Oxidation behavior of SiC–SiBCN ceramics
Source abstract
Abstract
Abstract The oxidation behavior of SiC–SiBCN ceramics was studied at temperature range of 1200–1500 °C in air atmosphere. Amorphous SiBCN derived from a polyborosilazane precursor was used to prepare SiC–SiBCN composite ceramics. XRD and SEM were employed to analyze the phase composition and microstructure after oxidation experiments. The oxidation kinetics was studied by measuring the thickness of oxide layers. The values of the oxide layer thickness were found to fit a typical parabolic kinetics. The activation energy of the oxidation was also calculated from the rate constants of the different temperatures according to Arrhenius equation.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced ceramic materials synthesis · Advanced materials and composites · Magnesium Oxide Properties and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (30)
Show source-provided references
1. Covalent high-performance ceramics10.1002/adma.19920040307 ↗
2. Oxidation behavior of silicon carbide10.1111/j.1151-2916.1958.tb12932.x ↗
3. Oxidation kinetics of silicon carbide crystals and ceramics: I, In dry oxygen10.1111/j.1151-2916.1986.tb07470.x ↗
4. Oxidation kinetics of hot-pressed silicon carbide10.1007/BF00545142 ↗
5. Oxidation kinetics of hot-pressed and sintered α-SiC10.1111/j.1151-2916.1981.tb10297.x ↗
6. Silazane derived ceramics and related materials10.1016/S0927-796X(00)00008-5 ↗
7. A silicoboron carbonitride ceramic stable to 2,000°C10.1038/382796a0 ↗
8. Oxidation behavior of precursor derived ceramics in the system Si–(B)–CN10.4028/www.scientific.net/KEM.175-176.69 ↗
9. Polymer derived non-oxide ceramics modified with late transition metals10.1039/c2cs15326b ↗
10. Precursor‐derived Si–B–C–N ceramics: oxidation kinetics10.1111/j.1151-2916.2001.tb00985.x ↗
11. Characterization of oxidized polymer‐derived SiBCN fibers10.1111/j.1151-2916.2001.tb00987.x ↗
12. Novel high‐performance ceramics—amorphous inorganic networks from molecular precursors10.1002/anie.199703281 ↗
13. H.P. Baldus, G. Passing, Studies on SiBN (C)–ceramics: oxidation- and crystallization behavior lead the way to applications, MRS Proceedings, vol. 346, Cambridge University Press, 1994.10.1557/PROC-346-617 ↗
14. K.G. Nickel, E. Butchereit, C. Schumacher, On the role of boron in the oxidation of Si–C1N1B ceramics, in: High Temperature Corrosion and Materials Chemistry: Proceedings of the Per Kofstad Memorial Symposium. The Electrochemical Society, 2000.
15. E. Butchereit, K.G..Nickel, Comparison of the oxidation kinetics of boron free and boron containing precursor derived ceramics, in: High Temperature Corrosion and Materials Chemistry III: Proceedings of the International Symposium, vol. 2001, The Electrochemical Society, 2001.
16. Synthesis and characterization of a new liquid polymer precursor for Si–B–C–N ceramics10.1007/s10853-011-5549-x ↗
17. Oxidation kinetics of hot-pressed ZrB2–SiC ceramic matrix composites10.1016/j.ceramint.2012.09.091 ↗
18. Oxidation behavior of a pressureless sintered ZrB2–MoSi2 ceramic composite10.1557/JMR.2005.0111 ↗
19. Synthesis and thermal behavior of novel Si–BCN ceramic precursors10.1021/cm9910299 ↗
20. Oxidation behavior of a fully dense polymer‐derived amorphous silicon carbonitride ceramic10.1111/j.1551-2916.2004.00483.x ↗
21. Processing, crystallization and characterization of polymer derived nano-crystalline Si–B–C–N ceramics10.1007/s10853-006-0934-6 ↗
22. Thermal stability, phase evolution, and crystallization in Si–B–C–N ceramics derived from a polyborosilazane precursor10.1111/j.1151-2916.2002.tb00357.x ↗
23. Oxidation of Si3N4 in the range 1300 to 1500C10.1111/j.1151-2916.1976.tb09505.x ↗
24. A comparison of the oxidation kinetics of SiC and Si3N410.1149/1.2048559 ↗
25. Bourhis · 2007
26. Effect of carbon and boron on the high-temperature oxidation of silicon carbide10.1111/j.1151-2916.1995.tb08918.x ↗
27. Initial stage of oxidation process and microstructure analysis of HfB2–20vol% SiC composite at 1500°C10.1016/j.scriptamat.2010.12.002 ↗
28. Insights into the oxidation chemistry of SiOC ceramics derived from silsesquioxanes10.1023/A:1008723813991 ↗
29. Some new perspectives on oxidation of silicon carbide and silicon nitride10.1111/j.1151-2916.1991.tb04348.x ↗
30. Vaporization of inorganic substances: B2O3, TeO2 and Mg3N210.1021/j150524a009 ↗