Effects of antimony tin oxide (ATO) additive on the properties of Na3Zr2Si2PO12 ceramic electrolytes
Source abstract
Abstract
Abstract Inorganic ceramic as one of the most promising candidate for solid state electrolytes (SSEs) have received extensive attention due to their excellent thermal stability, good electrochemical stability and wide electrochemical window. The sodium super ionic conductor (NASICON, Na3Zr2Si2PO12) structure possesses a three-dimensional network, which helps the migration of Na+. However, because of its low Na+ ion conductivity and poor sintering performance, Na3Zr2Si2PO12 is difficult to achieve application. Therefore, it is quite urgent to solve these questions. In this study, we have reported the effects of additive antimony-tin oxide (ATO) on the phase, microstructure and ionic conductivity of Na3Zr2Si2PO12 ceramic electrolytes. With the ATO sintering additive added, the Na+ ion conductivity and density of Na3Zr2Si2PO12 ceramic electrolytes were improved. The Na3Zr2Si2PO12 ceramic with 5 wt% ATO additive sintered at 1100 °C shows a relatively high ionic conductivity of 1.43 × 10 − 3 S cm-1 at room-temperature, most densest microstructure and wide electrochemical window up to 4.6 V (vs. Na/Na+). In addition, Na/NASICON/Na symmetrical cells were assembled and exhibited good cycling stability which implied good compatibility between sodium (Na) metal and NASICON electrolyte.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Thermal Expansion and Ionic Conductivity
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (38)
Show source-provided references
1. Transition from superlithiophobicity to superlithiophilicity of garnet solid-state electrolyte10.1021/jacs.6b06777 ↗
2. Biomorphic synthesis of mesoporous Co3O4 microtubules and their pseudocapacitive performance10.1021/am5044449 ↗
3. Formation of ultrafine three-dimensional hierarchical birnessite-typeMnO2 nanoflowers for supercapacitor MnO2 nanoflowers for supercapacitor10.1016/j.jallcom.2014.04.077 ↗
4. MnO2 film with three-dimensional structure prepared by hydrothermal process for supercapacitor10.1016/j.jpowsour.2011.10.051 ↗
5. Nanomaterials for solid oxide fuel cells: a review10.1016/j.rser.2017.09.046 ↗
6. Na-ion batteries, recent advances and present challenges to become low cost energy storage systems10.1039/c2ee02781j ↗
7. Enhanced electrochemical performance of core-shell Li4Ti5O12/PTh as advanced anode for rechargeable lithium-ion batteries10.1016/j.ceramint.2017.03.053 ↗
8. Survey of the transport properties of sodium superionic conductor materials for use in sodium batteries10.1016/j.jpowsour.2014.09.137 ↗
9. Efficient storing energy harvested by triboelectric nanogenerators using a safe and durable all-solid-state sodium-ion battery10.1002/advs.201700072 ↗
10. Na3Zr2(SiO4)2(PO4) prepared by a solution-assisted solid state reaction10.1016/j.ssi.2016.11.004 ↗
11. Sodium-ion batteries: present and future10.1039/C6CS00776G ↗
12. Na3Si2Y0.16Zr1.84PO12-ionic liquid hybrid electrolytes: an approach for realizing solid-state sodium-ion batteries10.1016/j.jpowsour.2017.12.037 ↗
13. An all-solid state NASICON sodium battery operating at 200 oC10.1016/j.jpowsour.2013.09.051 ↗
14. Sol-gel synthesis and conductivity properties of sodium ion solid state electrolytes Na3Zr2Si2PO1210.3724/SP.J.1077.2013.13120 ↗
15. NASICON-structured Na3.1Zr1.95Mg0.05Si2PO12 solid electrolyte for solid-state sodium batteries10.1007/s12598-018-1020-3 ↗
16. A self-forming composite electrolyte for solid-state sodium battery with ultralong cycle life10.1002/aenm.201601196 ↗
17. High temperature sodium batteries: status, challenges and future trends10.1039/c3ee24086j ↗
18. Electrolyte and interface engineering for solid-state sodium batteries10.1016/j.joule.2018.07.028 ↗
19. Crystal structures and crystal chemistry in the system Na1+xZr2SixP3-xO1210.1016/0025-5408(76)90073-8 ↗
20. Fast Na+-ion transport in skeleton structures10.1016/0025-5408(76)90077-5 ↗
21. Structural investigation of monoclinic-rhombohedral phase transition in Na3Zr2Si2PO12 and doped NASICON10.1111/jace.13692 ↗
22. Progress in the development of sodium-ion solid electrolytes10.1002/smtd.201700219 ↗
23. Influence of Nb5+, Ti4+ ,Y3+ and Zn2+ doped Na3Zr2Si2PO12 solid electrolyte on its conductivity10.1016/j.jallcom.2018.05.116 ↗
24. Structural investigation of monoclinic-rhombohedral phase transition in Na3Zr2Si2PO12 and doped NASICON10.1111/jace.13692 ↗
25. Influence of M: Ce4+, Gd3+ and Yb3+ substituted Na3+xZr2-xMxSi2PO12 solid NASICON electrolytes on sintering, microstructure and conductivity10.1016/j.electacta.2016.02.199 ↗
26. New promising NASICON material as solid electrolyte for sodium-ion10.1016/j.ssi.2016.06.005 ↗
27. Scandium-Substituted Na3Zr2(SiO4)2(PO4) prepared by a solution-assisted solid-state reaction method as sodium-ion conductors10.1021/acs.chemmater.6b02059 ↗
28. Divalent-doped Na3Zr2Si2PO12 natrium superionic conductor: improving the ionic conductivity via simultaneously optimizing the phase and chemistry of the primary and secondary phases10.1016/j.jpowsour.2017.02.042 ↗
29. Liquid-phase sintering of highly Na+ ion conducting Na3Zr2Si2PO12 ceramics using Na3BO3 additive10.1111/jace.15288 ↗
30. Improved structural stability and ionic conductivity of Na3Zr2Si2PO12 solid electrolyte by rare earth metal substitutions10.1016/j.ceramint.2017.03.095 ↗
31. Low temperature sintering of Na1+xZr2SixP3−xO12 by the addition of Na3BO310.1016/j.scriptamat.2017.10.010 ↗
32. Low temperature-densified NASICON-based ceramics promoted by Na2O-Nb2O5-P2O5 glass additive and spark plasma sintering10.1016/j.ssi.2018.04.025 ↗
33. Processing and electrical properties of NASICON prepared from yttria-doped zirconia precursors10.1016/S0955-2219(00)00264-8 ↗
34. Influence of microstructure on the electrical properties of NASICON materials10.1016/S0167-2738(01)00701-9 ↗
35. Sodium ion diffusion in nasicon (Na3Zr2Si2PO12) solid electrolytes: effects of excess sodium10.1021/acsami.6b09992 ↗
36. A high-performance monolithic solid-state sodium battery with Ca2+ doped Na3Zr2Si2PO12 electrolyte10.1002/aenm.201901205 ↗
37. Rechargeable sodium all-solid-state battery10.1021/acscentsci.6b00321 ↗
38. Optimization of Na3Zr2Si2PO12 ceramic electrolyte and interface for high performance solid-state sodium battery10.1016/j.ceramint.2018.10.062 ↗