journal article·2016-04

Magnetic interactions and hysteresis loops study of Co/CoFe2O4 nanoparticles

B. Aslibeiki

Ceramics International· Volume 42· Issue 5
Publisher page

Abstract

Abstract Co/CoFe2O4 nanoparticles with the mean size of 8.8, 10.8 and 16.9 nm were prepared by thermal decomposition of metal salts in the presence of citric acid. The X-ray diffraction patterns and Rietveld refinements confirmed coexistence of Co-ferrite and metallic cobalt phases in the nano-powders. Scanning electron microscope images showed an increase in particles aggregates mean diameter with increasing the annealing temperature. Magnetic hysteresis loops showed a demagnetization jump at low fields, which was attributed to different reversal fields of ferrite and the cobalt phases. Field-dependent behavior of maximum magnetization (Mmax), remanence (Mr), squareness (S) and coercivity (Hc) were studied through minor loops measurements. The calculated S value of the loops showed a maximum, between anisotropy and coercive fields. A sharp increase in Hc of larger particles was observed with increasing the applied field when compared to smaller particles. Henkel plots showed that the samples are interacting. Negative deviation of Henkel plots from linear behavior and negative δm plots revealed the dominant role of dipole–dipole interactions in the nano-aggregates.
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Research context

OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Magnetic properties of thin films · Characterization and Applications of Magnetic Nanoparticles

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References (41)

Show source-provided references
1. Magnetic hyperthermia investigation of cobalt ferrite nanoparticles: Comparison between experiment, linear response theory, and dynamic hysteresis simulations10.1063/1.4729271 ↗
2. Water-soluble Fe3O4 nanoparticles with high solubility for removal of heavy-metal ions from waste water10.1039/c2dt11827k ↗
3. Synthesis, functionalization, and biomedical applications of multifunctional magnetic nanoparticles10.1002/adma.201000260 ↗
4. Anchoring group effects of surface ligands on magnetic properties of Fe3O4 nanoparticles: towards high performance MRI contrast agents10.1002/adma.201304744 ↗
5. Origin of the magnetic anisotropy energy of cobalt ferrite10.1143/PTP.23.1055 ↗
6. Recent advances in chemical synthesis, self‐assembly, and applications of FePt nanoparticles10.1002/adma.200501464 ↗
7. Solvothermal synthesis of Co/CoFe2O4 nanobelts10.1016/j.matlet.2009.12.036 ↗
8. Exchange bias in Fe/Fe3O4 core-shell magnetic nanoparticles mediated by frozen interfacial spins10.1103/PhysRevB.80.134418 ↗
9. One-pot scalable synthesis of Cu–CuFe2O4/graphene composites as anode materials for lithium-ion batteries with enhanced lithium storage properties10.1039/C4TA02203C ↗
10. The enhanced microwave absorption property of CoFe2O4 nanoparticles coated with a Co3Fe7–Co nanoshell by thermal reduction10.1088/0957-4484/22/4/045707 ↗
11. On the origin of remanence enhancement in exchange-uncoupled CoFe2O4-based composites10.1063/1.4902351 ↗
12. Exchange coupling behavior in bimagnetic CoFe2O4/CoFe2 nanocomposite10.1016/j.jmmm.2012.03.034 ↗
13. Magnetic interactions and energy barrier enhancement in core/shell bimagnetic nanoparticles10.1021/acs.jpcc.5b04448 ↗
14. Exchange-coupling in thermal annealed bimagnetic core/shell nanoparticles10.1016/j.jallcom.2015.02.050 ↗
15. Applications of exchange coupled bi-magnetic hard/soft and soft/hard magnetic core/shell nanoparticles10.1016/j.physrep.2014.09.007 ↗
16. Unusually high coercivity and critical single-domain size of nearly monodispersed CoFe2O4 nanoparticles10.1063/1.1616655 ↗
17. Influence of Co2+ ion concentration on the size, magnetic properties, and purity of CoFe2O4 spinel ferrite nanoparticles10.1021/jp911966p ↗
18. Cationic distribution and spin canting in CoFe2O4 nanoparticles10.1088/0953-8984/23/42/426004 ↗
19. The influence of cobalt population on the structural properties of CoxFe3−xO410.1063/1.2712821 ↗
20. Synthesis and magnetic properties of CoFe2O4 ferrite nanoparticles10.1016/j.jmmm.2008.11.004 ↗
21. Size effects in bimagnetic CoO/CoFe2O4 core/shell nanoparticles10.1088/0957-4484/25/35/355704 ↗
22. The effect of grinding on magnetic properties of agglomereted MnFe2O4 nanoparticles10.1016/j.jmmm.2011.07.057 ↗
23. Strongly interacting superspins in Fe3O4 nanoparticles10.1016/j.cap.2011.11.012 ↗
24. Superspin glass state in MnFe2O4 nanoparticles10.1016/j.jmmm.2010.05.007 ↗
25. Interacting ferromagnetic nanoparticles in discontinuous Co80Fe20/Al2O3 multilayers: from superspin glass to reentrant superferromagnetism10.1103/PhysRevB.63.134423 ↗
26. The role of Ag on dynamics of superspins in MnFe2−xAgxO4 nanoparticles10.1007/s11051-013-1430-y ↗
27. Superspin glass originating from dipolar interaction with controlled interparticle distance among γ-Fe2O3 nanoparticles with silica shells10.1103/PhysRevB.83.224423 ↗
28. Solvothermal synthesis of MnFe2O4 nanoparticles: the role of polymer coating on morphology and magnetic properties10.1016/j.jmmm.2015.09.081 ↗
29. Magnetic properties of MnFe2O4 nano-aggregates dispersed in paraffin wax10.1016/j.jmmm.2015.03.023 ↗
30. Nanomagnetics
31. Exchange coupling in CoFe2O4/CoFe2 bilayers elaborated by pulsed laser deposition10.1016/j.jmmm.2004.01.040 ↗
32. Magnetic anisotropic properties in Fe3O4 and CoFe2O4 ferrite epitaxy thin films10.1016/j.jmmm.2003.09.005 ↗
33. The magnetization of epitaxial nanometric CoFe2O4 (001) layers10.1063/1.3267873 ↗
34. Facile and efficient one-pot solvothermal and microwave-assisted synthesis of stable colloidal solutions of MFe2O4 spinel magnetic nanoparticles10.1007/s11051-012-1034-y ↗
35. A model of interaction effects in granular magnetic solids10.1063/1.368761 ↗
36. Interaction effects on the coercivity and fluctuation field in granular powder magnetic systems10.1016/j.physb.2006.07.003 ↗
37. Interaction and size effects in magnetic nanoparticles10.1016/j.jmmm.2004.11.580 ↗
38. Relations between different modes of acquisition of the remanent magnetization of ferromagnetic particles10.1063/1.1723232 ↗
39. Magnetic interactions in silica coated nanoporous assemblies of CoFe2O4 nanoparticles with cubic magnetic anisotropy10.1088/0957-4484/21/31/315701 ↗
40. Henkel plots of single-domain ferromagnetic particles10.1063/1.372996 ↗
41. Interparticle interactions and magnetic anisotropy in cobalt ferrite nanoparticles: influence of molecular coating10.1021/cm203280y ↗