journal article·2015-12

A.C conductivity and dielectric properties of spinel LiMn2O4 nanorods

B. Nageswara Rao, O. Padmaraj, D. Narsimulu, M. Venkateswarlu, N. Satyanarayana

Ceramics International· Volume 41· Issue 10
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Abstract

Abstract Spinel LiMn 2 O 4 nanorods were prepared by a rapid two steps process. Powder XRD results revealed the formation of cubic crystal structured LiMn 2 O 4 phase. FE-SEM images clearly showed the formation of well defined one-dimensional (1-D) nanorods. The electrical conductivity of spinel LiMn 2 O 4 nanorods was evaluated by analyzing the measured impedance data and found to be 1.81×10 −4 S cm −1 at 303 K. Dielectric studies showed that the LiMn 2 O 4 nanorods exhibit high dielectric constant and it is found to increase with increase in temperature. The electric modulus studies revealed the non-Debye nature of the LiMn 2 O 4 nanorods. Further, the electrochemical performance of the fabricated Swagelok-type lithium cells using the prepared LiMn 2 O 4 nanorods was investigated. The charge–discharge studies of the fabricated Swagelok-type cell showed that the spinel LiMn 2 O 4 nanorods exhibit good cycleability in the voltage range 3.3–4.4 V.
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OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Ferroelectric and Piezoelectric Materials

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