journal article·2021-10

Ultra-fast charge-discharge and high energy storage density realized in NaNbO3–La(Mn0.5Ni0.5)O3 ceramics

Jitong Wang, Xinru Nie, Zhanhui Peng, Xiaoping Lei, Pengfei Liang, Zupei Yang, Xiaolian Chao

Ceramics International· Volume 47· Issue 20
Publisher page

Abstract

Abstract Lead-free antiferroelectric (AFE) NaNbO3 (NN) is one of promising materials for dielectric capacitors, but the recoverable energy-storage density and efficiency get restrained owing to huge remanent polarization and limited dielectric breakdown field strength. In this work, a variety of NN based lead-free bulk (1-x)NaNbO3-xLa(Mn0.5Ni0.5)O3 (abbreviated as (1-x)NN-xLMN, x = 0, 0.05, 0.10, 0.15, 0.20) ceramics were designed using a solid-state synthesis method. Remarkably, an ultra-fast charge-discharge speed 47 ns and an acceptable recoverable energy-storage density Wrec ~1.77 J/cm3 with a high efficiency η = 77% were obtained under the Eb of 200 kV/cm at x = 0.05. The superior energy storage performance is attributed to the regulation of domain size and voltage resistance by special ions substitution of A and B sites. This work not only proposes an efficient strategy to realize high recoverable energy-storage density and efficiency, but also provide an candidate material for application of advanced pulsed power capacitors.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis · Acoustic Wave Resonator Technologies

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