journal article·2019-12

MnO2 nanoneedles loaded on silicon oxycarbide-derived hierarchically porous carbon for supercapacitor electrodes with enhanced electrochemical performance

Haoyu Sun, Jianmei Pan, Xuehua Yan, Wei Shen, Wenqiang Zhong, Xiaonong Cheng

Ceramics International· Volume 45· Issue 18
Publisher page

Abstract

Abstract Manganese oxide nanoneedle/carbide-derived carbon (MnO2/CDC) composite electrodes with hierarchically porous structure for supercapacitors have been obtained by a convenient hydrothermal technology. MnO2 nanoneedles are homogeneously grown on the surface of CDC obtained by etching silicon oxycarbide (SiOC) using sodium hydroxide (NaOH) according to a self-limiting reaction. The as-prepared MnO2/CDC composites possess large specific surface area of 1749.3 m2 g−1, and facilitate to the enhancement of some certain pseudocapacitance. The MnO2/CDC composite electrodes show a high specific capacitance (255.8 F g−1 at 1 A g−1) in a three-electrode system. Additionally, MnO2/CDC electrodes are used to fabricate a symmetrical coin cell supercapacitor. The device delivers the remarkable energy density of 12.6 Wh kg−1 at a power density of 3997.7 W kg−1 and still maintain 92.2% of the capacitance after 2000 cycles. The electrode materials prepared by combining CDC with transition metal oxide have great potential in supercapacitor applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced battery technologies research · Electrochemical sensors and biosensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (45)

Show source-provided references
1. Merging of Kirkendall growth and ostwald ripening: CuO@MnO2 core-shell architectures for asymmetric supercapacitors10.1038/srep04518 ↗
2. Supercapacitor electrode materials: nanostructures from 0 to 3 dimensions10.1039/C4EE03229B ↗
3. One-dimensional assembly of conductive and capacitive metal oxide electrodes for high-performance asymmetric supercapacitors10.1021/acsami.7b00676 ↗
4. Controlled growth of nanostructured MnO2 on carbon nanotubes for high-performance electrochemical capacitors10.1016/j.electacta.2014.11.162 ↗
5. Hydrothermal synthesis of reduced graphene oxide-Mn3O4 nanocomposite as an efficient electrode material for supercapacitors10.1016/j.ceramint.2017.11.062 ↗
6. Hydrothermal synthesis of MoO3 nanobelt-graphene composites10.1002/crat.201100302 ↗
7. Dual functions of activated carbon in a positive electrode for MnO2-based hybrid supercapacitor10.1016/j.jpowsour.2010.12.056 ↗
8. A Controllable synthesis of rich nitrogen-doped ordered mesoporous carbon for CO2 capture and supercapacitors10.1002/adfm.201202764 ↗
9. Ultrahigh surface area meso/microporous carbon formed with self-template for high-voltage aqueous supercapacitors10.1016/j.jpowsour.2017.08.114 ↗
10. Effect of pore size and surface area of carbide derived carbons on specific capacitance10.1016/j.jpowsour.2005.09.008 ↗
11. Preparation and application of cellular and nanoporous carbides10.1039/c2cs15324f ↗
12. Enhanced capacitance of nitrogen-doped hierarchically porous carbide-derived carbon in matched ionic liquids10.1039/C5TA04773K ↗
13. Enhanced hydrogen and methane gas storage of silicon oxycarbide derived carbon10.1016/j.micromeso.2011.03.042 ↗
14. Electrospinning and electrospraying of silicon oxycarbide-derived nanoporous carbon for supercapacitor electrodes10.1016/j.jpowsour.2016.02.077 ↗
15. A facile one-step hydrothermal method to produce graphene–MoO3 nanorod bundle composites10.1016/j.matlet.2011.05.019 ↗
16. NaCl-assisted hydrothermal synthesis of high-quality crystalline α-MoO3 nanobelts10.1002/crat.201100061 ↗
17. Manganese oxide-based materials as electrochemical supercapacitor electrodes10.1039/C0CS00127A ↗
18. Highly transparent supercapacitors based on ZnO/MnO2 nanostructures10.1039/C7NR01320E ↗
19. Biological cell template synthesis of nitrogen-doped porous hollow carbon spheres/MnO2 composites for high-performance asymmetric supercapacitors10.1016/j.electacta.2018.11.074 ↗
20. Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors10.1038/nnano.2011.13 ↗
21. Nanocomposites of hierarchical ultrathin MnO2 nanosheets/hollow carbon nanofibers for high-performance asymmetric supercapacitors10.1016/j.apsusc.2018.09.041 ↗
22. Editable supercapacitors with customizable stretchability based on mechanically strengthened ultralong MnO2 nanowire composite10.1002/adma.201704531 ↗
23. Preparation and supercapacitive performance of nanosized manganese dioxide/ordered mesoporous carbon composites10.1016/j.electacta.2016.01.205 ↗
24. Highly flexible conductive fabrics with hierarchically nanostructured amorphous nickel tungsten tetraoxide for enhanced electrochemical energy storage10.1007/s12274-015-0874-z ↗
25. Asymmetric supercapacitors based on graphene/MnO2 nanospheres and graphene/MoO3 nanosheets with high energy density10.1002/adfm201301851 ↗
26. Synthesis of partially graphitic ordered mesoporous carbons with high surface areas10.1002/aenm.201000009 ↗
27. 3D aperiodic hierarchical porous graphitic carbon material for high-rate electrochemical capacitive energy storage10.1002/anie.200702721 ↗
28. Novel insight into neutral medium as electrolyte for high-voltage supercapacitors10.1039/C1EE02262H ↗
29. CN foam loaded with few-layer graphene nanosheets for high-performance supercapacitor electrodes10.1039/C5TA00837A ↗
30. Incorporation of MnO2-coated carbon nanotubes between graphene sheets as supercapacitor electrode10.1021/am2016848 ↗
31. Anion-assisted one-pot synthesis of 1D magnetic α-and β-MnO2 nanostructures for recyclable water treatment application10.1039/C4NJ02196G ↗
32. Hydrothermal synthesis and pseudocapacitance properties of MnO2 nanostructures10.1021/jp0543330 ↗
33. Materials for electrochemical capacitors10.1038/nmat2297 ↗
34. Charge storage mechanism of MnO2 electrode used in aqueous electrochemical capacitor10.1021/cm049649j ↗
35. In-situ synthesis of MnO2@ Graphdiyne oxides nanocomposite with enhanced performance of supercapacitors10.1016/j.electacta.2017.07.102 ↗
36. Facile synthesis of a nitrogen-doped graphene flower-like MnO2 nanocomposite and its application in supercapacitors10.1016/j.apsusc.2017.07.291 ↗
37. MnO2 and biomass-derived 3D porous carbon composites electrodes for high performance supercapacitor applications10.1016/j.jallcom.2018.01.108 ↗
38. Oxygen evolution assisted fabrication of highly loaded carbon nanotube/MnO2 hybrid films for high-performance flexible pseudosupercapacitors10.1002/smll.201503623 ↗
39. Facile synthesis of iron-doped hollow urchin-like MnO2 for supercapacitors10.1007/s10853-016-0720-z ↗
40. MnO2 -decorated hierarchical porous carbon composites for high-performance asymmetric supercapacitors10.1016/j.jpowsour.2019.03.122 ↗
41. Asymmetric supercapacitors using chemically prepared MnO2 as positive electrode materials10.1149/2.0161712jes ↗
42. Hierarchical porous C/MnO2 composite hollow microspheres with enhanced supercapacitor performance10.1039/C7TA00363C ↗
43. In situ assembly of MnO2 nanowires/graphene oxide nanosheets composite with high specific capacitance10.1016/j.electacta.2013.11.036 ↗
44. Free standing three-dimensional graphene/MnO2 composite networks as ultralight and flexible supercapacitor electrodes10.1021/nn304833s ↗
45. Electrophoretic deposition of MnO2-coated carbon nanotubes on a graphite sheet as a flexible electrode for supercapacitors10.1016/j.carbon.2012.07.002 ↗