journal article·2021-01

Characterization and corrosion behavior of plasma sprayed calcium silicate reinforced hydroxyapatite composite coatings for medical implant applications

Jarnail Singh, Sukhpal Singh Chatha, Hazoor Singh

Ceramics International· Volume 47· Issue 1
Publisher page

Abstract

Abstract Titanium and its alloys are widely used for medical implant applications, but their corrosion in the physiological environment leads to the discharge of metal ions, which can trigger severe health issues. In the present study, calcium silicate reinforced hydroxyapatite (HA-CS) coatings were deposited on the Ti6Al4V substrate by using atmospheric plasma spray (APS) process with an aim to improve the corrosion resistance and bioactivity. The coatings were prepared by varying the weight percentage (wt %) of calcium silicate (CS) reinforcement in hydroxyapatite (HA) as Ha/x CS (x = 0, 10, 20 wt %). The SEM analysis of the pure HA coating revealed the presence of surface microcracks, whereas HA-CS coatings displayed the crack-free surface morphology. The corrosion investigation revealed that with the progressive increment of CS content in HA coating, the corrosion resistance of HA-CS coatings improved. In addition, surface roughness, porosity, microhardness and crystallinity increased with the increase of CS content in HA. The findings of this study indicate that the development of plasma sprayed HA-CS coatings is a promising approach to improve the performance of Ti6Al4V alloy for medical implant applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Bone Tissue Engineering Materials · Magnesium Alloys: Properties and Applications · Titanium Alloys Microstructure and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (59)

Show source-provided references
1. Synthesis and characterization of hydroxyapatite-based coatings for medical implants obtained on chemically modi fi ed Ti6Al4V substrates10.1016/j.surfcoat.2011.05.040 ↗
2. Biocorrosion behavior and cell viability of adhesive polymer coated magnesium based alloys for medical implants10.1016/j.apsusc.2012.08.051 ↗
3. Intra-operatively customized implant coating strategies for local and controlled drug delivery to bone ☆10.1016/j.addr.2012.05.016 ↗
4. Applications of plasma coatings in artificial joints:an overview10.1016/j.vacuum.2003.12.160 ↗
5. A review on nickel-free nitrogen containing austenitic stainless steels for biomedical applications10.1016/j.msec.2013.06.002 ↗
6. Plasma surface modi fi cation of magnesium alloy for biomedical application10.1016/j.surfcoat.2010.07.045 ↗
7. Gradient titanium and silver based carbon coatings deposited on AISI316L10.1016/j.apsusc.2012.12.088 ↗
8. Significance of calcium phosphate coatings for the enhancement of new bone osteogenesis – a review q10.1016/j.actbio.2013.10.036 ↗
9. Pulsed laser deposition of pseudowollastonite coatings10.1016/S0142-9612(01)00335-0 ↗
10. Hydroxyapatite coating containing multi-walled carbon nanotubes on AZ31 magnesium: mechanical-electrochemical degradation in a physiological environment10.1016/j.ceramint.2018.02.015 ↗
11. Phase stability and biological property evaluation of plasma sprayed hydroxyapatite coatings for orthopedic and dental applications10.1016/j.actbio.2015.01.022 ↗
12. Mechanical properties of nanodiamond-reinforced hydroxyapatite composite coatings deposited by suspension plasma spraying10.1016/j.apsusc.2018.01.014 ↗
13. Wear behavior of plasma sprayed hydroxyapatite bioceramic coating in simulated body fluid
14. Dissolution and mineralization behaviors of HA coatings10.1016/S0142-9612(03)00371-5 ↗
15. Functional bioactive glass topcoats on hydroxyapatite coatings: analysis of microstructure and in-vitro bioactivity10.1016/j.surfcoat.2013.12.023 ↗
16. In-vitro assessment of HA-Nb coating on Mg alloy ZK60 for biomedical applications10.1016/j.matchemphys.2019.04.037 ↗
17. Analysis of corrosion behavior and surface properties of plasma- sprayed HA/Ta coating on CoCr alloy10.1007/s11666-018-0786-z ↗
18. Corrosion behavior of plasma sprayed hydroxyapatite and hydroxyapatite-silicon oxide coatings on AISI 304 for biomedical application10.1016/j.apsusc.2013.08.013 ↗
19. Improvement in mechanical properties of plasma sprayed hydroxyapatite coatings by Al2O3 reinforcement10.1016/j.msec.2013.03.005 ↗
20. Materials Today : proceedings In-vitro performance of reinforced hydroxyapatite coatings deposited using vacuum plasma spray technique on Ti-6Al-4V
21. Corrosion behaviour of plasma sprayed graphene nanoplatelets reinforced hydroxyapatite composite coatings in simulated body fl uid
22. Characterization of gas tunnel type plasma sprayed hydroxyapatite-nanostructure titania composite coatings10.1016/j.apsusc.2015.04.036 ↗
23. Balani · Tribological behavior of plasma-sprayed carbon nanotube-reinforced hydroxyapatite coating in physiological solution, · 2007 · 3 · 944
24. Singh · 2019 · 1
25. Microstructure, corrosion properties and bio-compatibility of calcium zinc phosphate coating on pure iron for biomedical application10.1016/j.msec.2013.09.010 ↗
26. TiO 2/CaF2 composite coating on titanium for biomedical application10.1016/j.matlet.2013.12.006 ↗
27. Incorporation of wollastonite bioactive ceramic with titanium for medical applications : an overview
28. Mechanical and microstructure of reinforced hydroxyapatite/calcium silicate nano-composites materials10.1016/j.matdes.2012.08.020 ↗
29. Fabrication and characterization of hydroxyapatite/wollastonite composite bioceramics with controllable properties for hard tissue repair10.1111/j.1551-2916.2010.04046.x ↗
30. Electrodeposition of porous hydroxyapatite/calcium silicate composite coating on titanium for biomedical applications10.1016/j.apsusc.2013.01.187 ↗
31. Mechanical and bioactive behavior of hydroxyapatite wollastonite sintered composites10.1111/j.1744-7402.2009.02377.x ↗
32. Feng · 2014 · 97 · 47
33. Wollastonite/hydroxyapatite scaffolds with improved mechanical , bioactive and biodegradable properties for bone tissue engineering10.1016/j.ceramint.2012.06.073 ↗
34. Synthesis and characterization of nanocomposite powders composed of hydroxyapatite nanoparticles and wollastonite nanowires10.1111/j.1744-7402.2009.02474.x ↗
35. A facile route to the synthesis of hydroxyapatite/wollastonite composite powders by a two-step
36. Synthesis and characterization of hydroxyapatite wollastonite composite powders by sol – gel processing10.1111/j.1744-7402.2008.02212.x ↗
37. Poorly crystallized hydroxyapatite and calcium silicate hydrate composites : synthesis , characterization and soaking in simulated body fl uid10.1016/j.matchar.2020.110158 ↗
38. Surface characterization of plasma sprayed pure and reinforced hydroxyapatite coating on Ti6Al4V alloy10.1016/j.surfcoat.2011.04.064 ↗
39. Studies on corrosion resistance and bio-activity of plasma spray deposited hydroxylapatite (HA) based TiO 2 and ZrO 2 dispersed composite coatings on titanium alloy (Ti-6Al-4V) and the same after post spray heat treatment10.1016/j.apsusc.2017.05.208 ↗
40. Mechanical and chemical properties of Baghdadite coatings manufactured by atmospheric plasma spraying10.1016/j.surfcoat.2019.124945 ↗
41. Microstructure and surface mechanical properties of plasma spray deposited and post spray heat treated hydroxyapatite (HA) based composite coating on titanium alloy (Ti-6Al-4V) substrate10.1016/j.matchar.2017.06.011 ↗
42. In vitro investigation of Nb e Ta alloy coating deposited on CoCr alloy for biomedical implants10.1016/j.surfcoat.2019.124932 ↗
43. Study of the Ca/P atomic ratio of the amorphous phase in plasma-sprayed hydroxyapatite coatings10.1016/S0022-4596(02)00085-3 ↗
44. Phase evolution of hydroxapatite coatings suspension plasma sprayed using variable parameters in simulated body fl uid10.1016/j.surfcoat.2009.10.022 ↗
45. Enhancement of protein adsorption induced by surface roughness10.1021/la0621923 ↗
46. Investigation of corrosion behavior and surface properties of plasma sprayed HA/Sr reinforced coatings on CoCr alloys10.1016/j.matchemphys.2020.123330 ↗
47. Effect of surface roughness of hydroxyapatite on human bone marrow cell adhesion, proliferation, differentiation and detachment strength10.1016/S0142-9612(00)00174-5 ↗
48. Variation of roughness and adhesion strength of deposited apatite layers on titanium dental implants10.1016/j.msec.2010.09.018 ↗
49. Effects of TiO 2 on microstructural , mechanical properties and in-vitro bioactivity of plasma sprayed yttria stabilised zirconia coatings for dental application10.1016/j.ceramint.2017.12.008 ↗
50. Application of response surface methodology in the design of functionally graded plasma sprayed hydroxyapatite coatings Tanya10.1016/j.surfcoat.2017.01.113 ↗
51. Evaluation of the mechanical properties of plasma sprayed hydroxyapatite coatings10.1016/j.apsusc.2014.02.125 ↗
52. Surface & Coatings Technology E ff ect of post-heat treatment on the microstructure of micro-plasma sprayed hydroxyapatite coatings10.1016/j.surfcoat.2019.03.056 ↗
53. U · 2001 · 141 · 269
54. Liu · 2002 · 153 · 173
55. Mechanical properties and dissolution behavior of plasma sprayed wollastonite coatings deposited at different substrate temperatures10.1007/s11666-011-9699-9 ↗
56. Titania/hydroxyapatite bi-layer coating on Ti metal by electrophoretic deposition : characterization and corrosion studies10.1016/j.ceramint.2011.12.026 ↗
57. In vitro corrosion behavior and cytocompatibility of pure Fe implanted with Ta
58. Effect of Sr on the bioactivity and corrosion resistance of nanoporous niobium oxide coating for orthopaedic applications10.1016/j.msec.2013.12.016 ↗
59. Structural and corrosion characterization of hydroxyapatite/zirconium nitride-coated AZ91 magnesium alloy by ion beam sputtering10.1016/j.apsusc.2017.01.022 ↗