journal article·2020-06

A modified wet chemical synthesis of Wollastonite ceramic nanopowders and their characterizations

Mehieddine Bouatrous, Ferhat Bouzerara, Arvind K. Bhakta, Florimond Delobel, Joseph Delhalle, Zineb Mekhalif

Ceramics International· Volume 46· Issue 8
Publisher page

Abstract

A simple, cost effective, reproducible, eco-friendly and very efficient novel modified wet chemical synthesis of high purity Wollastonite ceramics nanopowders is developed. The precursors used to synthesize calcium silicate hydrate (C-S-H) in this work are calcium chloride and sodium-disilicate. The method utilizes moderate heat comparatively with the methods reported in the literature. The resulting powders were calcined at different temperatures, characterized by XRD, FTIR, SEM, TEM, EDX, TGA/DTA, and N 2 adsorption. XRD patterns for samples calcined show the formation of crystalline Wollastonite. Furthermore, XRD reveal thatβ-CaSiO 3 occurs at 800 °C, then at 1200 °C, it transforms completely to α-CaSiO 3. The method is applicable for bulk synthesis at cheaper cost, which opens interesting perspectives for applications in the several industrial fields such as ceramics, paints, plastics, biomaterials, composites, to name few.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nuclear materials and radiation effects · Concrete and Cement Materials Research · Recycling and utilization of industrial and municipal waste in materials production

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Rock-forming minerals: single-chain silicates, volume 2A, second ed, geological society of London, 1997
2. Deer · 1997 · 2A · 1997
3. Apatite formed on the surface of plasma-sprayed wollastonite coating immersed in simulated body fluid,10.1016/S0142-9612(00)00386-0 ↗
4. Preparation and electrical properties of wollastonite coated with antimony-doped tin oxide nanoparticles10.1016/j.powtec.2018.09.092 ↗
5. Wollastonite raw materials and their applications (a review)10.1007/BF00681090 ↗
6. Liverani · 2019 · 188
7. Preparation and in vitro bioactivity of CaSiO3 powders10.1016/j.ceramint.2006.12.013 ↗
8. Sol-gel and SPS combined synthesis of highly porous wollastonite ceramic materials with immobilized Au-NPs10.1016/j.ceramint.2017.03.207 ↗
9. Sol-gel derived calcium silicate ceramics10.1016/j.colsurfa.2007.08.021 ↗
10. Bioactive nanocrystalline wollastonite synthesized by sol–gel combustion method by using eggshell waste as calcium source10.1007/s12034-014-0646-5 ↗
11. A facile route to the synthesis of hydroxyapatite/wollastonite composite powders by a two-step coprecipitation method10.1007/s12633-015-9339-y ↗
12. Synthesis and in vitro bioactivity mechanism of synthetic α-wollastonite and β-wollastonite bioceramics
13. Preparation of acicular wollastonite using hydrothermal and calcining methods10.1080/10584587.2013.789777 ↗
14. Synthesis of nanocrystalline wollastonite powders by citrate-nitrate gel combustion method10.1016/j.matchemphys.2008.11.066 ↗
15. Synthesis of wollastonite nanowires via hydrothermal microemulsion methods10.1016/j.matlet.2006.02.034 ↗
16. Synthesis of wollastonite single crystal nanowires by a novel hydrothermal route10.1246/cl.2004.1458 ↗
17. Comparative study of apatite formation on CaSiO3 ceramics in simulated body fluids with different carbonate concentrations10.1007/s10856-005-6449-x ↗
18. Synthesis and characterization of nano-wollastonite from rice husk ash and limestone
19. The suitability of rice straw ash as a precursor for synthesizing β-wollastonite
20. Phase pure, high hardness, biocompatible calcium silicates with excellent anti-bacterial and biofilm inhibition efficacies for endodontic and orthopaedic applications10.1016/j.jmbbm.2018.06.046 ↗
21. Microstructure and characterization of aluminum-incorporated calcium silicate hydrates (C–S–H) under hydrothermal conditions10.1039/C8RA04423F ↗
22. Morphogenesis of Cement Hydrate: From Natural C-S-H to Synthetic C-S-H
23. Structural study of sol–gel silicate glasses by IR and Raman spectroscopies10.1016/j.jnoncrysol.2009.01.010 ↗
24. Structure of nanocrystalline calcium silicate hydrates: insights from X-ray diffraction, synchrotron X-ray absorption and nuclear magnetic resonance10.1107/S1600576716003885 ↗
25. Structure of calcium silicate hydrate (C-S-H): near-, mid-, and far-infrared spectroscopy10.1111/j.1151-2916.1999.tb01826.x ↗
26. The power of databases: the RRUFF project
27. Infrared spectroscopy of minerals and related compounds10.1039/C8RA07116K ↗
28. Chukanov · 2016
29. Transformation of silicate gels during heat treatment in air and in argon – spectroscopic studies10.1016/j.molstruc.2014.04.020 ↗
30. Imaging of drug loading distributions in individual microspheres of calcium silicate hydrate – an X-ray spectromicroscopy study10.1039/C4NR07471H ↗
31. Recommendations for the characterization of porous solids (Technical Report)10.1351/pac199466081739 ↗
32. Lowell · 2012
33. Surface area and pore texture of catalysts10.1016/S0920-5861(98)00050-9 ↗
34. The influence of annealing temperature on the microstructural development of W–Cu composite powder prepared by high-energy ball milling10.1016/j.jallcom.2005.10.082 ↗
35. Dubois · 2010