 2 NRAs were synthesized by a hydrothermal method, and followed by depositing CdS NPLs on TiO 2 NRAs via successive ion layer absorption and reaction (SILAR) method. Their surface morphology, structure, photoelectrochemical, and photocatalytic properties were investigated. UV-via absorption spectra suggest that the absorption peaks shift from the ultraviolet region (408 nm) to the visible region (580 nm) when compared to pure TiO 2 nanorod arrays. Additionally, upon irradiation of visible light, the photocurrent response of CdS NPL sensitized TiO 2 NRAs after 8 SILAR cycles significantly improved, displaying an optimal photocurrent density of 168.5 μ A /cm 2 , which is much higher than that of the unsensitized samples (48.1 μ A /cm 2 ). They also exhibited excellent photocatalytic properties where the degradation rate of methyl orange under visible light showed an enhancement of 92.4% compared to bare TiO 2 NRAs. The mechanisms of the enhanced photocatalytic and photoelectrochemical properties of TiO 2 nanorod arrays sensitized with CdS nanoplates are discussed in detail.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · Quantum Dots Synthesis And Properties

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