journal article·2018-06

Spark plasma sintering of WC-based cermets/titanium and vanadium added composites: A comparative study on the microstructure and mechanical properties

Ehsan Ghasali, Touradj Ebadzadeh, Masoud Alizadeh, Mansour Razavi

Ceramics International· Volume 44· Issue 9
Publisher page

Abstract

Abstract In an attempt to develop the composition and properties of W2C-(W,Ti)C-TiC and WC-WC1-x-VC-V super hardmetals, spark plasma sintering (SPS) method was implemented. WC powders were mixed separately with 10 wt% Ti and 10 wt% V in a high energy mixer mill and sintering processes were performed at temperatures of 2150 and 2000 °C, respectively. XRD investigations revealed the formations of TiC and (Ti,W)C as the reaction products in WC-10 wt% Ti composite. Moreover, the interfacial reaction between WC and V led to the formation of WC1-x and VC compounds. A higher bending strength (613 ± 25 MPa) and fracture toughness (4.1 ± 0.58 MPa m1/2) were obtained for WC-10 wt% V samples compared to WC-10 wt% Ti, While the WC-10 wt% Ti composite showed a higher value of hardness (3128 ± 42 Vickers) in comparison to WC-10 wt% V (2632 ± 39 Vickers), which can act as a super hard cermet.
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Research context

OpenAlex topics: Advanced materials and composites · Advanced ceramic materials synthesis · Aluminum Alloys Composites Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (45)

Show source-provided references
1. Cemented carbide phase diagrams: a review10.1016/j.ijrmhm.2011.02.004 ↗
2. WC-Co particles reinforced aluminum matrix by conventional and microwave sintering10.1590/1516-1439.027115 ↗
3. Upadhyaya · 1998
4. Synthesis, sintering, and mechanical properties of nanocrystalline cemented tungsten carbide–a review10.1016/j.ijrmhm.2008.07.011 ↗
5. Solid-state solubilities of grain-growth inhibitors in WC-Co and WC-MC-Co hardmetals10.1016/j.jallcom.2016.03.117 ↗
6. Densification, microstructure and mechanical properties of hot pressed ZrB2–SiC ceramic doped with nano-sized carbon black10.1016/j.ceramint.2017.03.188 ↗
7. Kurlov · 2013
8. M. Prathabrao, S.Y.M. Amin, M.H.I. Ibrahim, Review on sintering process of WC-Co cemented carbide in metal injection molding technology, in: IOP Conf. Ser. Mater. Sci. Eng., IOP Publishing, 2017, p. 12017.10.1088/1757-899X/165/1/012017 ↗
9. Grain growth inhibition of hardmetals during initial heat-up10.1016/j.ijrmhm.2017.12.016 ↗
10. Influence and function of inhibitor VC/Cr3C2 on the grain growth in super fine WC–Co cermets
11. Effect of heating method on microstructure and mechanical properties of zircon reinforced aluminum composites10.1590/1980-5373-mr-2016-0390 ↗
12. Evaluation of microstructure and mechanical properties of Al-TaC composites prepared by spark plasma sintering process10.1016/j.jallcom.2017.02.144 ↗
13. Fracture toughness of two phase WC-Co cermets10.1016/0956-7151(94)90057-4 ↗
14. Microwave sintering of aluminum-ZrB2 composite: focusing on microstructure and mechanical properties10.1590/1980-5373-MR-2015-0799 ↗
15. Low temperature sintering of aluminum-zircon metal matrix composite prepared by spark plasma sintering10.1590/1980-5373-MR-2016-0395 ↗
16. Mechanical and microstructural properties of WC-based cermets: a comparative study on the effect of Ni and Mo binder phases10.1016/j.ceramint.2017.10.189 ↗
17. Z.Z. Fang, M.C. Koopman, H. Wang, Cemented tungsten carbide hardmetal-an introduction, in: Compr. Hard Mater., Elsevier Ltd., 2014.10.1016/B978-0-08-096527-7.00004-0 ↗
18. Sarin · 2014
19. Production of Al-SiC-TiC hybrid composites using pure and 1056 aluminum powders prepared through microwave and conventional heating methods10.1016/j.jallcom.2016.08.145 ↗
20. Evaluation of microstructure and mechanical properties of Al-TiC metal matrix composite prepared by conventional, microwave and spark plasma sintering methods10.3390/ma10111255 ↗
21. Fabrication of magnesium-boron carbide metal matrix composite by powder metallurgy route: comparison between microwave and spark plasma sintering10.1016/j.jallcom.2016.12.146 ↗
22. The effect of electric field and pressure on the synthesis and consolidation of materials: a review of the spark plasma sintering method10.1007/s10853-006-6555-2 ↗
23. Preparation of silicon carbide/carbon fiber composites through high-temperature spark plasma sintering10.1016/j.jascer.2017.10.004 ↗
24. Effect of molybdenum additions on the microstructure and properties of WC–W 2 C alloys10.1007/s11106-014-9607-1 ↗
25. Enhanced interface structure and properties of titanium carbonitride-based cermets with the extra solid phase reaction10.3390/ma10091090 ↗
26. TiO2ceramic particles-reinforced aluminum matrix composite prepared by conventional, microwave, and spark plasma sintering10.1177/0021998317751283 ↗
27. Sintering behavior of ZrB2–SiC composites doped with Si3N4: a fractographical approach10.1016/j.ceramint.2017.04.144 ↗
28. Effects of nano-graphite content on the characteristics of spark plasma sintered ZiB 2–SiC composites
29. Electron microscopy study of reaction layers between single-crystal WC particle and Ti–6Al–4V after laser melt injection10.1016/j.actamat.2009.04.021 ↗
30. Microstructure evolution of single crystal WCp reinforced Ti–6Al–4V metal matrix composites produced at different cooling rates10.1016/j.jallcom.2009.04.057 ↗
31. Microstructure and mechanical properties of (Ti, W) C–Ni cermet prepared using a nano-sized TiC–WC powder mixture10.1016/j.jallcom.2015.03.115 ↗
32. Effect of V, Cr and Mn additions on the microstructure of WC–Co10.1016/j.ijrmhm.2009.02.002 ↗
33. On the formation of WC1− x in nanocrystalline cemented carbides10.1016/j.scriptamat.2012.09.016 ↗
34. Tungsten carbides and WC phase diagram10.1134/S0020168506020051 ↗
35. Kosolapova · 1990
36. Davis · 2002
37. Goldschmid · 2013
38. The Ti-WC (titanium-tungsten-carbon) system10.1361/105497199770335866 ↗
39. Untersuchungen im system Vanadin-Wolfram-Kohlenstoff10.1007/BF01189609 ↗
40. Experimental investigation and thermodynamic assessment of the V–W–C system10.1016/j.jallcom.2004.11.047 ↗
41. Fine grained WC–VC–Co hardmetal10.1179/pom.1996.39.3.210 ↗
42. Determination of the composition range suitable to the formation of WC–(V, W) Cx–Co materials10.1016/S0263-4368(01)00047-6 ↗
43. International Standard, ISO 28079, Hardmetals - Palmqvist Toughness Test, 2009, pp. 1–8. 〈https://www.iso.org/standard/44495.html〉.
44. The effect of TiC on structure and hardness of WC-Co composites prepared using various consolidation methods
45. Effect of Al and Mo addition on phase formation, mechanical and microstructure properties of spark plasma sintered iron alloy10.1016/j.mtcomm.2017.10.005 ↗