journal article·2017-01

Enhanced discharged energy density and efficiency of poly(vinylidene fluoride) nanocomposites through a small loading of core-shell structured BaTiO3@Al2O3 nanofibers

Shaohui Liu, Jiao Wang, Bo Shen, Jiwei Zhai

Ceramics International· Volume 43· Issue 1
Publisher page

Abstract

Abstract Nanocomposite based on poly(vinylidene fluoride) (PVDF) polymer filled with surface functionalized core-shell structure BaTiO3@Al2O3 nanofibers (BT@Al2O3 NF) were prepared via the solution casting method. Experimental results clearly demonstrate that the nanocomposites with BT@Al2O3 NF exhibit enhanced discharged energy density under high electric field compared to those of BT NF. The maximum discharged energy density in the nanocomposite with 2.5 vol% BT@Al2O3 NF is 7.1 J/cm3 at 3800 kV/cm with an efficiency of above 65.1%. According to the results of complex impedance analysis, coating Al2O3 layers on the surface of BT NF reduces the Maxwell–Wagner–Sillars interfacial polarization, which might be the reason of the improvement of the discharged energy density and discharged efficiency. This work may provide an effective solution to enhance discharged energy density in polymer-based nanocomposites.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Dielectric materials and actuators · Advanced Sensor and Energy Harvesting Materials · High voltage insulation and dielectric phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Ultrahigh energy density of polymer nanocomposites containing BaTiO3@ TiO2 nanofibers by atomic‐scale interface engineering10.1002/adma.201404101 ↗
2. Surface modification of polypropylene battery separator by direct fluorination with different gas components10.1016/j.apsusc.2013.11.015 ↗
3. Preparation and dielectric properties of core-shell structural composites of poly(1H,1H,2H,2H-perfluorooctyl methacrylate)@BaTiO3 nanoparticles10.1016/j.apsusc.2013.03.178 ↗
4. Crystallinity, morphology and high dielectric permittivity of NiO nanosheets filling Poly (vinylidene fluoride)10.1016/j.ceramint.2015.07.199 ↗
5. The influence of crystalline transformation of Ba 0.6 Sr 0.4 TiO3 nanofibers/poly (vinylidene fluoride) composites on the energy storage properties by quenched technique
6. Significantly enhanced breakdown strength and energy density in sandwich-structured barium titanate/poly (vinylidene fluoride) nanocomposites10.1002/adma.201503186 ↗
7. High energy density of polymer nanocomposites at a low electric field induced by modulation of their topological-structure10.1039/C6TA02186G ↗
8. Giant energy density and improved discharge efficiency of solution-processed polymer nanocomposites for dielectric energy storage10.1002/adma.201503881 ↗
9. Fundamentals, processes and applications of high-permittivity polymer matrix composites10.1016/j.pmatsci.2011.08.001 ↗
10. Highly enhanced energy density induced by hetero-interface in sandwich-structured polymer nanocomposites10.1039/c3ta11886j ↗
11. Enhanced dielectric and energy storage density induced by surface-modified BaTiO3 nanofibers in poly(vinylidene fluoride) nanocomposites10.1016/j.ceramint.2014.07.083 ↗
12. Electrical energy density and dielectric properties of poly(vinylidene fluoride-chlorotrifluoroethylene)/BaSrTiO3 nanocomposites10.1016/j.ceramint.2011.08.033 ↗
13. High-energy-density dielectric films based on polyvinylidene fluoride and aromatic polythiourea for capacitors10.1039/C4TA03374D ↗
14. Polyhedral oligosilsesquioxane-modified boron nitride nanotube based epoxy nanocomposites: an ideal dielectric material with high thermal conductivity10.1002/adfm.201201824 ↗
15. Core@double-shell structured BaTiO3-polymer nanocomposites with high dielectric constant and low dielectric loss for energy storage application10.1021/jp407340n ↗
16. A review on the dielectric materials for high energy-storage application10.1142/S2010135X13300016 ↗
17. High energy density nanocomposite capacitors using non-ferroelectric nanowires10.1063/1.4792513 ↗
18. Core-shell structured poly(methyl methacrylate)/BaTiO3 nanocomposites prepared by in situ atom transfer radical polymerization: a route to high dielectric constant materials with the inherent low loss of the base polymer10.1039/c0jm04574h ↗
19. Poly(vinylidene fluoride) polymer based nanocomposites with significantly reduced energy loss by filling with core-shell structured BaTiO3/SiO2 nanoparticles10.1063/1.4795017 ↗
20. TiO2-nanorod decorated carbon nanotubes for high-permittivity and low-dielectric-loss polystyrene composites10.1016/j.compscitech.2011.12.014 ↗
21. Tailoring dielectric properties and energy density of ferroelectric polymer nanocomposites by high-k nanowires10.1021/acsami.5b06480 ↗
22. Improving the dielectric constants and breakdown strength of polymer composites: effects of the shape of the BaTiO3 nanoinclusions, surface modification and polymer matrix10.1039/c2jm32579a ↗
23. Effect of microwave processes on the energy-storage properties of barium strontium titanate glass ceramics10.1557/jmr.2013.386 ↗
24. Novel three-dimensional zinc oxide superstructures for high dielectric constant polymer composites capable of withstanding high electric field10.1021/jp3088644 ↗
25. Dielectric and magnetic properties of ferrite/poly(vinylidene fluoride) nanocomposites10.1016/j.matchemphys.2011.10.037 ↗