Transparent sol-gel glass ceramics containing β-NaYF4:Yb3+/Er3+ nanocrystals: Structure, upconversion luminescent properties and optical thermometry behavior

Abstract Transparent bulk glass ceramics (GCs) containing β − NaY F 4 : Yb 3 + / Er 3 + upconversion nanocrystals were successfully prepared via a new sol-gel route for the first time. The structure, composition and morphology of the as-fabricated glass ceramics are characterized by X-ray diffraction ( XRD ), scanning electron microscopy ( SEM ) and transmission electron microscopy ( TEM ), which confirm the segregation of β-NaYF 4 nanocrystals in silica glass matrix with the maintenance of their crystalline phase and microstructure. More significantly, intense upconversion (UC) emissions can be realized for Yb 3 + / Er 3 + co-doped glass ceramics by profiting from low-phonon-energy environment of erbium ions in β-NaYF 4 nanophase. Furthermore, temperature-dependent UC emission performance of the present GC is systematacially investigated to explore their potential application in optical thermometry. Obviously, owing to intense UC emissions of β − NaY F 4 : Yb 3 + / Er 3 + nanocrystals and high transparency, superior chemical/mechanical stability of oxide glassy matrix, the as-fabricated GCs exhibit good temperature sensing performance and good thermostability for precise temperature detecting. It is expected that the preliminary research can give a reference for designing new transparent bulk GCs and may exploit a valid method for developing high-performance optical temperature sensors.