Surface modification of Li1.3Al0.3Ti1.7(PO4)3 ceramic electrolyte by Al2O3-doped ZnO coating to enable dendrites-free all-solid-state lithium-metal batteries
Source abstract
Abstract
Abstract The Na+ super-ionic conductor (NASICON) type solid electrolytes Li1.3Al0.3Ti1.7(PO4)3 (LATP) are of increasing interest because of their high total ionic conductivity and excellent stability against moist air. However, they are not stable when contacting with lithium metal because of the rapid Ti4+ reduction by Li metal, which greatly restrict their application in lithium batteries. Here, we propose a Al2O3-doped ZnO (AZO) surface coating method by magnetron sputtering to improve the stability of the Li1.3Al0.3Ti1.7(PO4)3 electrolyte against the attack of lithium-metal anode and to avoid the growth of lithium dendrite. The Al2O3-doped ZnO coating of the electrolyte Li1.3Al0.3Ti1.7(PO4)3 demonstrates high chemical stability against the attack of lithium-metal in a wide electrochemical potential ranges (>5 V), as well as an excellent performance of suppressing of lithium dendrites. Furthermore, the Al2O3-doped ZnO coated Li1.3Al0.3Ti1.7(PO4)3 was found to be the candidate electrolyte for the all-solid-state lithium battery. An all-solid-state Li/LiFePO4 battery with Al2O3-doped ZnO coated Li1.3Al0.3Ti1.7(PO4)3 as the solid electrolyte shows good cyclability and a high columbic efficiency for 50 charge/discharge cycles. Furthermore, the surface-modified electrolyte Li1.3Al0.3Ti1.7(PO4)3 by Al2O3-doped ZnO coating also enables the lithium metal battery to exhibit extremely long cycling for nearly 1000 h due to the ability of suppressing of lithium dendrites.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (42)
Show source-provided references
1. Li7La3Zr2O12 interface Modification for Li dendrite prevention10.1021/acsami.6b00831 ↗
2. Flexible, solid-state, ion-conducting membrane with 3D garnet nanofiber networks for lithium batteries10.1073/pnas.1600422113 ↗
3. Oxide electrolytes for lithium batteries10.1111/jace.13844 ↗
4. Challenges in the development of advanced Li-ion batteries: a review10.1039/c1ee01598b ↗
5. Challenges and perspectives of garnet solid electrolytes for all solid-state lithium batteries10.1016/j.jpowsour.2018.04.019 ↗
6. In-situ scanning electron microscopy observations of Li plating and stripping reactions at the lithium phosphorus oxynitride glass electrolyte/Cu interface10.1016/j.jpowsour.2012.10.026 ↗
7. All solid state lithium batteries based on lamellar garnet-type ceramic electrolytes10.1016/j.jpowsour.2015.09.061 ↗
8. Preparation and evaluation of high lithium ion conductivity Li1.3Al0.3Ti1.7(PO4)3 solid electrolyte obtained using a new solution method10.1016/j.ssi.2016.07.010 ↗
9. Lithium diffusion Pathway in Li1.3Al0.3Ti1.7(PO4)3 (LATP) superionic conductor10.1021/acs.inorgchem.5b02821 ↗
10. Rechargeable sodium all-solid-state battery10.1021/acscentsci.6b00321 ↗
11. Composite electrolyte for all-solid-state lithium batteries: low-temperature fabrication and conductivity enhancement10.1002/cssc.201700104 ↗
12. Recent advances in all-solid-state rechargeable lithium batteries10.1016/j.nanoen.2017.01.028 ↗
13. Efficient storing energy harvested by triboelectric nanogenerators using a safe and durable all-solid-state sodium-ion battery10.1002/advs.201700072 ↗
14. Synthesis of Li1.3Al0.3Ti1.7(PO4)3 by sol–gel technique10.1016/j.matlet.2003.09.013 ↗
15. Mastering the interface for advanced all-solid-state10.1073/pnas.1615912113 ↗
16. Effects of synthesis conditions on the structural, stability and ion conducting properties of Li0.30(La0.50Ln0.50)0.567TiO3 (Ln=La, Pr, Nd) solid electrolytes for rechargeable lithium batteries10.1016/j.ceramint.2014.01.097 ↗
17. Lithium conducting solid electrolyte Li1.3Al0.3Ti1.7(PO4)3 obtained via solution chemistry10.1016/j.jeurceramsoc.2012.08.005 ↗
18. Electrolytic stability Limit and rapid lithium Insertion in the fast-ion-conducting Li0.29La0.57TiO3 perovskite-type compound10.1149/1.1837713 ↗
19. W-doped Li7La3Zr2O12 ceramic Electrolytes for solid state Li-ion batteries10.1016/j.electacta.2015.08.046 ↗
20. Hybrid polymer/garnet electrolyte with a small interfacial resistance for lithium-ion batteries10.1002/anie.201608924 ↗
21. A durable and safe solid-state lithium battery with a hybrid electrolyte membrane10.1016/j.nanoen.2018.01.028 ↗
22. Imaging the diffusion pathway of Al3+ ion in NASICON-type (Al0.2Zr0.8)20/19Nb(PO4)3 as electrolyte for rechargeable solid-state Al batteries10.1088/1674-1056/27/12/128201 ↗
23. Influence of LiBO2 addition on the microstructure and lithium-ion conductivity of Li1+xAlxTi2−x(PO4)3 (x = 0.3) ceramic electrolyte10.1016/j.ceramint.2018.01.058 ↗
24. Facile Synthesis of nanosized lithium-ion-conducting solid electrolyte Li1.4Al0.4Ti1.6(PO4)3 and its mechanical Nanocomposites with LiMn2O4 for enhanced cyclic Performance in lithium ion batteries10.1021/acsami.6b16233 ↗
25. Pechini synthesis of high ionic conductivity Li1.3Al0.3Ti1.7(PO4)3 solid electrolytes: The effect of dispersant10.1016/j.jallcom.2016.04.173 ↗
26. Preparation of LiCoO2/Li1.3Al0.3Ti1.7(PO4)3 composite cathode granule for all-solid-state lithium-ion batteries by simple mechanical method10.1016/j.apt.2015.10.013 ↗
27. A high-performance and durable poly(ethylene oxide)-based composite solid electrolyte for all solid-state lithium battery10.1021/acs.jpcc.8b02556 ↗
28. Inorganic solid Li ion conductors: an overview10.1016/j.ssi.2009.03.022 ↗
29. The synergistic effect of dual substitution of Al and Sb on structure and ionic conductivity of Li7La3Zr2O12 ceramic10.1016/j.ceramint.2017.10.072 ↗
30. Fabrication of LiNi0.5Mn1.5O4 thin film cathode by PVP sol–gel process and its application of all-solid-state lithium ion batteries using Li1+xAlxTi2−x(PO4)3 solid electrolyte10.1016/j.ssi.2011.12.018 ↗
31. A new kind of all-solid-state thin-film-type lithium-ion battery developed by applying a D.C. high voltage10.1016/j.elecom.2006.03.003 ↗
32. Control of interface of glass-ceramic electrolyte/liquid electrolyte for aqueous lithium batteries10.1016/j.jpowsour.2013.04.071 ↗
33. 2D boron nitride nanoflakes as a multifunctional additive in gel polymer electrolytes for safe, long cycle life and high rate lithium metal batteries10.1039/C7EE01095H ↗
34. Transparent conducting aluminum-doped zinc oxide thin films for organic light-emitting devices10.1063/1.125740 ↗
35. Conformal, nanoscale ZnO surface modification of garnet-based solid-state electrolyte for lithium metal anodes10.1021/acs.nanolett.6b04695 ↗
36. Effects of MgO Coating on the Structural and electrochemical Characteristics of LiCoO2 as cathode Materials for lithium ion battery10.1021/cm403846a ↗
37. Comparison of Al2O3- and AlPO4-coated LiCoO2 cathode materials for a Li-ion cell10.1016/j.jpowsour.2005.03.118 ↗
38. Highly stable inverted organic photovoltaics using aluminum-doped zinc oxide as electron transport layers10.1016/j.jpowsour.2014.11.011 ↗
39. Superior electrochemical performance of LiCoO2 electrodes enabled by conductive Al2O3-doped ZnO coating via magnetron sputtering10.1016/j.jpowsour.2015.08.031 ↗
40. Sputtering TiO2 on LiCoO2 composite electrodes as a simple and effective coating to enhance high-voltage cathode performance10.1016/j.jpowsour.2017.02.035 ↗
41. Negating interfacial impedance in garnet-based solid-state Li metal batteries10.1038/nmat4821 ↗
42. Investigation on the enhanced electrochemical performances of Li1.2Ni0.13Co0.13Mn0.54O2 by surface modification with ZnO10.1016/j.electacta.2015.05.084 ↗