journal article·2014-07

Enhancing the photocatalytic degradation of salicylic acid by using molecular imprinted S-doped TiO2 under simulated solar light

Zhiqiang Wang, Xiang Liu, Wenqiang Li, Huiying Wang, Hexing Li

Ceramics International· Volume 40· Issue 6
Publisher page

Abstract

Molecular imprinted polymer coated S-doped TiO2 (MIP/S-TiO2) nanocomposites were successfully synthesized by a surface molecular imprinting technique using p-phenylenediamine as the functional monomer and salicylic acid as the template molecule. The structure and properties of the catalysts were characterized by X-ray diffraction, scanning electron microscopy, and UV–vis diffuse reflectance spectra. Compared with TiO2 nanoparticles, the absorption edge of MIP/S-TiO2 nanocomposites was enhanced over the whole range of visible region. Moreover, MIP/S-TiO2 nanocomposites showed higher adsorption capacity for salicylic acid than for S-TiO2 nanoparticles. The rate constant for the photodegradation of salicylic acid over MIP/S-TiO2 nanocomposites was 1.7 times that of salicylic acid over S-TiO2 nanoparticles, which was attributed to the molecular recognition ability of MIP/S-TiO2 nanocomposites for the target molecules.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · Advanced Nanomaterials in Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Electrochemical photocatalysis of water at a semiconductor electrode10.1038/238037a0 ↗
2. Environmental applications of semiconductor photocatalysis10.1021/cr00033a004 ↗
3. Scaling properties in photocatalysis10.1016/S0920-5861(00)00246-7 ↗
4. Visible-light photocatalysis in nitrogen-doped titanium oxides10.1126/science.1061051 ↗
5. Studies on nitrogen modified TiO2 photocatalyst prepared in different conditions10.1016/j.materresbull.2010.06.024 ↗
6. Photocatalytic properties of phosphor-doped titania nanoparticles10.1016/j.apcatb.2007.03.016 ↗
7. Supercritical preparation of a highly active S-doped TiO2 photocatalyst for methylene blue mineralization10.1021/es062680x ↗
8. Hydrothermal synthesis of S-doped TiO2 nanoparticles and their photocatalytic ability for degradation of methyl orange10.1016/j.ceramint.2008.05.003 ↗
9. Band gap narrowing of titanium dioxide by sulfur doping10.1063/1.1493647 ↗
10. Visible light-induced degradation of methylene blue on S-doped TiO210.1246/cl.2003.330 ↗
11. Synthesis of highly active sulfate-promoted rutile titania nanoparticles with a response to visible light10.1021/jp045676l ↗
12. Low-temperature hydrothermal synthesis of S-doped TiO2 with visible light photocatalytic activity10.1016/j.jssc.2006.01.009 ↗
13. Heterogeneous water phase catalysis as an environmental application: a review10.1016/S0045-6535(02)00168-6 ↗
14. Single-crystal-like titania mesocages10.1002/anie.201004972 ↗
15. Discrimination between enantiomers of structurally related molecules: separation of benzodiazepines by molecularly imprinted polymers10.1021/ja9926313 ↗
16. Molecularly-imprinted polymers: useful sorbents for selective extractions10.1016/j.trac.2010.07.020 ↗
17. Molecularly imprinted polymers: present and future prospective10.3390/ijms12095908 ↗
18. Synthesis of molecular imprinted polymer coated photocatalysts with high selectivity10.1039/b615303h ↗
19. Enhanced photocatalytic decomposition of 4-nonylphenol by surface-organografted TiO2: a combination of molecular selective adsorption and photocatalysis10.1016/j.apcatb.2004.04.013 ↗
20. Enhanced photocatalytic degradation and selective removal of nitrophenols by using surface molecular imprinted titania10.1021/es071788p ↗
21. Enhanced photocatalytic degradation of tetracycline hydrochloride by molecular imprinted film modified TiO2 nanotubes10.1007/s11434-011-4897-x ↗
22. Preferential photodegradation of contaminants by molecular imprinting on titanium dioxide10.1016/j.apcatb.2009.12.024 ↗
23. Simple fabrication and photocatalytic activity of S-doped TiO2 under low power LED visible light irradiation10.1016/j.ceramint.2009.04.021 ↗
24. Preparation of conductive polypyrrole/TiO2 nanocomposite via surface molecular imprinting technique and its photocatalytic activity under simulated solar light irradiation10.1016/j.colsurfa.2011.12.029 ↗
25. Preparation of poly-o-phenylenediamine/TiO2/fly-ash cenospheres and its photo-degradation property on antibiotics10.1016/j.apsusc.2009.12.038 ↗