journal article·2015-12

Effect of surfactant concentration on textural, morphological and magnetic properties of CoFe2O4 nanoparticles and evaluation of their adsorptive capacity for Pb(II) ions

Daniela C. Culita, Claudia Maria Simonescu, Mioara Dragne, Nicolae Stanica, Cornel Munteanu, Silviu Preda, Ovidiu Oprea

Ceramics International· Volume 41· Issue 10
Publisher page

Abstract

Abstract Mesoporous CoFe 2 O 4 nanoparticles were synthesized through a simple precipitation method using cetyltrimethylammonium bromide (CTAB) as surfactant. Variation of surfactant concentration has been investigated to synthesize CoFe 2 O 4 nanoparticles with superior textural properties. The samples were characterized by FTIR, TG/DSC, XRD, SEM, N 2 adsorption–desorption technique, and vibrating sample magnetometer (VSM). The obtained results revealed that the surface area and magnetic properties of CoFe 2 O 4 are significantly influenced by the initial concentration of CTAB. The capacity of the synthesized samples to adsorb lead ions from aqueous solution and the factors affecting the adsorption process, like contact time and pH of the media, were evaluated. The Pb 2+ adsorption followed pseudo-second-order kinetics, and the maximum Pb 2+ adsorption capacity was 32.11 mg g −1 according to the Langmuir isotherm.
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Research context

OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Iron oxide chemistry and applications · Nanomaterials for catalytic reactions

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