journal article·2016-05

Effect of lateral size of graphene nano-sheets on the mechanical properties and machinability of alumina nano-composites

Harshit Porwal, Richa Saggar, Peter Tatarko, Salvatore Grasso, Theo Saunders, Ivo Dlouhý, Mike J. Reece

Ceramics International· Volume 42· Issue 6
Publisher page

Abstract

Abstract Graphene Nano-Sheets (GNS) with different lateral sizes (193, 373 and 1070 nm) were produced using liquid phase exfoliation and controlled centrifugation. Alumina-GNS (0.8 vol%) composites with different size GNS were consolidated using spark plasma sintering. The fracture toughness, hardness and elastic modulus of the composites decreased with increasing GNS size. Microstructural investigation of the composites suggested that their mechanical properties were directly related to: (1) average number of GNS present per unit volume in composite; and (2) relative size of GNS to alumina grains. Small size GNS resulted in a 35% improvement of fracture toughness of alumina-GNS composite. The mechanism of crack propagation changed as the size of the GNS increased. The smaller size GNS produced various toughening mechanisms, while the larger size GNS, with similar size to the alumina grains, resulted in grain boundary sliding. The composite with larger size GNS was machinable using ordinary tungsten carbide drill bits.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Aluminum Alloys Composites Properties · Advanced ceramic materials synthesis · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (41)

Show source-provided references
1. Review of graphene–ceramic matrix composites10.1179/174367613X13764308970581 ↗
2. Recent advances on carbon nanotubes and graphene reinforced ceramics nanocomposites10.3390/nano5010090 ↗
3. Graphene ceramic composite as a new kind of surface-renewable electrode: application to the electroanalysis of ascorbic acid10.1007/s00604-014-1238-1 ↗
4. Interfacial stress transfer in a graphene nanosheet toughened hydroxyapatite composite10.1063/1.4900424 ↗
5. Directional architecture of graphene/ceramic composites with improved thermal conduction for thermal applications10.1039/C3TA14325B ↗
6. Toughening in ceramics containing graphene fillers10.1016/j.ceramint.2014.03.150 ↗
7. Enhancement mechanisms of graphene in nano-58S bioactive glass scaffold: mechanical and biological performance10.1038/srep04712 ↗
8. Role of synthesis method on microstructure and mechanical properties of graphene/carbon nanotube toughened Al2O3 nanocomposites10.1016/j.ceramint.2015.04.054 ↗
9. A novel approach to electroconductive ceramics filled by graphene covered nanofibers10.1016/j.matdes.2015.10.148 ↗
10. Graphene NanoPlatelets reinforced tantalum carbide consolidated by spark plasma sintering10.1016/j.msea.2013.06.006 ↗
11. Toughening mechanisms and mechanical properties of graphene nanosheet-reinforced alumina10.1016/j.matdes.2015.09.125 ↗
12. Fabrication and properties of reduced graphene oxide reinforced yttria-stabilized zirconia composite ceramics10.1016/j.jeurceramsoc.2013.11.034 ↗
13. Thermal stability and conductivity of hot-pressed Si3N4–graphene composites10.1007/s10973-013-3565-6 ↗
14. Processing and bioactivity of 45S5 Bioglass®-graphene nanoplatelets composites10.1007/s10856-014-5172-x ↗
15. Graphene for tough and electroconductive alumina ceramics10.1016/j.jeurceramsoc.2013.07.007 ↗
16. Toughened and machinable glass matrix composites reinforced with graphene and graphene-oxide nano platelets10.1088/1468-6996/14/5/055007 ↗
17. Elastic properties of silicon nitride ceramics reinforced with graphene nanofillers10.1016/j.matdes.2015.08.044 ↗
18. Anisotropic elastic moduli and internal friction of graphene nanoplatelets/silicon nitride composites10.1016/j.compscitech.2012.12.003 ↗
19. Toughening in graphene ceramic composites10.1021/nn200319d ↗
20. Graphene-reinforced mechanical properties of calcium silicate scaffolds by laser sintering10.1039/C3RA47862A ↗
21. Synthesis of hydroxyapatite-reduced graphite oxide nanocomposites for biomedical applications: oriented nucleation and epitaxial growth of hydroxyapatite10.1039/c3tb00531c ↗
22. Tribological properties of silica–graphene nano-platelet composites10.1016/j.ceramint.2014.04.046 ↗
23. Mechanical properties of graphene platelet-reinforced alumina ceramic composites10.1016/j.ceramint.2013.01.041 ↗
24. In situ reduction of graphene oxide nanoplatelet during spark plasma sintering of a silica matrix composite10.1016/j.jeurceramsoc.2014.04.031 ↗
25. Simultaneous strengthening and toughening of reduced graphene oxide/alumina composites fabricated by molecular-level mixing process10.1016/j.carbon.2014.06.074 ↗
26. Graphene reinforced alumina nano-composites10.1016/j.carbon.2013.07.086 ↗
27. Chemical methods for the production of graphenes10.1038/nnano.2009.58 ↗
28. Liquid exfoliation of defect-free graphene10.1021/ar300009f ↗
29. Solvent-exfoliated graphene at extremely high concentration10.1021/la201797h ↗
30. Improved adhesive strength and toughness of polyvinyl acetate glue on addition of small quantities of graphene10.1021/am302864f ↗
31. Reliability of the chevron-notch technique for fracture toughness determination in glass10.1016/S0921-5093(02)00612-3 ↗
32. High-concentration solvent exfoliation of graphene10.1002/smll.200902066 ↗
33. Size selection of dispersed, exfoliated graphene flakes by controlled centrifugation10.1016/j.carbon.2011.09.001 ↗
34. Highly electrically conducting glass-graphene nanoplatelets hybrid coatings10.1021/acsami.5b02553 ↗
35. The beneficial effect of graphene nanofillers on the tribological performance of ceramics10.1016/j.carbon.2013.04.102 ↗
36. Unoxidized graphene/alumina nanocomposite: fracture- and wear-resistance effects of graphene on alumina matrix10.1038/srep05176 ↗
37. Tribological performance of graphene/carbon nanotube hybrid reinforced Al2O3 composites10.1038/srep11579 ↗
38. Tribological properties of Si3N4–graphene nanocomposites10.1016/j.jeurceramsoc.2013.03.035 ↗
39. Wear damage of Si3N4–graphene nanocomposites at room and elevated temperatures10.1016/j.jeurceramsoc.2014.02.025 ↗
40. Machining a machinable glass–ceramic10.1016/S0042-207X(78)80514-4 ↗
41. Scratch behaviour of graphene alumina nanocomposites10.1179/1743676115Y.0000000030 ↗