journal article·2012-01

Temperature compensating ZnAl2O4–Co2TiO4 spinel-based low-permittivity microwave dielectric ceramics

Wen Lei, Wen-Zhong Lu, Xiao-Chuan Wang

Ceramics International· Volume 38· Issue 1
Publisher page

Abstract

TiO2, CaTiO3 and SrTiO3 were added to the 0.79ZnAl2O4–0.21Co2TiO4 (ZACT in abbreviation) system to control its temperature coefficient of resonant frequency (τf). The effects of these additions on sinterability, phase compositions and microwave dielectric properties of the ceramics synthesized by the solid-state reaction were investigated. The results show that TiO2, CaTiO3 and SrTiO3 can all reduce the densification temperature of the ZACT ceramics within the scope from 75 to 150 °C. CoTi2O5 second-phase with negative τf value appears in the TiO2 doped ZACT system, which inhibits TiO2 addition's function for adjusting τf value of ZACT ceramics. While, CaTiO3 and SrTiO3 can both tune effectively τf value to obtain temperature-stable materials.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Microwave Dielectric Ceramics Synthesis · Ferroelectric and Piezoelectric Materials · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (11)

Show source-provided references
1. Effects of TiO2 on sinterability and dielectric properties of high-Q forsterite ceramics10.1016/S0955-2219(03)00177-8 ↗
2. Synthesis and microwave dielectric properties of Re3Ga5O12 (Re: Nd, Sm, Eu, Dy, Yb, and Y) ceramics10.1111/j.1551-2916.2006.01435.x ↗
3. High-Q microwave dielectric materials based on the spinel Mg2TiO410.1111/j.1551-2916.2006.01271.x ↗
4. Temperature stable low loss ceramic dielectrics in (1−x)ZnAl2O4−xTiO2 system for microwave substrate applications10.1140/epjb/e2004-00321-8 ↗
5. (1−x)MgAl2O4−xTiO2 dielectrics for microwave and millimeter wave applications10.1007/s00339-005-3282-5 ↗
6. Modification of MgAl2O4 microwave dielectric ceramics by Zn substitution10.1111/j.1551-2916.2007.01550.x ↗
7. Microwave dielectric properties of ZnAl2O4–TiO2 spinel-based composites10.1016/j.matlet.2007.01.017 ↗
8. Modification of ZnAl2O4-based low-permittivity microwave dielectric ceramics by adding 2MO-TiO2 (M=Co, Mg, and Mn)10.1111/j.1551-2916.2007.02233.x ↗
9. Low sintering temperature of (Zn0.65Mg0.35)TiO3−xCaTiO3-based dielectric with controlled temperature coefficient10.1016/j.ceramint.2008.10.015 ↗
10. Effects of SrTiO3 additives on the structure and microwave dielectric properties of Ba4.2Sm9.2Ti18O54 ceramics10.1016/j.ceramint.2008.03.015 ↗
11. A dielectric resonant method of measuring inductive capacitance in the millimeter range10.1109/TMTT.1960.1124749 ↗