journal article·2018-06

Effect of MoSi2 addition on ablation behavior of ZrC coating fabricated by vacuum plasma spray

Tao Liu, Yaran Niu, Chong Li, Jun Zhao, Jimei Zhang, Yi Zeng, Xuebin Zheng, Chuanxian Ding

Ceramics International· Volume 44· Issue 8
Publisher page

Abstract

Abstract To improve the ablation resistance of ZrC coating, MoSi2 incorporated ZrC composite coatings were fabricated by vacuum plasma spray. The ablation resistance of the composite coatings was evaluated using a plasma jet with a heat flux of 1.94 MW/m2. The phase compositions and microstructures of the coatings before and after ablation were investigated, and the ablation mechanisms and effect of MoSi2 were analyzed based on thermal dynamics and microstructure changes. Results showed that MoSi2 addition could improve the ablation resistance of ZrC coating by means of decreasing the surface temperature and changing the microstructure of the oxidation layer. Si derived from the decomposition of MoSi2, which occurred within coating, was beneficial to maintain the thickness and integrity of the SiO2 layer and reduce the oxygen pressure beneath. The thickness of the SiO2 layer was related to the formation rate (Vf) and the consumption rate (Vc) of SiO2. The diffusion of Si was in favor of increasing the value of Vf. MoSi2 could be one choice to improve the ablation resistance of the ZrC coating.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: High-Temperature Coating Behaviors · Advanced ceramic materials synthesis · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (33)

Show source-provided references
1. Multiple ablation resistance of La2O3/Y2O3-doped C/SiC-ZrC composites10.1016/j.ceramint.2015.06.126 ↗
2. Ablation behavior of ZrB2-based coating prepared by supersonic plasma spraying for SiC-coated C/C composites under oxyacetylene torch10.1007/s11666-013-9913-z ↗
3. Oxidation-based materials selection for 2000 °C+ hypersonic aerosurfaces: theoretical considerations and historical experience10.1023/B:JMSC.0000041686.21788.77 ↗
4. ZrC Ablation protective coating for carbon/carbon composites10.1016/j.carbon.2009.07.047 ↗
5. Preparation and ablation properties of ZrC-SiC coating for carbon/carbon composites by solid phase infiltration10.1016/j.apsusc.2011.08.102 ↗
6. Microstructures and ablation resistance of ZrC coating for SiC-coated carbon/carbon composites prepared by supersonic plasma spraying10.1007/s11666-011-9676-3 ↗
7. Ablation behavior of rare earth La-modified ZrC coating for SiC-coated carbon/carbon composites under an oxyacetylene torch10.1016/j.corsci.2015.11.030 ↗
8. Ablation of vacuum plasma sprayed TaC-based composite coatings10.1016/j.ceramint.2015.05.100 ↗
9. Influence of oxidation behavior of feedstock on microstructure and ablation resistance of plasma-sprayed zirconium carbide coating10.1007/s11666-015-0307-2 ↗
10. Mechanical, thermal, and oxidation properties of refractory hafnium and zirconium compounds10.1016/S0955-2219(99)00129-6 ↗
11. Pierson · 1996 · 68
12. Interfacial reaction on oxidation of carbides with formation of carbon10.1016/S0167-2738(01)00727-5 ↗
13. A model for transitions in oxidation regimes of ZrB210.1111/j.1551-2916.2011.04927.x ↗
14. Microscopy of structural ceramics10.1002/adma.19970090304 ↗
15. Ablation resistance of ZrC/SiC gradient coating for SiC-coated carbon/carbon composites prepared by supersonic plasma spraying10.1016/j.jeurceramsoc.2016.02.047 ↗
16. Suspension plasma spraying of sub-micron silicon carbide composite coatings10.1007/s11666-015-0242-2 ↗
17. Oxidation-resistant ZrB2–SiC composites at 2200 °C10.1016/j.compscitech.2007.08.017 ↗
18. Toward oxidation-resistant ZrB2-SiC ultrahigh temperature ceramics10.1007/s11661-010-0540-8 ↗
19. Microstructure and wear resistance of plasma-sprayed molybdenum coating reinforced by MoSi2 Particles10.1007/s11666-016-0440-6 ↗
20. Thermal stability of MoSi2-SiC composites in air at temperature of 1100–1400 °C10.1134/S1087659609020151 ↗
21. Dense ZrB2-MoSi2 composite coating fabricated by low pressure plasma spray (LPPS)10.1016/j.ceramint.2013.05.038 ↗
22. Microstructure characteristics and oxidation behavior of molybdenum disilicide coatings prepared by vacuum plasma spraying10.1007/s11666-013-9896-9 ↗
23. Comparison of ZrB2-MoSi2 composite coating fabricated by atmospheric and vacuum plasma spray processes10.1007/s11666-016-0490-9 ↗
24. SiC coatings for carbon/carbon composites fabricated by vacuum plasma spraying technology10.1007/s11666-011-9697-y ↗
25. Phase stability, thermal conductivity and crystal growth behavior of RE2O3 (RE= La, Yb, Ce, Gd) co-doped Y2O3 stabilized ZrO2 powder10.1007/s10971-017-4483-z ↗
26. Stabilization of tetragonal ZrO2 in ZrO2-SiO2 binary oxides10.1111/j.1151-2916.2000.tb01243.x ↗
27. Mechanism of ablation of 3D C/ZrC-SiC composite under an oxyacetylene flame10.1016/j.corsci.2012.11.009 ↗
28. Oxidation kinetics and mechanisms of a 2D-C/C composite10.1016/j.carbon.2006.06.027 ↗
29. The oxidation behavior of SiC-ZrC-SiC-coated C/SiC minicomposites at ultrahigh temperatures10.1111/j.1551-2916.2010.04178.x ↗
30. Diffusion annealing of Mo/MoSi2 couple and silicon diffusivity in Mo5Si3 layer10.1016/j.msea.2007.01.026 ↗
31. Oxidation and interdiffusion behavior of Niobium substrate coated MoSi2 coating prepared by spark plasma sintering10.1016/j.apsusc.2014.09.018 ↗
32. Formation of MoSi2-SiO2 coatings on molybdenum substrates by CVD/MOCVD10.1016/j.surfcoat.2005.02.212 ↗
33. Microstructure characteristics and oxidation behavior of vacuum plasma sprayed tungsten disilicide coating10.1016/j.ceramint.2016.09.024 ↗