journal article·2009-03

The effect of Fe2O3 addition on tialite formation

H.R. Rezaie, R. Naghizadeh, N. Farrokhnia, S. Arabi, M. sobhani

Ceramics International· Volume 35· Issue 2
Publisher page

Abstract

Abstract Aluminium titanate (Al2TiO5) exhibits interesting properties, such as low thermal expansion, high thermal shock resistance, high refractoriness, and good corrosion resistance. In this research, effect of hematite (Fe2O3) addition on the formation temperature of Al2TiO5 was studied starting from very fine (micronsized) rutile (TiO2) and aluminum hydrate (Al(OH)3) powders. Samples with (0, 2.5, 5, 7.5, and 10) wt.% hematite were prepared for comparison. Identification of phases was accomplished using X-ray diffraction. The samples were characterized by simultaneous thermal analysis and microstructural analysis using scanning electron microscopy. The addition of Fe2O3 changes the mechanism of tialite formation. The main results are reduction in tialite formation temperature down to 1150 °C, tialite grains growth, and decrease of porosity.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced ceramic materials synthesis · MXene and MAX Phase Materials · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (20)

Show source-provided references
1. Combustion synthesis of aluminum titanate10.1016/S0955-2219(98)00004-1 ↗
2. Aluminum titanate—a literature review. Part 2. Engineering properties and thermal stability
3. Thermal stabilization of aluminium titanate and properties of aluminium titanate solid solution10.1007/BF02387756 ↗
4. Structure studies on Al2TiO5 at room temperature and at 600°C10.1107/S0567740872003681 ↗
5. Improved thermal stability of Al-titanate solid solutions
6. Grain size/microcracking relations for pseudobrookite oxides10.1111/j.1151-2916.1978.tb16121.x ↗
7. K. Hamano, Y. Ohya, Z. Nakagawa, Crack propagation resistance of aluminium titanate ceramics, J. Int. High-Tech. Ceram., Elsevier Applied Science Publishers Ltd., Great Britain (1985), 129–137.10.1016/0267-3762(85)90004-9 ↗
8. Aluminum titanate—a literature review. Part 1. Microcracking phenomena
9. Decomposition temperature of β-Al2TiO510.1111/j.1151-2916.1980.tb10745.x ↗
10. Reaction sintered aluminium titanate10.1007/BF01730486 ↗
11. Preparation of alkoxides for the synthesis of ceramics10.1016/0272-8842(86)90039-8 ↗
12. Preparation of composite Al2O3–TiO2 particles from organo-metallic precursors and transformation during heating10.1007/BF01106567 ↗
13. Low-temperature heat capacities and entropies at 298.16K of some titanates of aluminum, calcium, lithium and zinc10.1021/ja01613a032 ↗
14. High temperature heat contents of some titanates of aluminium, iron and zinc10.1021/ja01613a033 ↗
15. Thermodynamics of formation of some compounds with the pseudobrookite structure and of the Fe2TiO5–Ti3O5 solid solution series
16. Aluminum titanate formation by solid-state reaction of fine Al2O3 and TiO2 powders10.1111/j.1151-2916.1987.tb04849.x ↗
17. Aluminum titanate formation by solid-state reaction of coarse Al2O3 and TiO2 powders10.1111/j.1151-2916.1988.tb05755.x ↗
18. Calculated X-ray powder diffraction data for beta Al2TiO510.1111/j.1151-2916.1973.tb12462.x ↗
19. The formation and decomposition of aluminium titanate. 1. The reaction of formation of aluminium titanate
20. Sintering behavior of Al2TiO5 base ceramics and their thermal properties10.1016/S0272-8842(98)00083-2 ↗