Defect chemistry and colossal dielectric behavior of Nd-modified SrTiO3 lead-free ceramic materials
Source abstract
Abstract
Abstract Colossal permittivity (CP) ceramics have a great potential in the development of miniaturization, integration and lightweight of electronic components. In this work, NdxSr1-xTiO3 (0.000 ≤ x ≤ 0.014) (NST) ceramics are successfully prepared via sintering in N2. Simultaneously microstructure and dielectric properties of NST ceramics are characterized. It can be found that 0.010 ≤ x ≤ 0.014 ceramics show CP (>20000, 20–1 × 106 Hz) and low dielectric loss ( T i T i ' , N d S r ⋅ , V O ⋅ ⋅ ) forms the defect dipoles ( Ti Ti ' − N d S r ⋅ , T i T i ' − V O ⋅ ⋅ − T i T i ' ) and the defect clusters ( V O ⋅ ⋅ − 3 T i T i ' − N d S r ⋅ ), which produces the electron pinning effect and restricts the long-range movement of the carriers. Additionally, the grain boundary with high insulation resistivity plays a major role in the resistance of ceramics, and it also acts as a high barrier layer to limit the movement of several delocalized carriers.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Dielectric properties of ceramics · Ferroelectric and Piezoelectric Materials · Multiferroics and related materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (67)
Show source-provided references
1. Electron-pinned defect-dipoles for high-performance colossal permittivity materials10.1038/nmat3691 ↗
2. Colossal permittivity materials as superior dielectrics for diverse applications
3. Strong non-volatile voltage control of magnetization and the magnetodielectric properties in polymer-based sandwich-structured composites10.1016/j.compscitech.2019.107931 ↗
4. Colossal permittivity in TiO2 co-doped by donor Nb and isovalent Zr
5. High energy-storage density under low electric fields and improved optical transparency in novel sodium bismuth titanate-based lead-free ceramics10.1016/j.jeurceramsoc.2019.09.001 ↗
6. Colossal dielectric behavior of Ga+Nb co-doped rutile TiO210.1021/acsami.5b07467 ↗
7. Colossal permittivity in ceramics of TiO2 Co-doped with niobium and trivalent cation10.1039/C5TA00141B ↗
8. Ultra-high energy storage performance under low electric fields in Na0.5Bi0.5TiO3-based relaxor ferroelectrics for pulse capacitor applications10.1016/j.ceramint.2019.08.238 ↗
9. Colossal permittivity of Sb and Ga co-doped rutile TiO2 ceramics10.1016/j.ceramint.2018.09.279 ↗
10. Influence of BaZrO3 additive on the energy-storage properties of 0.775Na0.5Bi0.5TiO3-0.225BaSnO3 relaxor ferroelectrics10.1016/j.jallcom.2018.10.025 ↗
11. Giant dielectric permittivity observed in Li and Ti doped NiO10.1103/PhysRevLett.89.217601 ↗
12. Giant dielectric permittivity in Li and Pr co-doped NiO ceramics10.1016/j.jallcom.2009.08.155 ↗
13. Flash sintering of barium titanate10.1016/j.ceramint.2018.12.211 ↗
14. Giant permittivity and low dielectric loss of Fe doped BaTiO3 ceramics: experimental and first-principles calculations10.1016/j.jeurceramsoc.2017.10.014 ↗
15. Giant dielectric constant and good temperature stability in Y2/3Cu3Ti4O12 ceramics10.1111/j.1551-2916.2012.05152.x ↗
16. X. Sun, J. Deng, S. Liu, T. Yan, B. Peng, W. Jia, Z. Mei, H. Su, L. Fang, L. Liu, Grain boundary defect compensation in Ti-doped BaFe0.5Nb0.5O3ceramics, Appl. Phys. A. DOI: 10.1007/s00339-016-0407-y.10.1007/s00339-016-0407-y ↗
17. Grain boundary effect on dielectric properties of (Nd0.5Nb0.5)xTi1-xO2 ceramicsceamics10.1016/j.jallcom.2019.01.243 ↗
18. Surface barrier layer effect in (In + Nb) co-doped TiO2 ceramics: an alternative route to design low dielectric loss10.1111/jace.14688 ↗
19. Colossal dielectric permittivity in (Nb+Al) codoped rutile TiO2 ceramics: compositional gradient and local structure10.1021/acs.chemmater.5b01351 ↗
20. The effect of segregation structure on the colossal permittivity properties of (La0.5Nb0.5)xTi1-xO2 ceramics10.1039/C7TC05277D ↗
21. The contribution of doped-Al to the colossal permittivity properties of AlxNb0.03Ti0.97−xO2 rutile ceramics10.1039/C6TC00742B ↗
22. Dielectric constant versus voltage and non-Ohmic characteristics of Bi2/3Cu3Ti4O12 ceramics prepared by different methods10.1016/j.ceramint.2015.10.054 ↗
23. Enhanced dielectric properties in (In, Nb) co-doped BaTiO3 ceramics10.1016/j.matlet.2017.04.044 ↗
24. High insulation resistivity and ultralow dielectric loss in La-doped SrTiO3 colossal permittivity ceramics through defect chemistry optimization10.1021/acssuschemeng.9b02143 ↗
25. Effects of secondary phases on the high-performance colossal permittivity in titanium dioxide ceramics10.1021/acsami.7b18356 ↗
26. High-performance colossal permittivity materials of (Nb + Er) co-doped TiO2 for large capacitors and high-energy-density storage devices10.1039/C6CP02236G ↗
27. Breakdown in the case for materials with giant permittivity?10.1021/acsenergylett.7b00798 ↗
28. Structural and dielectric behavior of giant permittivity SrNbxTi1−xO3 ceramics sintered in nitrogen atmosphere10.1016/j.ceramint.2016.05.153 ↗
29. Point defect structure of La-doped SrTiO3 ceramics with colossal permittivity10.1016/j.actamat.2018.10.025 ↗
30. Structures and dielectric properties of Sr0.9775Sm0.015TiO3 ceramics sintered in N210.1016/j.ceramint.2015.06.137 ↗
31. Origin of high dielectric permittivity and low dielectric loss of Sr0.985Ce0.01TiO3 ceramics under different sintering atmospheres10.1016/j.jallcom.2018.12.078 ↗
32. Giant dielectric permittivity and high tunability in Y-doped SrTiO3 ceramics tailored by sintering atmosphere10.1016/j.actamat.2017.03.051 ↗
33. Colossal permittivity and defect-dipoles contribution for Ho0.02Sr0.97TiO3 ceramics10.1016/j.jallcom.2018.07.118 ↗
34. Dielectric relaxation in Zr-Doped SrTiO3 ceramics sintered in N2 with giant permittivity and low dielectric loss10.1111/jace.13288 ↗
35. Colossal permittivity and low dielectric loss in Ta doped strontium titanate ceramics by designing defect chemistry
36. Origin of low dielectric loss and giant dielectric response in (Nb+Al) co-doped strontium titanate10.1111/jace.15762 ↗
37. Defect engineering toward the structures and dielectric behaviors of (Nb, Zn) co-doped SrTiO3 ceramics10.1016/j.jeurceramsoc.2019.09.027 ↗
38. Colossal permittivity and high insulation resistivity in Dy- modified SrTiO3 lead-free ceramic materials with low dielectric loss
39. Structural evolution and dielectric properties of Nd and Mn co-doped BaTiO3 ceramics10.1016/j.jallcom.2018.05.089 ↗
40. Colossal dielectric behavior and relaxation in Nd-doped BaTiO3 at low temperature10.1016/j.ceramint.2018.01.181 ↗
41. Modified giant dielectric properties of samarium doped CaCu3Ti4O12 ceramics10.1016/j.materresbull.2012.05.058 ↗
42. Enhanced relative permittivity in niobium and europium co-doped TiO2 ceramics10.1016/j.jeurceramsoc.2018.04.026 ↗
43. Colossal permittivity and low dielectric loss in niobium and europium co-doped TiO2 ceramics by adding B2O310.1016/j.jallcom.2019.05.093 ↗
44. Colossal permittivity in niobium doped BaTiO3 ceramics annealed in N210.1016/j.scriptamat.2017.11.026 ↗
45. Reduced dielectric loss in new colossal permittivity (Pr, Nb)TiO2 ceramics by suppressing adverse effects of secondary phases10.1039/C8CP03304H ↗
46. Correlation between the radius of acceptor ion and the dielectric properties of co-doped TiO2 ceramics10.1016/j.ceramint.2019.04.181 ↗
47. Structural, optical, magnetic and antibacterial properties of Nd doped NiO nanoparticles prepared by co-precipitation method, J. Alloy10.1016/j.jallcom.2018.01.298 ↗
48. Giant dielectric response in (Nb + Zn) co-doped strontium titanate ceramics tailored by atmosphere10.1016/j.scriptamat.2019.05.034 ↗
49. A novel lead-free NaNbO3–Bi(Zn0.5Ti0.5)O3 ceramics system for energy storage application with excellent stability
50. Giant permittivity and low dielectric loss of SrTiO3 ceramics sintered in nitrogen atmosphere10.1016/j.jeurceramsoc.2014.01.015 ↗
51. Novel Na0.5Bi0.5Ti0.5O3 based, lead-free energy storage ceramics with high power and energy density and excellent high-temperature stability
52. Defect chemistry and dielectric behavior of Sr0.99Ce0.01Ti1−xO3 ceramics with high permittivity10.1016/j.ceramint.2018.03.221 ↗
53. Oxygen-vacancy-related dielectric relaxations in SrTiO3 at high temperatures
54. Enhanced energy storage and fast charge-discharge capability in Ca0.5Sr0.5TiO3-based linear dielectric ceramic
55. Simultaneous realization of broad temperature stability range and outstanding dielectric performance in (Ag+, Ta5+) co–doped TiO2 ceramics10.1016/j.jallcom.2018.12.321 ↗
56. Nonlinear current-voltage and giant dielectric properties of Al3+ and Ta5+ co-doped TiO2 ceramics10.1016/j.materresbull.2019.04.026 ↗
57. Colossal permittivity and impedance analysis of tantalum and samarium co-doped TiO2 ceramics10.1016/j.ceramint.2017.07.034 ↗
58. Very low dielectric loss and giant dielectric response with excellent temperature stability of Ga3+ and Ta5+ co-doped rutile-TiO2 ceramics10.1016/j.matdes.2017.03.037 ↗
59. Colossal dielectric permittivity in hydrogen-reduced rutile TiO2 crystals10.1016/j.jallcom.2016.09.044 ↗
60. Effects of sintering temperature on microstructure and giant dielectric properties of (V + Ta) co–doped TiO2 ceramics10.1016/j.jallcom.2017.07.143 ↗
61. Structure and enhanced dielectric properties of B and Sr modified CaCu3Ti4O12 ceramics10.1007/s11664-019-07430-0 ↗
62. (Al3+, Nb5+) co–doped CaCu3Ti4O12: an extended approach for acceptor–donor heteroatomic substitutions to achieve high–performance giant–dielectric permittivity10.1016/j.jeurceramsoc.2017.08.040 ↗
63. Microstructures and dielectric properties of sol-gel prepared K-doped CaCu3Ti4O12 ceramics10.1007/s10832-018-0110-9 ↗
64. High permittivity and low dielectric loss of the Ca1−xSrxCu3Ti4O12 ceramics10.1016/j.jallcom.2011.06.039 ↗
65. Dielectric properties of Al2O3 modified CaCu3Ti4O12 ceramics10.1007/s10854-019-01810-2 ↗
66. Colossal permittivity and dielectric relaxations in BaTi0.99(Nb0.5Ga0.5)0.02O3 ceramics10.1016/j.ceramint.2015.03.303 ↗
67. Microstructure and dielectric properties of Ag-BaTiO3 composite ceramics10.1016/j.jeurceramsoc.2018.08.002 ↗