journal article·2016-02Open access

Acceptor doping effects in (K0.5Na0.5)NbO3 lead-free piezoelectric ceramics

Kepi Chen, Fangli Zhang, Dianshan Li, Jing Tang, Yanlin Jiao, Linan An

Ceramics International· Volume 42· Issue 2

Abstract

Abstract In this paper, the effects of acceptor dopants on the synthesis, sintering and properties of KNN ceramics were studied for (K 0.5 Na 0.5 )(Nb 0.994 A 0.006 )O 3− δ (A=Ge 4+ , Ga 3+ , Zn 2+ , Mn 2+ , Ni 2+ , and Cu 2+ ) ceramics. The results reveal that the eutectic phase(s) is (are) formed between the acceptor oxide and alkali metal carbonate, thereby significantly improving the sinterability of the materials. Compared to the trivalent and tetravalent acceptor dopants, divalent dopant can lead to higher Q m values, most likely due to the formation of defect complexes.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Acoustic Wave Resonator Technologies · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (27)

Show source-provided references
1. Lead-free piezoceramics10.1038/nature03028 ↗
2. Lead-free piezoelectric ceramics: alternatives for PZT?10.1007/s10832-007-9047-0 ↗
3. Perspective on the development of lead-free piezoceramics10.1111/j.1551-2916.2009.03061.x ↗
4. (K, Na)NbO3-based lead-free piezoceramics: fundamental aspects, processing technologies, and remaining challenges10.1111/jace.12715 ↗
5. Transferring lead-free piezoelectric ceramics into application10.1016/j.jeurceramsoc.2014.12.013 ↗
6. Potassium-sodium niobate lead-free piezoelectric materials: past, present, and future of phase boundaries10.1021/cr5006809 ↗
7. Phase transitional behavior and piezoelectric properties of (Na0.5K0.5)NbO3–LiNbO3 ceramics10.1063/1.1813636 ↗
8. Piezoelectric properties in perovskite 0.948(K0.5Na0.5)NbO3-0.052LiSbO3 lead-free ceramics10.1063/1.2382348 ↗
9. Remarkably strong piezoelectricity of lead-free (K0.45Na0.55)0.98Li-0.02(Nb0.77Ta0.18Sb0.05)O3 ceramic10.1111/j.1551-2916.2011.04468.x ↗
10. Lead-free piezoelectrics based on potassium-sodium niobate with giant d3310.1021/am402548x ↗
11. New Lead-Free (1−x)(K0.5Na0.5) NbO3-x(Bi0.5Na0.5)ZrO3 ceramics with high piezoelectricity10.1111/jace.12836 ↗
12. New potassium-sodium niobate material system: a giant-d33 and high-Tc lead-free piezoelectric10.1039/C4DT01293C ↗
13. Processing and piezoelectric properties of lead-free (K,Na)(Nb,Ta)O3 ceramics10.1111/j.1551-2916.2005.00229.x ↗
14. Enhancement of Qm, by co-doping of Li and Cu to potassium sodium niobate lead-free ceramics10.1109/TUFFC.2008.743 ↗
15. Microstructural features and electrical properties of copper oxide added potassium sodium niobate ceramics10.1016/j.ceramint.2010.03.018 ↗
16. Highly enhanced mechanical quality factor in lead-free (K0.5Na0.5)NbO3 piezoelectric ceramics by co-doping with K5.4Cu1.3Ta10O29 and CuO10.1016/j.matlet.2010.04.031 ↗
17. The hardening of CuO-(K,Na)NbO3 via post annealing with argon10.7567/JJAP.53.015503 ↗
18. Screening sintering aids for (K0.5Na0.5)NbO3 ceramics10.1111/jace.13583 ↗
19. Local variations in defect polarization and covalent bonding in ferroelectric Cu2+-doped PZT and KNN functional ceramics at the morphotropic phase boundary10.1039/b905642d ↗
20. Antiferroelectric-like properties and enhanced polarization of Cu-doped K0.5Na0.5NbO3 piezoelectric ceramics10.1063/1.4747212 ↗
21. Interactions of defect complexes and domain walls in CuO-doped ferroelectric (K,Na)NbO310.1063/1.4811268 ↗
22. Analyzing the defect structure of CuO-Doped PZT and KNN piezoelectrics from electron paramagnetic resonance10.1109/TUFFC.2014.3058 ↗
23. Lead-free piezoelectrics based on alkaline niobates: synthesis, sintering and microstructure
24. Effect of calcination conditions and excess alkali carbonate on the phase formation and particle morphology of Na0.5K0.5NbO3 powders10.1111/j.1551-2916.2007.01629.x ↗
25. Influence of Alkaline and niobium excess on sintering and microstructure of sodium-potassium niobate (K0.5 Na0.5)NbO310.1111/j.1551-2916.2010.03578.x ↗
26. Hysteresis in piezoelectric and ferroelectric materials
27. Losses in ferroelectric materials10.1016/j.mser.2015.01.002 ↗