journal article·2020-11

A novel BaFe0.8Zn0.1Bi0.1O3−δ cathode for proton conducting solid oxide fuel cells

Yunpeng Xia, Xi Xu, Yue Teng, Huanlin Lv, Zongzi Jin, Di Wang, Ranran Peng, Wei Liu

Ceramics International· Volume 46· Issue 16
Publisher page

Abstract

Abstract Cobalt-free materials with triple conductivity are considered potential cathode materials for solid oxide fuel cells (SOFC). We applied Zn to improve the hydration ability and redox activity of a traditional barium-ferrite (BFO) cathode, in order to improve the performance of the proton conductor-based SOFC (H-SOFC). Evidence suggests that the performance of BFO cathode is improved by Zn-doping. The single cell with BaFe0.8Zn0.1Bi0.1O3−δ (BFZB) as the cathode can achieve 816.26 mW cm−2 at 700 °C after Zn-doping. Coupled with the impregnation method, cell performance with BFZB nanoparticles as the cathode was further improved to 1138.21 mW cm−2 at 700 °C. The new cobalt-free cathode has excellent performance, which is even comparable to that of some cobalt-containing cathodes and thus worthy of further investigations.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Solid Oxide Fuel Cells · Electronic and Structural Properties of Oxides · Magnetic and transport properties of perovskites and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (55)

Show source-provided references
1. Advances in solid oxide fuel cell technology10.1016/S0167-2738(00)00452-5 ↗
2. Zr and Y co-doped perovskite as a stable, high performance cathode for solid oxide fuel cells operating below 500 C10.1039/C6EE01915C ↗
3. Tailoring the cathode–electrolyte interface with nanoparticles for boosting the solid oxide fuel cell performance of chemically stable proton‐conducting electrolytes
4. Highly-conductive proton-conducting electrolyte membranes with a low sintering temperature for solid oxide fuel cells10.1016/j.memsci.2018.04.037 ↗
5. Impressive performance of proton-conducting solid oxide fuel cells using a first-generation cathode with tailored cations10.1039/C9TA06676D ↗
6. Solid oxide fuel cell technology—features and applications10.1016/j.ssi.2004.07.042 ↗
7. Solid oxide fuel cells using Sm0. 075Nd0. 075Ce0. 85O2− δ electrolyte coupled with an electron-blocking interlayer10.1016/j.ceramint.2020.01.035 ↗
8. Nanoscaled Sm-doped CeO2 buffer layers for intermediate-temperature solid oxide fuel cells10.1016/j.elecom.2013.08.017 ↗
9. P-substituted Ba0. 95La0. 05FeO3− δ as a cathode material for SOFCs10.1021/acsaem.9b00624 ↗
10. Nb-substituted PrBaCo2O5+ δ as a cathode for solid oxide fuel cells: a systematic study of structural, electrical, and electrochemical properties10.1016/j.ijhydene.2017.06.056 ↗
11. A novel cobalt-free cathode with triple-conduction for proton-conducting solid oxide fuel cells with unprecedented performance10.1039/C9TA02449B ↗
12. Evaluating the effect of Pr-doping on the performance of strontium-doped lanthanum ferrite cathodes for protonic SOFCs10.1016/j.ceramint.2019.10.017 ↗
13. Optimization of sintering temperature for SOFCs by a co-firing method10.1016/j.ceramint.2019.11.134 ↗
14. Sintering aids for proton-conducting oxides–a double-edged sword? A mini review
15. Tailoring cations in a perovskite cathode for proton-conducting solid oxide fuel cells with high performance10.1039/C9TA05300J ↗
16. Electrochemical performance of protonic ceramic fuel cells with stable BaZrO3-based electrolyte: a mini-review10.1016/j.elecom.2018.09.001 ↗
17. Steam electrolysis by solid oxide electrolysis cells (SOECs) with proton-conducting oxides10.1039/C4CS00194J ↗
18. Evaluation of potential reaction between BaZr0. 8Y0. 2O3-δ ceramics and Pt at high temperatures10.1016/j.ceramint.2019.07.159 ↗
19. Fabrication of high-performance proton-conducting electrolytes from microwave prepared ultrafine powders for solid oxide fuel cells10.1016/j.jpowsour.2018.11.051 ↗
20. Improving the sinterability of CeO2 by using plane-selective nanocubes10.1016/j.jeurceramsoc.2019.06.024 ↗
21. Proton-conducting solid oxide fuel cell (SOFC) with Y-doped BaZrO3 electrolyte10.1016/j.elecom.2017.05.006 ↗
22. Improving the performance of the Ba0. 5Sr0. 5Co0. 8Fe0. 2O3-δ cathode for proton-conducting SOFCs by microwave sintering10.1016/j.ceramint.2019.06.281 ↗
23. A novel in situ diffusion strategy to fabricate high performance cathodes for low temperature proton-conducting solid oxide fuel cells10.1039/C8TA00859K ↗
24. Fabrication of one-step co-fired proton-conducting solid oxide fuel cells with the assistance of microwave sintering10.1016/j.jeurceramsoc.2018.08.020 ↗
25. Modification of a first-generation solid oxide fuel cell cathode with Co 3 O 4 nanocubes having selectively exposed crystal planes10.1007/s40243-019-0154-z ↗
26. Tailoring cathode composite boosts the performance of proton-conducting SOFCs fabricated by a one-step co-firing method10.1016/j.jeurceramsoc.2018.02.022 ↗
27. Ba0. 5Sr0. 5Co0. 8-xFe0. 2NbxO3-δ (x≤ 0.1) as cathode materials for intermediate temperature solid oxide fuel cells with an electron-blocking interlayer
28. A new cobalt-free composite cathode Pr0. 6Sr0. 4Cu0. 2Fe0. 8O3− δ-Ce0. 8Sm0. 2O2− δ for proton-conducting solid oxide fuel cells10.1016/j.electacta.2015.07.159 ↗
29. Cobalt-free oxide Ba0. 5Sr0. 5Fe0. 8Cu0. 2O3− δ for proton-conducting solid oxide fuel cell cathode10.1016/j.ijhydene.2010.01.039 ↗
30. Ca and in co-doped BaFeO3− δ as a cobalt-free cathode material for intermediate-temperature solid oxide fuel cells10.1016/j.jpowsour.2016.05.089 ↗
31. An efficient electrocatalyst as cathode material for solid oxide fuel cells: BaFe0· 95Sn0· 05O3− δ10.1016/j.jpowsour.2016.07.023 ↗
32. Ciucci · 2018
33. The effect of A-site and B-site substitution on BaFeO3− δ: an investigation as a cathode material for intermediate-temperature solid oxide fuel cells10.1016/j.jpowsour.2015.08.016 ↗
34. Fe-based perovskite-type oxides as excellent oxygen-permeable and reduction-tolerant materials10.1016/j.ssi.2006.05.037 ↗
35. High performance BaFe1− xBixO3− δ as cobalt-free cathodes for intermediate temperature solid oxide fuel cells10.1016/j.ijhydene.2017.05.061 ↗
36. Bismuth doped lanthanum ferrite perovskites as novel cathodes for intermediate-temperature solid oxide fuel cells10.1021/am5017045 ↗
37. Mixed‐conducting perovskites as cathode materials for protonic ceramic fuel cells: understanding the trends in proton uptake10.1002/adfm.201801241 ↗
38. Cobalt-free nanofiber cathodes for proton conducting solid oxide fuel cells10.1016/j.elecom.2019.01.022 ↗
39. Influence of composition and Cu impregnation method on the performance of Cu/CeO2/YSZ SOFC anodes10.1016/j.jpowsour.2005.04.018 ↗
40. Nano-structured composite cathodes for intermediate-temperature solid oxide fuel cells via an infiltration/impregnation technique10.1016/j.electacta.2010.02.019 ↗
41. Electrochemical characteristics of nano-structured PrBaCo2O5+ x cathodes fabricated with ion impregnation process10.1016/j.jpowsour.2011.11.069 ↗
42. Nanoscale bismuth oxide impregnated (La, Sr) MnO3 cathodes for intermediate-temperature solid oxide fuel cells10.1016/j.jpowsour.2008.07.003 ↗
43. Nanostructuring the electronic conducting La 0.8 Sr 0.2 MnO 3− δ cathode for high-performance in proton-conducting solid oxide fuel cells below 600 C10.1007/s40843-017-9125-1 ↗
44. X-ray diffraction and the Bragg equation10.1021/ed074p129 ↗
45. Evaluation of La2-xNiMnO6-δ as cathode for intermediate temperature solid oxide fuel cells10.1016/j.jpowsour.2018.04.083 ↗
46. Nanocasted synthesis of mesoporous LaCoO3 perovskite with extremely high surface area and excellent activity in methane combustion10.1021/jp8048394 ↗
47. Effect of Na content on the physical properties of powders
48. La1− xCaxCoO3 perovskite-type oxides: identification of the surface oxygen species by XPS10.1016/j.apsusc.2006.02.035 ↗
49. Readily processed protonic ceramic fuel cells with high performance at low temperatures10.1126/science.aab3987 ↗
50. Triple‐conducting layered perovskites as cathode materials for proton‐conducting solid oxide fuel cells10.1002/cssc.201402351 ↗
51. Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells10.1038/s41560-017-0085-9 ↗
52. Chemically stable yttrium and tin Co‐doped barium zirconate electrolyte for next generation high performance proton‐conducting solid oxide fuel cells10.1002/aenm.201201062 ↗
53. Ab initio DFT+ U analysis of oxygen vacancy formation and migration in La1-xSr x FeO3-δ (x= 0, 0.25, 0.50)10.1021/cm401052w ↗
54. Computational design of cobalt-free mixed proton–electron conductors for solid oxide electrochemical cells10.1039/C7TA00338B ↗
55. High-performance anode-supported solid oxide fuel cells based on nickel-based cathode and Ba (Zr0. 1Ce0. 7Y0. 2) O3− δ electrolyte10.1016/j.jallcom.2013.07.210 ↗