journal article·2016-05

Enhanced thermoelectric efficiency of Cu2−Se–Cu2S composite by incorporating Cu2S nanoparticles

M.U. Farooq, Sajid Butt, Kewei Gao, Xigui Sun, XiaoLu Pang, Sajid U. Khan, Wei Xu, Fida Mohmed, Asif Mahmood, Nasir Mahmood

Ceramics International· Volume 42· Issue 7
Publisher page

Abstract

The study of thermoelectric transport properties in Cu2-xSe and Cu2S has gained an importance in the thermoelectric research during last few years due to their supertonic behavior and low cost. Here, we reported a facile method to enhance the thermoelectric efficiency of Cu2-xSe by introducing Cu2S nanoparticles (NPs) in the matrix of Cu2-xSe. The observed efficiency is a direct result of simultaneous improvement of Seebeck coefficient (S) because of the external strain induced by Cu2S nanoinclusions in Cu2-xSe and decline in the total thermal conductivity by suppressing both electronic and lattice thermal contributions. Such higher S and lower thermal conductivity is realized for a composite structure with 10 wt% nanoinclusions of Cu2S which effectively contributed to higher ZT value of 0.90 at moderate temperature of 773 K. Thus, it is believed that the proposed hybrid structure is a promising p-type thermoelectric material for mid-temperature range energy harvesting applications. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Thermoelectric Materials and Devices · Thermal properties of materials · Thermal Radiation and Cooling Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (39)

Show source-provided references
1. T.M. Tritt, M.A. Subramanian, Thermoelectric Materials, Phenomena, and Applications : A Bird's Eye View, 31, 200610.1557/mrs2006.44 ↗
2. Thermoelectric Materials : Principles, Structure, Properties, and Applications, 2002
3. G.S. Nolas, J. Sharp, H.J. Goldsmid. Thermoelectrics: Basic Principles and New Materials Development, 200110.1007/978-3-662-04569-5 ↗
4. Enhancement of thermoelectric performance in hierarchical mesoscopic oxide composites of Ca3Co4O9 and La0.8Sr0.2CoO3
5. New directions for low-dimensional thermoelectric materials10.1002/adma.200600527 ↗
6. High-performance nanostructured thermoelectric materials10.1038/asiamat.2010.138 ↗
7. High-performance bulk thermoelectrics with all-scale hierarchical architectures10.1038/nature11439 ↗
8. Nano-inclusions: a novel approach to tune the thermal conductivity of In2O310.1039/c3cp52942h ↗
9. Enhancement of thermoelectric performance in Cd-doped Ca3Co4O9 via spin entropy, defect chemistry and phonon scattering10.1039/C4TA03891F ↗
10. Enhanced thermoelectric performance of rough silicon nanowires10.1038/nature06381 ↗
11. Silicon nanowires as efficient thermoelectric materials10.1038/nature06458 ↗
12. Quantum dot superlattice thermoelectric materials and devices10.1126/science.1072886 ↗
13. Thin-film thermoelectric devices with high room-temperature figures of merit10.1038/35098012 ↗
14. Nanostructured thermoelectrics: big efficiency gains from small features10.1002/adma.201000839 ↗
15. Enhancement of thermoelectric performance of Sr0.7Ba0.3Nb2O6−δ ceramics by lanthanum doping10.1016/j.ceramint.2015.09.041 ↗
16. High-temperature thermoelectric properties of the solid solutions BaBi1−x PbxO3 (x=0−1)10.1023/A:1017974413142 ↗
17. Convergence of electronic bands for high performance bulk thermoelectrics10.1038/nature09996 ↗
18. High thermoelectric figure of merit and nanostructuring in bulk p-type Na1−xPbmSbyTem+210.1002/anie.200600865 ↗
19. High performance Na-doped PbTe–PbS thermoelectric materials: electronic density of states modification and shape-controlled nanostructures10.1021/ja206380h ↗
20. Enhancing the thermoelectric performance of β-Cu2Se by incorporating SnSe10.1016/j.jallcom.2015.08.154 ↗
21. Cubic AgPb(m)SbTe(2+m): bulk thermoelectric materials with high figure of merit10.1126/science.1092963 ↗
22. BaCu2Se2 based compounds as promising thermoelectric materials
23. Copper ion liquid-like thermoelectrics10.1038/nmat3273 ↗
24. Low-temperature structural and transport anomalies in Cu2Se10.1103/PhysRevB.89.195209 ↗
25. X-ray study of the average structures of Cu2Se and Cu1.8S in the room temperature and the high temperature phases10.1016/0022-4596(91)90289-T ↗
26. Ultrahigh thermoelectric performance by electron and phonon critical scattering in Cu2Se1−xIx10.1002/adma.201302660 ↗
27. Thermoelectric properties of Ag-doped Cu2Se and Cu2Te10.1039/c3ta12508d ↗
28. Self-propagating high-temperature synthesis for compound thermoelectrics and new criterion for combustion processing10.1038/ncomms5908 ↗
29. Structure-transformation-induced abnormal thermoelectric properties in semiconductor copper selenide10.1016/j.matlet.2012.11.058 ↗
30. From Cu2S nanocrystals to Cu doped CdS nanocrystals through cation exchange: controlled synthesis, optical properties and their p-type conductivity research10.1007/s40843-015-0080-z ↗
31. Reversible Cu2−xSe↔Cu3Se2 phase transformation in copper selenide thin films prepared by chemical bath deposition10.1016/S0040-6090(00)01783-1 ↗
32. Thermoelectric properties of copper selenide with ordered selenium layer and disordered copper layer10.1016/j.nanoen.2012.02.010 ↗
33. High thermoelectric performance in non-toxic earth-abundant copper sulfide10.1002/adma.201400515 ↗
34. Weak electron–phonon coupling contributing to high thermoelectric performance in n-type PbSe10.1073/pnas.1111419109 ↗
35. C. Indium, (4) (5) (6)., 14 (n.d.) 0–3.
36. Thermoelectric property studies on Cu-doped n-type CuxBi2Te2.7Se0.3 nanocomposites10.1002/aenm.201100149 ↗
37. Effect of mixed grain sizes on thermoelectric performance of Bi2Te3 compound
38. Nanostructures boost the thermoelectric performance of PbS10.1021/ja109138p ↗
39. Lower limit to the thermal conductivity of disordered crystals10.1103/PhysRevB.46.6131 ↗