Properties of aerosol deposited NASICON-type Li1.5Al0.5Ge1.5(PO4)3 solid electrolyte thin films
Source abstract
Abstract
Abstract NASICON-type Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 (LAGP) solid electrolyte thin films were fabricated without any heat treatment by aerosol deposition (AD). Ball-milled LAGP powders with different particle sizes were used as raw material and deposited directly on a stainless steel substrate via room temperature impact consolidation. X-ray diffraction patterns revealed that as-deposited LAGP film has a same crystal structure with raw LAGP powder and no secondary phases are formed during deposition. SEM observation showed that film consists of fractured LAGP nanoparticles but the porosity is strongly influenced by an averaged particle size of raw LAGP powder. Maximum total (bulk+grain-boundary) ionic conductivity at room temperature in aerosol deposited (ADed) LAGP film was 0.5×10 −5 S cm −1 , while the bulk conductivity of film was approximately 10 −4 S cm −1 , which is comparable with the bulk property of LAGP as previously reported. Therefore, lower total conductivity of ADed LAGP film is mainly attributed to large grain-boundary resistance between the LAGP nanoparticles in the film. Improvement of film density and the connectivity among the LAGP nanoparticles in the film should be needed to enhance the total conductivity.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (49)
Show source-provided references
1. Progress and prospective of solid-state lithium batteries10.1016/j.actamat.2012.10.034 ↗
2. Recent development of sulfide solid electrolytes and interfacial modification for all-solid-state rechargeable lithium batteries10.1016/j.jascer.2013.03.005 ↗
3. Recent developments in garnet based solid state electrolytes for thin film batteries10.1016/j.cossms.2013.10.002 ↗
4. Fast Li+ ion conducting glass-ceramics in the system Li2O–Al2O3–GeO2–P2O510.1016/S0167-2738(97)00434-7 ↗
5. Lithium ion conducting glass-ceramics of Li1.5Al0.5Ge1.5(PO4)3–xLi2O (x=0.0–0.20) with good electrical and electrochemical properties10.1111/j.1551-2916.2007.01827.x ↗
6. Correlation between micro-structural properties and ionic conductivity of Li1.5Al0.5Ge1.5(PO4)3 ceramics10.1016/j.jpowsour.2011.03.065 ↗
7. Increase in grain boundary ionic conductivity of Li1.5Al0.5Ge1.5(PO4)3 by adding excess lithium10.1016/j.ssi.2014.05.016 ↗
8. All solid state lithium ion rechargeable batteries using NASICON structured electrolyte10.1179/1753555713Y.0000000085 ↗
9. Influence of phosphorus sources on lithium ion conducting performance in the system of Li2O–Al2O3–GeO2–P2O5 glass-ceramics10.1016/j.ssi.2014.12.013 ↗
10. Lithium storage capability of lithium ion conductor Li1.5Al0.5Ge1.5(PO4)310.1016/j.jallcom.2010.04.084 ↗
11. Ionic conductivity of the lithium titanium phosphate (Li1+XMXTi2−X(PO4)3, M=Al, Sc, Y, and La) systems10.1149/1.2096693 ↗
12. Ionic conductivity of solid electrolytes based on lithium titanium phosphate10.1149/1.2086597 ↗
13. Superionic conductivity of glass-ceramics in the system Li2O–Al2O3–TiO2–P2O510.1016/S0167-2738(97)00018-0 ↗
14. High ionic conductivity in lithium lanthanum titanate10.1016/0038-1098(93)90841-A ↗
15. A rechargeable lithium-air battery using a lithium ion-conducting lanthanum lithium titanate ceramics as an electrolyte separator10.1016/j.jpowsour.2012.11.098 ↗
16. Ionic conductivity, lithium insertion and extraction of lanthanum lithium titanate10.1016/S0167-2738(01)00884-0 ↗
17. Lithium storage in perovskite lithium lanthanum titanate10.1016/j.elecom.2013.03.038 ↗
18. Fast lithium ion conduction in garnet-type Li7La3Zr2O1210.1002/anie.200701144 ↗
19. The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li7La3Zr2O1210.1016/j.ssi.2011.10.022 ↗
20. Phase transformation of the garnet structured lithium ion conductor: Li7La3Zr2O1210.1016/j.ssi.2013.09.027 ↗
21. Synthesis and properties of Al-free Li7−xLa3Zr2−xTaxO12 garnet related oxides10.1016/j.ssi.2013.09.008 ↗
22. Preparation of positive LiCoO2 films by electron cyclotron resonance (ECR) plasma sputtering method and its application to all-solid-state thin-film lithium batteries10.1016/j.jpowsour.2007.06.081 ↗
23. A lithium phosphorous oxynitride (LiPON) film sputtered from unsintered Li3PO4 powder target10.1016/j.ssi.2011.04.001 ↗
24. Ionic conductivity properties of amorphous Li–La–Zr–O solid electrolyte for thin film batteries10.1016/j.ssi.2012.09.011 ↗
25. Fabrication and ionic conductivity of amorphous Li–Al–Ti–P–O thin film10.1016/j.jnoncrysol.2011.05.023 ↗
26. Fabrication and characterization of Li7La3Zr2O12 thin films for lithium ion battery10.1149/2.013206ssl ↗
27. Epitaxial growth and lithium ion conductivity of lithium-oxide garnet for an all solid-state battery electrolyte10.1039/c3dt51795k ↗
28. Preparation and characterization of lithium-ion-conductive Li1.3Al0.3Ti1.7(PO4)3 thin films by the solution deposition10.1016/S0040-6090(02)01094-5 ↗
29. Sol–gel preparation of Li+ ion conductive thin film10.1016/S0169-4332(01)01007-8 ↗
30. Preparation of lithium ion conductive Al-doped Li7La3Zr2O12 thin films by a sol–gel process10.1016/j.jpowsour.2014.09.164 ↗
31. Aerosol deposition of ceramic thick films at room temperature: densification mechanism of ceramic layers10.1111/j.1551-2916.2006.01030.x ↗
32. Piezoelectric properties and poling effect of Pb(Zr,Ti)O3 thick films prepared for microactuators by aerosol deposition10.1063/1.1309029 ↗
33. Powder preparation in aerosol deposition method for lead zirconate titanate thick films10.1143/JJAP.41.6669 ↗
34. Fabrication and ferroelectric properties of highly dense lead-free piezoelectric (K0.5Na0.5)NbO3 thick films by aerosol deposition10.1063/1.2720751 ↗
35. Photocatalytic TiO2 thin films by aerosol-deposition: from micron-sized particles to nano-grained thin film at room temperature10.1016/j.apcatb.2008.01.020 ↗
36. Enhanced thermoelectric properties of Textured Ca3Co4O9 thick film by aerosol deposition10.1111/j.1551-2916.2010.03674.x ↗
37. Preparation of lithium aluminum titanium phosphate electrolytes thick films by aerosol deposition method10.1111/j.1551-2916.2011.04551.x ↗
38. Microstructure and ionic conductivity in Li7La3Zr2O12 film prepared by aerosol deposition method10.1149/2.0411501jes ↗
39. Anode properties of Cu-coated Si thick film electrodes prepared by electroless deposition and gas-deposition10.5796/electrochemistry.76.329 ↗
40. Anode properties of Ru-coated Si thick film electrodes prepared by gas-deposition10.1016/j.jpowsour.2009.12.072 ↗
41. Anode properties of thick-film electrodes prepared by gas deposition of Ni-coated Si particles10.1016/j.jpowsour.2010.10.013 ↗
42. Anode properties of composite thick-film electrodes consisted of Si and various metal silicides10.1016/j.jpowsour.2010.12.027 ↗
43. Cathode performance of LiMn2O4 thick films prepared by gas-deposition for lithium rechargeable battery10.5796/electrochemistry.76.293 ↗
44. LiNi0.4Co0.3Mn0.3O2 thin film electrode by aerosol deposition10.1186/1556-276X-7-64 ↗
45. Preparation of thick-film LiNi1/3Co1/3Mn1/3O2 electrodes by aerosol deposition and its application to all-solid-state batteries10.1016/j.jpowsour.2014.09.038 ↗
46. Electrochemical properties of an as-deposited LiFePO4 thin film electrode prepared by aerosol deposition10.1016/j.jpowsour.2012.12.108 ↗
47. Characterization of as-deposited Li4Ti5O12 thin film electrode prepared by aerosol deposition method10.1016/j.jpowsour.2013.12.084 ↗
48. Microstructure and electrochemical properties of iron oxide film fabricated by aerosol deposition method for lithium ion battery10.1016/j.jpowsour.2014.11.033 ↗
49. Structure and thermal expansion of LiGe2(PO4)310.1016/0022-4596(91)90134-4 ↗