Preparation and characterization of hydroxyapatite–forsterite–bioactive glass nanocomposite coatings for biomedical applications

Abstract In order to improve biological and mechanical properties of hydroxyapatite, the concept of hydroxyapatite-included nanocomposite coatings was introduced. By judiciously choosing constituent ceramics for composites preparation, the biological and mechanical performance of coatings can be tailored in order to meet various clinical requirements. The aim of this work was fabrication, development and characterization of novel hydroxyapatite–forsterite–bioactive glass nanocomposite coatings. The sol–gel technique was used to prepare hydroxyapatite–forsterite–bioactive glass nanocomposite in order to apply coating on 316L stainless steel (SS) by dip coating technique. The X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX) were used to investigate the phase structure, microstructure and morphology of the coating. In order to evaluate the forsterite incorporation influence upon bioactivity, the changes on the surfaces of the prepared composite coatings after the predicted days of contact with simulated body fluid (SBF) were investigated by SEM. Results showed that the suitable calcined temperature for nanocomposite coatings with different amounts of forsterite was 600 °C. At this temperature, the homogenous and crack-free coating could attach to the 316L SS substrate. The crystallite sizes of the prepared coatings were lower than 100 nm. The EDX analysis of hydroxyapatite–forsterite–bioglass, coated 316L SS surface, indicated consisting elements of prepared coatings and the substrate. During immersion in the SBF at pre-determined time intervals, apatite layer was formed and stimulation for apatite formation was increased with increase in forsterite amounts. It seems that hydroxyapatite–forsterite–bioactive glass nanocomposite coatings might be good candidates for biomedical applications.