journal article·2020-07

Synthesis and characterization of CeO2/rGO nanoflakes as electrode material for capacitive deionization technology

Ayman Yousef, Abdullah M. Al-Enizi, Ibrahim M.A. Mohamed, M.M. El-Halwany, Mohd Ubaidullah, Robert M. Brooks

Ceramics International· Volume 46· Issue 10
Publisher page

Abstract

Abstract The development of capacitive deionization (CDI) electrode materials to improve electrochemical properties and specific capacitance (Cs) has attracted considerable attention. Due to their excellent physical, chemical, electrical, and electrochemical properties, cerium oxide nanoparticles (CeO2 NPs) have been intercalated between graphene nanoflakes (GNFs) to improve the electrosorption capacity of GNFs in CDI cells. In this study, the nanocomposite was prepared via simple sonication and hydrothermal treatment processes. The electrochemical activity of the nanocomposite was examined by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) in an NaCl aqueous solution. Moreover, the desalination activity was performed based on a batch mode CDI technique. The studied nanocomposite demonstrated a distinct improvement in the Cs and electrosorption capacity compared to those of the pristine GNFs. The studied electrode material (5% CeO2@GNF) showed higher cycling stability, higher specific capacitance (452.26 F/g), higher salt removal efficiency (65%), and better electrosorption capacity (7.2 mg g−1) than GNFs and 10% CeO2@GNFs in 100 μS cm−2 NaCl solution at 1.4 V. Overall, this study introduces a novel, efficient, and low-cost nanocomposite (CeO2@GNF) for the technological advancement of CDI.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Membrane-based Ion Separation Techniques · Membrane Separation Technologies · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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