Strongly adherent Al2O3 coating on SS 316L: Optimization of plasma spray parameters and investigation of unique wear resistance behaviour under air and nitrogen environment

Abstract Plasma spray deposition of Al2O3 is a well-established technique for thick ceramic coatings on various substrates to shield them from corrosion and wear. Owing to its high hardness, aluminum oxide is known to protect stainless steel substrates from wear. However, the plasma process requires optimization for desired coating thickness and adhesion strength. It is also necessary to understand the sensitivity of friction and wear resistance of the deposited coating on exposed environment for evaluation of service life. The study offers comprehensive investigation on plasma process parameters for the development of strongly adherent aluminium oxide coatings on SS 316L substrate. Impact of environment like dry air and dry nitrogen on tribological properties of the coatings was also investigated. Dense adherent coatings of alumina could be deposited on SS 316L at a plasma power of 20 kW with an intermediate bond coat of NiCrAlY to enhance the adhesion properties. The effects of stand-off distance and bond coat thickness on adhesion strength were additionally examined. Further, the coatings were characterised for phase composition, microstructure, microhardness and wear resistance potential. Reciprocating wear tests of the coatings were carried out using ball on disc reciprocating tribometer at different loading conditions (5, 10 and 15 N) at constant (5 Hz) sliding frequency. Unlike the coefficient of friction (COF), wear volume was found to increase with an increase in normal load. These adherent coatings revealed promising properties for the applications where the tribological failure of SS 316L in dry air or dry nitrogen environment is to be controlled.