journal article·2020-06

Surfactant-free synthesis of a novel octahedral ZnFe2O4/graphene composite with high adsorption and good photocatalytic activity for efficient treatment of dye wastewater

Jianping Ai, Liling Hu, Zehua Zhou, Lihong Cheng, Wenjin Liu, Kaiyu Su, Ruibo Zhang, Zhiqin Chen, Wenkui Li

Ceramics International· Volume 46· Issue 8
Publisher page

Abstract

Abstract Recently, significant effort has been made toward the development of graphene-based visible-ligh-responsive photocatalysts and their application to dye wastewater treatment. Herein, a series of octahedral ZnFe2O4/graphene (ZnFe2O4-G) nanocomposites were synthesized using a one-pot solvothermal reaction without the need of a surfactant as novel bifunctional materials exhibiting both high adsorption and good visible-light-responsive photocatalyst properties. The crystal structure, morphology and photocatalytic degradation properties, as well as adsorption behavior, of the octahedral ZnFe2O4/graphene composites were investigated in detail. The adsorption capacity and UV–vis spectrometry results indicate that the dye removal efficiency over the samples followed the order of: methylene blue (MB) > rhodamine B (RhB) > methyl orange (MO). The ZnFe2O4-G materials exhited enhanced photocatalytic degradation properties for cationic dyes (MB and RhB) compared to those for the anionic dye (MO). In addition, the experimental results indicate that the ZnFe2O4-G materials can decompose H2O2 in the visible-light photocatalytic process to form hydroxyl radicals (•OH), which are mainly responsible for the photodegradation of the organic contaminants.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · ZnO doping and properties · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (56)

Show source-provided references
1. Surfactant-free synthesis of octahedral ZnO/ZnFe2O4 heterostructure with ultrahigh and selective adsorption capacity of malachite green10.1038/srep25074 ↗
2. Nanoparticles with photoinduced precipitation for the extraction of pollutants from water and soil10.1038/ncomms8765 ↗
3. Interfacial reaction-directed synthesis of Ce-Mn binary oxide nanotubes and their applications in CO oxidation and water treatment10.1002/adfm.201200900 ↗
4. Nanoporous nitrogen-doped titanium dioxide with excellent photocatalytic activity under visible light irradiation produced by molecular layer deposition10.1002/anie.201302329 ↗
5. Ordered mesoporous black TiO2 as highly efficient hydrogen evolution photocatalyst10.1021/ja504802q ↗
6. Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications10.1021/cr0500535 ↗
7. Surface modification of MnFe2O4 nanoparticles to impart intrinsic multiple fluorescenece and novel photocatalytic properties10.1021/am405950q ↗
8. In situ synthesis of water-soluble magnetic graphitic carbon nitride photocatalyst and its synergistic catalytic performance10.1021/am404123z ↗
9. Synthesis and performance of novel magnetically separable nanospheres of titanium dioxide photocatalyst with egg-like structure10.1088/0957-4484/19/9/095606 ↗
10. Optical and photocatalytic properties of solar light active Nd-substituted Ni ferrite catalysts: for environmental protection10.1021/sc400060z ↗
11. Core-ring structured NiCo2O4 nanoplatelets: synthesis, characterization, and electrocatalytic applications10.1002/adfm.200700982 ↗
12. Ni(x)Co(3-x)O4 nanowire arrays for electrocatalytic oxygen evolution10.1002/adma.200903896 ↗
13. Chaotic Dirac billiard in graphene quantum dots10.1126/science.1154663 ↗
14. Graphene-based materials10.1126/science.1158180 ↗
15. Photocatalyst Interface Engineering: spatially confined growth of ZnFe2O4 within graphene networks as excellent visible-light-driven photocatalysts10.1002/adfm.201502970 ↗
16. Microwave synthesis of magnetically separable ZnFe2O4-reduced graphene oxide for wastewater treatment10.1016/j.ceramint.2013.12.037 ↗
17. Facile fabrication of magnetic reduced graphene oxide-ZnFe2O4 composites with enhanced adsorption and photocatalytic activity10.1016/j.apsusc.2015.10.101 ↗
18. Synthesis of magnetic ZnFe2O4/graphene composite and its application in photocatalytic degradation of dyes10.1016/j.jallcom.2013.06.098 ↗
19. Magnetically separable ZnFe2O4-graphene catalyst and its high photocatalytic performance under visible light irradiation10.1021/ie200162a ↗
20. Shape-controlled synthesis of bare ZnO nanomaterials with improved photoactivity and photostability10.1080/02670836.2018.1558578 ↗
21. Use of Raman micro-spectroscopy in the characterization of MFe2O4 (M=Fe, Zn) electric double layer ferrofluids10.1002/(SICI)1097-4555(200003)31:3<185::AID-JRS511>3.0.CO;2-B ↗
22. Reducing sugar: new functional molecules for the green synthesis of graphene nanosheets10.1021/nn1002387 ↗
23. Visible light-driven α-Fe2O3 nanorod/graphene/BiV1-xMoxO4 core/shell heterojunction array for efficient photoelectrochemical water splitting10.1021/nl303961c ↗
24. Fabrication of pit-structured ZnO nanorods and their enhanced photocatalytic performance10.1039/c3ra42874e ↗
25. Generalized preparation of porous nanocrystalline ZnFe2O4 superstructures from zinc ferrioxalate precursor and its superparamagnetic property10.1021/jp804009h ↗
26. Porous graphene oxide frameworks: synthesis and gas sorption properties10.1039/c1jm11699a ↗
27. ZnFe2O4 multi-porous microbricks/graphene hybrid photocatalyst: facile synthesis, improved activity and photocatalytic mechanism10.1016/j.apcatb.2013.04.062 ↗
28. Superparamagnetic zinc ferrite spinel-graphene nanostructures for fast wastewater purification10.1016/j.carbon.2013.12.019 ↗
29. Synthesis of ZnFe2O4/ZnO nanocomposites immobilized on graphene with enhanced photocatalytic activity under solar light irradiation10.1016/j.jallcom.2013.02.147 ↗
30. Template-free synthesis of hierarchical ZnFe2O4 yolk-shell microspheres for high-sensitivity acetone sensors10.1039/C5NR06308F ↗
31. Electrochemical method for synthesis of a ZnFe2O4/TiO2 composite nanotube array modified electrode with enhanced photoelectrochemical activity10.1002/adfm.200902390 ↗
32. Au/α-Fe2O3 catalyst for water-gas shift reaction prepared by deposition-precipitation10.1016/S0926-860X(97)00302-5 ↗
33. Spinel ZnFe2O4 nanoparticle-decorated rod-like ZnO nanoheterostructures for enhanced gas sensing performances10.1039/C4RA14033H ↗
34. Functionalized single graphene sheets derived from splitting graphite oxide10.1021/jp060936f ↗
35. Enhanced photocatalytic degradation of methylene blue under visible irradiation on graphene@TiO2 dyade structure10.1016/j.apcatb.2011.10.012 ↗
36. Self-assembly of ZnFe2O4/graphene hybrid and its application as high-performance anode material for Li-ion batteries10.1039/c2nj40534b ↗
37. Reporting physisorption data for gas/solid systems with special reference to determination of surface area and porosity10.1351/pac198557040603 ↗
38. Electrochemical lithium storage of a ZnFe2O4/graphene nanocomposite as an anode material for rechargeable lithium ion batteries10.1039/C4RA08414D ↗
39. Facile microwave-assisted green synthesis of Ag-ZnFe2O4@rGO nanocomposites for efficient removal of organic dyes under UV- and visible-light irradiation10.1016/j.apcatb.2016.10.033 ↗
40. Uniformly dispersed ZnFe2O4 nanoparticles on nitrogen-modified graphene for high-performance supercapacitor as electrode10.1038/srep43116 ↗
41. One-pot synthesis of ultrafine ZnFe2O4 nanocrystals anchored on graphene for high-performance Li and Li-ion batteries10.1039/c3ra46904b ↗
42. Reduced graphene oxide anchored magnetic ZnFe2O4 nanoparticles with enhanced visible-light photocatalytic activity10.1039/C4RA14587A ↗
43. One-step hydrothermal synthesis of ZnFe2O4 nano-octahedrons as a high capacity anode material for Li-ion batteries10.1007/s12274-012-0233-2 ↗
44. Simple solution-combusting synthesis of octahedral ZnFe2O4 nanocrystals and additive-promoted photocatalytic performance10.1039/C4RA06993E ↗
45. Synthesis of high electrochemical performance Ni(OH)2 nanosheets through a solvent-free reaction for application in supercapacitor10.1016/j.apt.2014.11.016 ↗
46. β-Ni(OH)2 nanosheets grown on graphene as advanced electrochemical pseudocapacitor materials with improved rate capability and cycle performance10.1016/j.matlet.2014.07.063 ↗
47. Effect of solvents on the morphology of NiCo2O4/graphene nanostructures for electrochemical pseudocapacitor application10.1007/s10008-015-3022-5 ↗
48. One-pot solvothermal preparation of magnetic reduced graphene oxide-ferrite hybrids for organic dye removal10.1016/j.carbon.2012.01.057 ↗
49. A facile approach to the fabrication of rattle-type magnetic carbon nanospheres for removal of methylene blue in water10.1016/j.carbon.2015.03.047 ↗
50. Visible light photocatalytic activity enhancement and mechanism of AgBr/Ag3PO4 hybrids for degradation of methyl orange10.1016/j.jhazmat.2012.03.002 ↗
51. Fabrication of FeWO4@ZnWO4/ZnO heterojunction photocatalyst: synergistic effect of ZnWO4/ZnO and FeWO4@ZnWO4/ZnO heterojunction structure on the enhancement of visible-light photocatalytic activity10.1021/acssuschemeng.6b00660 ↗
52. Construction of TiO2 nanobelts-Bi2O4 heterojunction with enhanced visible light photocatalytic activity10.1016/j.colsurfa.2018.03.063 ↗
53. Preparation, characterization and photocatalytic activity of visible-light-driven plasmonic Ag/AgBr/ZnFe2O4 nanocomposites10.1016/j.materresbull.2014.05.013 ↗
54. Magnetically separable CdS/ZnFe2O4 composites with highly efficient photocatalytic activity and photostability under visible light10.1021/acsanm.7b00243 ↗
55. Evaluation of MnO2-templated iron oxide-coated diatomites for their catalytic performance in heterogeneous photo Fenton-like system10.1016/j.jhazmat.2017.10.018 ↗
56. Graphene: status and prospects10.1126/science.1158877 ↗